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Three alicyclic dianhydrides, 1,2,3,4-cyclobutanetetracarboxylic dianhydride, 1,2,4,5-cyclopentanetetracarboxylic dianhydride, and 1,2, 4, 5-cydohexane tetracarboxylic dianhydride were polymerized with two aromatic diamines, 1,4-bis (4-amino-2-trifluoromethylphenoxy) benzene (6FAPB, a) and 4, 4'-bis(4-amino-2-trifluoromethyl phenoxy) biphenyl (6FBAB, b) respectively, via a two-step polycondensation procedure to afford two series of fluorinated semi-alicyclic polyimides.

分别将脂环族二酐单体1,2,3,4-环丁烷四酸二酐、1,2,4,5-环戊烷四酸二酐和1,2,4,5-环己烷四酸二酐与芳香族含氟二胺1,4-双(4-胺基-2-三氟甲基苯氧基)苯(6FAPB, a)和4,4'-双(4-胺基-2-三氟甲基苯氧基)联苯(6FBAB, b)反应制备两个系列的含氟半脂环族聚酰亚胺,研究了PI薄膜的热性能和光学性能。

The commercial processes of cyclohexane oxidation to cyclohexanone and cyclohexanol generally show many problems, such as low conversion, poor selectivity, complicated technology, high-energy consumption and environmental pollution. So it seems to be of great academic and practical interesting to study and develop highly efficient and environmentally friendly catalytic cyclohexane oxidation processes.

现有的环己烷氧化制环己酮和环己醇生产工艺普遍存在转化率低、选择性差、工艺复杂、耗能大和对环境污染严重等问题,这就使得研究和开发高效、环境友好的环己烷催化氧化工艺具有重要的理论意义和实用价值。

Application of isopentane /cyclopentane foamed rigid polyurethane in refrigerators is introduced.

介绍碳氢发泡新一代替代技术:环戊烷-异戊烷发泡聚氨酯硬泡技术在冰箱生产中的应用情况,并从发泡工艺及性能上与环戊烷发泡体系进行了比较。

Ethylene Oxide and Pentafluoroethane Mixture, with not more

环氧 烷和五氟烷的混合物,环氧烷含量不超过

Using poly (4-merhylpentene-l) as a membrane material and cyclohexane, irich-loroethylene, tetrachloroethylene, mixture of cyclohexane and trichloroethylene or tetrachloro-ethylene as solvents, the solution were cast to form homogeneous dense membranes, and the crystalline properties and surface morphology were investigated by DSC and TEM.

以聚4-甲基戊烯-1为膜材质,分别以环己烷、三氯乙烯、四氯乙烯、环己烷/三氯乙烯及环己烷/四氯乙烯为溶剂,研究了这些溶液浇铸膜的结晶性质和表面形态。结果表明,溶剂对PMP的相对溶解能力和挥发速度同所成膜内PMP的结晶形式和结晶度密切相关;不同溶剂体系的PMP溶液浇铸膜的表面形态也不尽相同。

By means of GC-MS-Ms method, the multiple series of age-related and taxon specific biomarkers are tested in source rocks and oil samples from Liaohe oilfield and Tarim basin, which are hard to be detected by conventional GC-MS method. They are steranes, methylsteranes, Tricyclic and tetracyclic diterpanes, methyl hopanoid alkanes and hexacyclic hopanoid alkanes, etc.

利用色谱-质普-质普方法在辽河与塔里木盆地源岩和原油样品中,检测出了多个系列时代相关及特定种属生物标志物,包括:降胆甾烷系列、甲基甾烷及甲藻甾烷系列、三环二萜烷及四环二萜烷系列、六环蒮烷及甲基藿烷系列等等,这些化合物很难用常规GC-MS形方法检测到。

The present invention concerns the compounds having the formula N-oxides, salts, stereoisomeric forms, racemic mixtures, prodrugs, esters and metabolites thereof, wherein R1 and R8 each are H, optionally substituted C1-6alkyl, C2-6alkenyl, C3-7cycloalkyl, aryl, Het1, Het2; R1 may also be a radical of formula (R11aR11b)NC(R10aR10b)CR9-; t is 0, 1 or 2; R2 is H or C1-6alkyl; L is -C-,-O-C-,-NR8-C-,-O-C1-6alkanediyl-C-,-NR8-C1-6alkanediyl-C-,-S2-,-O-S2-,-NR8-S2 ; R3 is C1-6alkyl, aryl, C3-7cycloalkyl, C3-7cycloalkylC1-4alkyl, or arylC1-4alkyl; R4 is H, C1-4alkylOC, carboxyl, aminoC, mono- or di(C1-4alkyl)aminoC, C3-7cycloalkyl, C2-6alkenyl, C2-6alkynyl or optionally substituted C1-6alkyl; R5 and R6 are H or C1-6alkyl.

