环状二酯

A photoresist composition including a polymer is disclosed, wherein the polymer includes at least one monomer having the formula: wherein, R1 is selected from H, linear, branched or circular alkyl with 1-20 carton atoms, linear, branched or circular alkyl with 1-20 C atom, which is perfluorinated or semi-perfluorinated; and CN; R2 is alicyclic group with 5 or more carbon atoms; X is selected from methylene, aether, ester, amide and the connecting part of the carbonate; R3 is linear or branched alkylene with one or more carbon atoms or perfluorinated or semi-perfluorinated linear or branched alkylene; R4 is selected from H, CH3, CF3, CHF2, CH2F and perfluorinated or semi-perfluorinated aliphatic group; R5 is selected from the CF3, CHF2, CH2F and perfluorinated or semi-perfluorinated substituted and unsubstituted aliphatic group; n is 1 or higher integer; OR12 is OH or at least an acid unstable group selected from the tert-alkyl carbonate, tert-alkyl ester, tert-alkyl aether, acetal and ketal.

本发明公开了一种包含一种聚合物的光刻胶组合物，该聚合物包括至少一种具有下列结构的单体：其中，R 1 选自氢、具有1～20个碳原子的线形、支化或环状烷基、半氟化或全氟化的具有1～20个碳原子的线形、支化或环状烷基、以及CN；R 2 为具有5个或更多个碳原子的脂环基团；X为选自亚甲基、醚、酯、酰胺和碳酸酯的连接部分；R 3 为具有1个或多个碳原子的线形或支化亚烷基或者半氟化或全氟化的线形或支化亚烷基；R 4 选自氢、甲基(CH 3 )、三氟甲基(CF 3 )、二氟甲基(CHF 2 )、氟代甲基(CH 2 F)、以及半氟化或全氟化的脂族基团；R 5 选自三氟甲基(CF 3 )、二氟甲基(CHF 2 )、氟代甲基(CH 2 F)、以及半氟化或全氟化的取代或未取代的脂族基团；n为1或更大的整数；OR 12 为OH或者选自叔烷基碳酸酯、叔烷基酯、叔烷基醚、缩醛和缩酮的至少一种酸不稳定基团。

In addition to the multi-ring alkenyl ethers and alpha-fluorinated acrylates, additional monomers comprising one or more cyclic aliphatic and heterocyclic compounds, both unsubstituted and substituted, in particular dihydropyrans, may be incorporated into the photosensitive polymers.

除了多环烯基醚和α-氟化丙烯酸酯之外，可向所述光敏聚合物引入另外的单体，所述单体包括一种或多种未取代的和取代的环状脂肪族化合物和杂环化合物，特别是二氢吡喃。

A series of segmented thermally stimulated shape-memory polyurethanes, which consist of polyethylene adipate glycolas the soft segment and 4,4'-diphenylmethane diisocyanate-1,4-butanediol-DPA(which consists of ring components) as the hard segment were synthesized by one-step polymerization.

以聚己二酸乙二醇酯二醇为软段、4，4' -二苯基甲烷二异氰酸酯 1，4 丁二醇含环状结构的扩链剂DPA为硬段，采用一步聚合法制备了一种具有热致形状记忆功能的多嵌段聚氨酯弹性体。

The condensation reaction of levulinates with ethylene glycol brings about corresponding ketal , with respective productivity of 74%, 75% and 75%, and respective structure being verified by IRS.

由乙酰丙酸酯类化合物与乙二醇进行缩合反应，得到相应的环状缩酮化合物，产率分别为 74 %，75 %和 75 ，其结构为红外光谱所证

The density functional theory and MP2 method were employed to study the reaction pathways of methanolysis of 3-methyl cyclic ethylene phosphate: CH3O－＋MEP; CH3OH＋MEP; CH3O－＋HMEP; CH3OH＋HMEP.

采用密度泛函理论和MP2方法研究了3-甲基环状乙撑磷酸二酯与甲醇的反应途径： CH3O－＋MEP； CH3OH＋MEP； CH3O－＋HMEP； CH3OH＋HMEP。

In the presence of catalytic rhodium acetate, ethyl 2-diazo-3-oxo-per fluoroalkanoates, reacted readily with nitriles to give a series of 5-fluoroalkyl substituted 1, 3oxazoles with high regio-selectivity through a metal carbenoid intermediate. The reactions of carbenoids with noncyclic vinyl ethers or cyclic vinyl ethers afforded dihydrofuroates in good to excellent yields. Interestingly, only vinyl C-H insertion compound was obtained concerning of the reaction of carbenoids with 2, 5dimethylfuran due to the steric hindrance of methyl group

醋酸铑分解2-重氮-3-氧代-全氟羧酸乙酯形成的金属卡宾作为1，3-偶极体，可以与一系列芳基或烷基取代的腈反应，高度区域选择性地生成一系列4-乙氧羰基-5-氟烷基取代的噁唑化合物；也可以与富电子的链状和环状的烯基醚反应，以优良的产率得到一系列氟烷基取代的二氢呋喃类化合物；而与2，5-二甲基呋喃的反应，由于甲基的位阻作用，只得到金属卡宾对呋喃3-位烯基碳氢键插入产物。

Cyclic phosphate was synthesized from trimethylolalkane,triethyl phosphate and dimethyl methyl phosphonate,which can be used as environment-friendly durable flame retardant for the padding process of PET fabric.

以亚磷酸三乙酯、三羟甲基丙烷和甲基磷酸二甲酯为原料合成了环状磷酸酯，可作为涤纶织物浸轧用的环保型耐久阻燃剂。

Thus, the thermodynamic equilibrium was shifted and the yield of cyclic carbonates was improved.

在乙腈体系中，以不同的乙酸盐作催化剂，研究了CO2与二醇合成环状碳酸酯的反应。

Tris-(1-aziridinyl)- phosphine oxide and 2-[bis-(2-chloroethyl)-amino]-tetrahydro-1, 3, 2-oxazaphospholidine-2-oxide(Ⅲ, B-518) possess inhibitory action against a variety of animal tumours and have been used clinically. Recently, bis-(1-aziridinyl)-phosphinyl carbamic acid ethyl ester(Ⅱ, AB-100) was found to possess significant activity with low toxicity on experimental animal tumours.

双(2-氯乙基)氨基磷酰二氯与乙烯亚胺在脱水苯或对氧六环中并在三乙胺的存在下进行缩合，生成N，N-双(2-氯乙基)-N′，N-二乙烯基-磷酰胺；与双巯基或双氨基化合物作用，则生成相应的环状磷酰胺、磷酰胺酯以及磷酰胺硫代酯氮芥类化合物。

The optimum conditions for this reaction were confirmed: the mole ratios of the Lewis base and AlCl〓 with the electron-rich aromatic monomer are 1. 2 and 3. 4, respectively; 1, 2-dichloride ethane is the most suitable solvent in this reaction; The solution of the two reactants must be added slowly to a large amount of solvent containing catalyst under pseudo-high dilution conditions; The Lewis base, such as NMP, DMF are applicable in this reaction system.

在此理论的指导下，通过对单体结构的模拟，高选择性地合成了一种新型结构的芳香环状聚硫酯二聚体，对其结构进行了精确的表征，在不同溶剂中得到了该环状二聚体的单晶，单晶X-ray衍射表明该二聚体为环张力极小的大环化合物。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新