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But in the + moiety, the three benzimidazole rings shared the whole space equally, the dihedral angel among them is about 120°, just like three fan blades of an airscrew, the molecular structure appear gear-like shape.

X-射线单晶衍射测试、红外、紫外等方法确定了三(2-苯并咪唑亚甲基)胺的Fe和Co配合物的结构,由晶体结构发现金属配位情况不同、配合物在结构上存在着差异,Fe为八面体构型,而Co为三角双锥构型;其次,两配合物中的苯并咪唑环间夹角不同,配合物中包含N2和N4的两个苯并咪唑环间夹角仅为9.41(0.11),几乎构成一个平面,呈蝴蝶形;后者Co三个苯并咪唑环几乎平分了整个空间,它们之间的夹角约为120,呈三扇叶螺旋桨式构型,为齿轮形。

Epoxides, episulphides and ethylene imines also polymerize via similar cyclic onium ion mechanisms.

环氧化合物,环硫化合物和乙烯亚胺也可以按类似于环氧?睦胱拥幕?理进行聚合。

Epoxides, episulphides and ethylene imines also polymerize via similar cyclic onium ion mechanisms

环氧化合物,环硫化合物和乙烯亚胺也可以按类似于环氧?

In this paper, the innovative improvement of the cyclization and chlorination of quinoxaline was: 1. DHQX was prepared via reactingο-phenylenediamine with ethyl- oxalate in hydrochloric acid, the mixture was stired at 75-80℃for 2h.

本文对喹喔啉环合和氯代反应作了一些革新性的改进: 1、在环合合成DHQX时:以盐酸溶液为介质,邻苯二胺和草酸二乙酯在75-80℃进行环合反应约2h,即可得产物。

Two kinds of polymer-β-cyclodextrin derivatives(PCM-β-CD and PAE-β-CD) with different substition degrees and crosslinked densitiese were synthesized by using epoxychloropropane and Carboxymethyl-β-Cyclodextrin and N-(2- aminoethyl) amidine-β-Cyclodextrin of retaining the amino with different substitution degrees crosslinking polymerization.

论文对含有羧基和氨基的两类β-环糊精聚合物即聚合羧甲基-β-环糊精及聚合N-(2-氨乙基)胺基β-环糊精的合成及其吸附有机污染物碱性品红和苯酚的性能进行了以下研究。1。

Five types of compounds were synthesized via modification of the leading compounds, Mannich bases of cyclopentanones. Among the target compounds, one type was aromatic amine derivatives of a leading compound, three were Mannich bases of a - benzylidene cyclopentanone, the fifth was a Mannich base of a - benzyl cyclopentanone.

以具有抗炎活性的环戊酮Mannich碱为先导化合物进行结构改造,设计合成了一类已知化合物的芳胺Mannich碱衍生物,三类α-苯亚甲基环戊酮Mannich碱类化合物,一类α-苄基环戊酮Mannich碱类化合物。22个目标化合物的结构经核磁共振氢谱、红外光谱和质谱检测确证。

In this paper isopropyl -γ- chlorobutyrate was prepared from γ- butyrolactone by one - step. The effects of molar ratio of reactants, reaction temperature, reaction time on the yield of product were discussed, the optimum reaction condition was obtained.

一氯代丁酸异雨酯是合成新型拟除虫菊酯中间体环丙烷较酸及高效抗菌新药丙氟见酸和环丙氟院酸中间体环丙胺的重要原料['']。

The preparation of grafted derivant of tertiary amine: it is prepared by the reacting of above (1) product and (2) product heated in water bath at 40℃ within 10min.

聚环氧氯丙烷乙二醇哌啶接支衍生物的制备:将上面制备的聚环氧氯丙烷乙二醇与0.25mol环氧丙基哌啶叔胺于40℃水浴条件下进行接支反应。

Its reaction with ketenes generated in situ from acid chlorides afforded-4--azetidin-2-one, thus provided a 14-member library of-4--azetidin-2-one with yields 76~91% and an excellent stereoselectivity.

我们从PEG支载的苯甲醛出发,经腙的制备及其氯代之后,在三辛胺作用下,由氯代腙原位生成的腈亚胺与亚胺发生[3+2]偶极环加成反应,得到PEG支载四芳基-4,5-二氢-1,2,4-三氮唑衍生物。

Employing high-dilute method and 5-fold excess amine prepared two new "two-armed" acyclic diamine intermediates I_a and I_b, which are also intermediates of synthesizing microcyclic compounds, and eight aromatic Schiff bases, II_, were synthesized from reaction of I_a or I_b condensing with different aromatic aldehydes. Their composition and structure were characterized by Elemental analysis, IR, UV-Vis, LIF,~1HNMR and MS. The hydrogen bond interactions and MS fragmental patterns were also discussed.3. Several novel transition metal complexes using II_a as ligand were synthesized and identified by Elemental analysis, IR, UV-Vis,~1HNMR and molar conductivity.

1,采用高度稀释及胺过量五倍的方法合成了两个具有吡啶双酰胺臂的非环二胺Ⅰ_a和Ⅰ_b,并以它们为中间体进一步合成了八个芳香席夫碱Ⅱ_a-Ⅱ_h,通过元素分析及各种波谱测试鉴定了它们的组成与结构,对化合物的UV-Vis、LIF、IR、~1HNMR及MS进行了较为详细的讨论,还探讨了席夫碱的氢键相互作用及质谱裂解方式; 2,以席夫碱Ⅱ_a为配体合成了几个新型的过渡金属配合物,并通过元素分析、UV-Vis、IR、~1HNMR、摩尔电导及DTA—TG对其进行了表征,讨论了化合物的配位情况及配体在配位中的脱质子行为。

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Finally, according to market conditions and market products this article paper analyzes the trends in the development of camera technology, and designs a color night vision camera.

最后根据市场情况和市面上产品的情况分析了摄像机技术的发展趋势,并设计了一款彩色夜视摄像机。

Only person height weeds and the fierce looks stone idles were there.

只有半人深的荒草和龇牙咧嘴的神像。

This dramatic range, steeper than the Himalayas, is the upturned rim of the eastern edge of Tibet, a plateau that has risen to 5 km in response to the slow but un stoppable collision of India with Asia that began about 55 million years ago and which continues unabated today.

这一引人注目的地域范围,比喜马拉雅山更加陡峭,是处于西藏东部边缘的朝上翻的边框地带。响应启始于约5500万年前的、缓慢的但却不可阻挡的印度与亚洲地壳板块碰撞,高原已上升至五千米,这种碰撞持续至今,毫无衰退。