本发明涉及右式化合物其N-氧化物、盐、立体异构形式、外消旋混合物、前药、酯及代谢物,其中R 1 及R 8 各是氢、C 1-6 烷基、C 2-6 烯基、C 3-7 环烷基、芳基、Het 1 、Het 2 ;R 1 也可以是式(R 11a R 11b )NC(R 10A R 10b )CR 9 -之基;t是0、1或2;R 2 是氢或C 1-6 烷基;L是-C-、-O-C-、-NR 8 -C-、-O-C 1-6 烷二基-C-、-NR 8 -C 1-6 烷二基-C-、-S 2 -,-O-S 2 -、-NR 8 -S 2 -;R 3 是C 1-6 烷基、芳基、C 3-7 环烷基、C 3-7 环烷基C 1-4 烷基或芳基C 1-4 烷基;R 4 是氢、C 1-4 烷基OC、羧基、氨基C、一-或二(C 1-4 烷基)氨基C、C 3-7 环烷基、C 2-6 烯基、C 2-6 炔基或任选被取代的C 1-6 烷基;R 5 及R 6 是氢或C 1-6 烷基。

The selected process consists of several steps as follows. Firstly, ammonifying the oily mixture of PXA pyrolysis by ammonia or aqueous ammonia, then adding the organic solvent to extra

实验结果表明,合适的分离提纯工艺为:先将裂解产物用氨水氨化、有机溶剂萃取,然后用硫酸酸化11-CUA铵盐水溶液、再将粗品11-CUA于合适介质中结晶,得到高纯度11-CUA晶体;优化工艺条件为:氨化pH值8.0~10.0、温度25-35℃,甲苯为萃取剂,酸化pH值1.5~2.0、温度55-60℃,环己烷为结晶介质,粗品11-CUA在环己烷中溶解温度50~55℃、与环己烷初始质量比4:100、结晶前沉降分层时间10min、结晶温度20℃。

The recent progress in molecular design and synthesis of polyborosilazane precurosors for SiBCN ceramics is reviewed.Especially the borazine modified polyborosilazane,monofunctional borane modified polyborosilazane on side chai...

本文分4个方面,即基于硼吖嗪的聚硼硅氮烷、侧基含有环硼氮烷或单硼烷的聚硼硅氮烷、基于多官能硼烷构筑的聚硅氮烷和含硼聚硅基碳化二亚胺,从聚硼硅氮烷分子结构设计、改性、合成及在多维尺寸材料中初步应用的角度综述了该领域国内外研究的新进展,指出了聚硼硅氮烷陶瓷前驱体设计合成研究发展中值得关注的新方向。

The invention relates to a continuous method for the intermediate separation of the oxirane produced by the reaction of a hydroperoxide with an organic compound, characterised in that the product mixture generated during the synthesis is separated in a partition-wall column into a low-, middle and high-boiling fraction and the oxirane is taken off with the middle-boiling fraction at the side tap point of the column and the hydroperoxide is taken off with the high-boiling fraction from the bottom of the column.

一种对在环氧烷合成中通过氢过氧化物与有机化合物反应形成的环氧烷进行中间分离的连续方法,其中在隔离壁塔中将该合成中形成的产物混合物分馏得到低沸点馏分、中间沸点馏分和高沸点馏分,并在侧线采出处从中间沸点馏分中取出所述环氧烷,在该塔的底部从高沸点馏分中取出所述氢过氧化物。

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As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸,那乌黑、忧郁的眼睛,她便会相信,他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失

But because of its youthful corporate culture—most people are hustled out of the door in their mid-40s—it had no one to send.

但是因为该公司年轻的企业文化——大多数员工在40来岁的时候都被请出公司——一时间没有好的人选。