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Based on the possible degradation products, Microbial degradation pathways of metsulfuron-methyl is concluded as follows: after the cleavage of the sulfonylurea bridge, 2-amino-4-methoxy-6-methyl-triazine is demethylated and the annularity reaction of sulphanilamide occurs.

甲磺隆主要降解途径首先是脲桥的断裂,然后6-甲氧基-4-甲基-2-氨基-三氮嗪进一步脱甲基,而磺酰胺类物质将进一步脱氨基环化。

N-formylmorpholine was synthesized using morpholine and formic acid as starting materials,phosphorous acid as catalyst and cyclohexane as water carrying agent.

马西功,于世涛,季开慧,刘福胜,N-甲酰吗啉的合成以吗啉和甲酸为原料,磷酸为催化剂,环己烷为带水剂合成了N-甲酰吗啉。

Northman ringmail smithy hammer, frost temper, appropriate large chain pattern, appropriate piece of large leather armor, medium quality rings in the appropriate amounts

北人锁甲:冶炼锤,寒霜淬火剂,相应的大型锁甲模具,相应的大型皮甲,数量不等的普通锁环

Imbued northman ringmail smithy hammer, frost temper, appropriate large chain pattern, appropriate piece of large leather armor, imbued ivory, medium quality rings in the appropriate amounts

北人渗透锁甲:冶炼锤,寒霜淬火剂,相应的大型锁甲模具,相应的大型皮甲,数量不等的普通锁环,渗透象牙

RESULTS: The AF cells cultured in different substrates were morphologically undistinguishable. Toluidine blue staining showed that there was also no difference between AF cells cultured on flexible silicone membranes and in plastic plates. The cells growing in different substrates expressed the same levels of collagen typeⅠ,Ⅱ and aggrecan mRNA and integrin β1. AF cells grew well on silicone membranes.

结果:种植于不同基质的纤维环细胞形态学观察无明显差别;在两种基质上的纤维环细胞甲苯胺蓝染色无差异;Ⅰ,Ⅱ型胶原及聚集蛋白聚糖mRNA及细胞膜整合素β1的表达亦无明显差异;纤维环细胞可以黏附于硅橡胶膜上生长。

Computationalresults indicate that the no-planar trans-benzanilide is the most stable structure. The spectra indicate that the Franck Condon region photodissociation dynamics have multidimensional character withnine activemodes. The intensity of υ24 mode in methanol is much stronger than that in acetonitrile. Compared with fatty amides and benzamide, phenyl substitution for H atom on-NH2 group makes C=O solvent effects disappear.

结果表明,苯甲酰苯胺的非平面反式结构为最稳定结构;在Frank-Condon区域内,苯甲酰苯胺主要由9个活性振动模组成;其中ν24(苯环上C=C不对称伸缩振动和CCH的面内弯曲振动,NH面内弯曲振动)振动模在甲醇溶剂中的强度远远大于其在乙腈的强度;与脂肪酰胺类化合物和苯甲酰胺的研究结果比较发现,苯基取代-NH2上的H原子使得C=O不再具有明显的溶剂效应。

The photocycloaddition of 1-naphthonitrile (1-NpCN) and 2,3-dimethyl-2-butene in cyclohexane or benzene gave cyclobutane 3 primarily,but that of 2-NpCN gave azetine 6 asthe major and cyclobutane 5 as the minor product in low conversion photolysis.

在低转化光解情况下,1-萘甲腈(1-NpCN)和2,3-二甲基丁烯-2在环已烷或苯中的光环加成反应主要得到环丁烷3,但2-NpCN主要得到氮杂环丁烯6和少量的环丁烷5,三氟醋酸量增加抑制1-NpCN和DMB的光环加成反应,表明TFA与基态及单激发态1-NpCN生成非光反应的复合物,它也淬灭(1-NpCN-DMB)激基复合物。

The photocycloaddn. of 1-naphthonitrile (1-NpCN) and 2,3-dimethyl-2-butene in cyclohexane or benzene gave cyclobutane I primarily, but that of 2-NpCN gave azetine II as the major and cyclobutane III as the minor product in low conversion photolysis. The photocycloaddn. of 1-NpCN with DMB is retarded by increasing amts. of trifluoroacetic acid which is shown to form non-photoreactive complexes with ground state as well as with singlet excited state 1-NpCN. It also quenches the *(1-NpCN-DMB) exciplex.

在低转光解情况下,1-萘甲腈(1-NpCN)和2,3-二甲基丁烯-2在环已烷或苯中的光环加成反应主要得到环丁烷3,但2-NpCN主要得到氨杂环丁烯6和少量的环丁烷5,三氟醋酸量增加抑制1-NpCN和DMB的光环加成反应,表明TFA与基态及单激发态1-NpCN生成非光反应的复合物,它也淬灭^*(1-NpCN-DMB)激基复合物。

Good thermal stability and self-extinguishing behavior was observed with the cured polybenzoxazine resins. Second, furan-containing benzoxazine monomers, P-FBz, BPA-FBz, and 4FP-FBz were prepared using furfurylamine as a raw material. Formation of furfurylamine Mannich bridge networks in the polymerizations of P-FBz and BPA-FBz increased the cross-linking densities and thermal stability of the resulting polybenzoxazines. P-FBz and BPA-FBz- based polymers also exhibited high glass transition temperatures above 300℃, high char yields, and low flammability with a limited oxygen index value of 31. The dielectric (Dk3.21–3.39) and mechanical properties (high storage modulus of 3.0–3.9 GPa and low coefficient of thermal expansion of 37.7– 45.4 ppm) of the P-FBz and BPA-FBz-based polymers were superior or comparable to other polybenzoxazines. 4FP-FBz used for polybenzo- xazine modification by means of formation of benzoxazine hybridation with P-FBz.

第二部份以2-呋喃甲胺为起始物,制备了P-FBz、4FP-FBz与BPA-FBz 三个含呋喃官能基之氧代氮代苯并环己烷的单体;BPA-FBz与P-FBz於开环聚合中形成之Mannich bridge网状结构有效地提升聚氧代氮代苯并环己烷聚合物之交联密度与热安定性;Poly与Poly具有大於300℃之玻璃转移温度、高的焦炭生成率与具有31之极限氧指数(Limited oxygen index, LOI)的难燃性特质,Poly与Poly之介电常数(Dk=3.21~3.39)与机械性质[3.0~3.9 GPa的储存模数与37.7~45.4ppm之低热膨胀系数( Low coefficient of thermal expansion, Low CTE)]均较其他聚氧代氮代苯并环己烷为优;4FP-FBz具有低之介电常数(Dk=2.7),以其作为降低介电常数之反应型改质剂,与P-FBz混成,证实可有效地降低Poly的介电常数。

Our results indicated that (1)SO_2 derivatives could dose-dependently relax the isolated aorta rings with or without endothelium precontracted by NE, no difference was found for the rings with and without endothelium;(2)Levels of cAMP and 6-Keto(PGI_2) in isolated aortic rings were increased by SO_2 derivatives in a dose-dependent way, which were independent of endothelium;(3)SO_2 derivatives decreased cGMP levels in the rings, but not significantly; The decrease of cGMP levels was also independent of endothelium;(4)No changes of TXB_2 in rings with or without endothelium were observed;(5)Whether presence or absence of endothelium, cAMP/cGMP and 6-Keto/TXB_2 ratios were increased significantly.

结果:①SO_2衍生物对去甲肾上腺素预收缩的内皮完整和去除内皮的大鼠胸主动脉血管环均呈浓度依赖性舒张作用,且其张力变化在内皮完整与去内皮的血管环之间无显著性差异;②SO_2衍生物可引起血管组织中cAMP、6-Keto(即PGI_2)含量剂量依赖性增加,其增加程度与内皮无关;③SO_2衍生物对血管环cGMP含量呈降低趋势但在统计学上无显著意义,且对去除内皮血管无显著影响;④SO_2衍生物对去内皮或内皮完整血管环的TXB_2含量均无明显影响;⑤无论是否去除内皮,SO_2衍生物均可引起cAMP/cGMP和6-Keto/TXB_2比值显著升高。

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Neither the killing of Mr Zarqawi nor any breakthrough on the political front will stop the insurgency and the fratricidal murders in their tracks.

在对危险的南部地区访问时,他斥责什叶派民兵领导人对中央集权的挑衅行为。

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