环烷

The results showed that molar ratio of cyclohexanone to ethylene glycol was 1∶1.4, the amount of catalyst was 2% cyclohexanone, amount of cyclohexane was 10 mL, the reaction time 2 h, the yield of cyclohexanone ethylene ketal reached 99.6% under the optimum condition.

通过正交实验得出了最佳反应条件：n∶n=1∶1.4、催化剂用量为环己酮质量的2%、带水剂环己烷用量10.0 mL、反应时间2 h，缩酮产率可达99.6%。

The macrocyclic polyamines are a kind of excellent ligands and have a substantially high binding affinity with transition metal ions. Macrocyclic polyamine metal complexes as enzyme models are widely used in chemical biology, medicine and gene therapy. 1, 4, 7, 10-tetrazacyclododecane is a representative macrocyclic polyamines compound and shows high binding affinity with transition metal ions, such as Zn, Cu and Co. Their metal complexes especially multinuclear complexes were widely used in DNA, RNA recognition.

大环多胺化合物是一类性质独特的优秀配体，具有良好的金属配位能力，其金属配合物作为人工酶模型广泛应用于核酸结构及功能研究、基因表达与调控、抗癌药物的研制等生物、化学和医学领域。1，4，7，10-四氮杂十二烷是典型的大环多胺化合物，对过渡金属离子Zn， Cu and Co有良好的配位能力，这些金属配合物特别是多核金属配合物被广泛应用于DNA识别中。

Then peracetic acid was employed as oxidant to prepare POSS-epoxide and the epoxy value can be controlled by reaction temperature.

而后，又以过氧乙酸为氧化剂，制备了带有环氧基团的多面体低聚硅倍半氧烷分子，并可通过反应温度控制其环氧值。

Seven of them have not been reported.Their structures were confirmed by IR,~1HNMR,MS,and element analysis. 4.Meanwhile,the green methylation procedure of imides was developed by using dimethyl carbonate as methylation reagent.A series of imides,for example,phthalimide,3,4-dibromo-maleimide and succincide were used for substrates.The effects of DABCO(1,4-diazabicyclo [2.2.2]octane)and DBU(1,8-diazabicyclo[5.4.0]undec-7-ene)as a catalyst in this kind of reactions were investigated.2-Bromo-3-(1-methylindolyl-3-yl)-1-methyl-1H-pyrrole-2,5-dione was prepared by using dimethyl carbonate,which further expanded the use of dimethyl carbonate,as a green agent in organic synthesis.

在以硫酸二甲酯为甲基化试剂对3，4-二溴马来酰亚胺进行N-甲基化反应合成3，4-二溴-N-甲基马来酰亚胺的同时，以碳酸二甲酯为甲基化试剂，对3，4-二溴马来酰亚胺、邻苯二甲酰亚胺、琥珀酰亚胺等酰亚胺类化合物的N-甲基化反应进行了研究；考察了1，4-二氮杂双环[2.2.2]辛烷，1，8-二氮杂双环[5.4.0]十一碳-7-烯、碳酸钾和四丁基溴化铵等作为催化剂对碳酸二甲酯N-甲基化反应的反应时间和收率等的影响，并应用碳酸二甲酯为甲基化试剂，合成了N-甲基-3-溴-4-(1-甲基-吲哚-3)-马来酰亚胺。

A series of new DB21C7 derivatives with straight arm chains (crown 1 ~ 20) were firstly synthesized, and a thorough and systematic study about the influence of side arms which containing different length polymethylene and certain functional groups on extraction capacity of the parent DB21C7 was made.

本文利用DB21C7中苯环的活性，通过苯环上的亲电取代反应，首次设计合成了二苯并-21-冠-7桥连的二酮、直链烷烃、二醇、二酮酸、二烷酸以及二酰胺，共20个DB21C7取代衍生物，并以IR、~1H NMR、MS和元素分析进行了表征。

This work is mainly concerned with molecular magnetism of polynuclear complexes and supramolecular crystal engineering.

本论文围绕多核配合物的分子磁学和超分子晶体工程这两个最为活跃的前沿研究领域，选用大环配体tacn（1，4，7-三氮杂环壬烷）和含有外延桥的双草胺。。。

The measurement of apparent volume change is described during cure reaction of a new spiro ortho -carbonate, 3, 9, di (p-methooxybenzyl)- 1, 5, 7, 11-tetraoxspiro (5,5) undecaneand epoxy resin, and the volume expansion ratio of this new monomer is culcu-lated,and its applications are approached.

叙述了新的螺环化合物3，9-二-1，5，7，11-四氧杂螺环[5，5]十一烷与环氧树脂进行固化反应时，其表现体积变化率的侧定方法，推算了这种新单体的体积膨胀率。

An expansion monomer 3, 9-dihydroxymethyl-di (6-methyl-5 -hydroxyl)-2- heptanone-1, 5, 7, 11tetraoxaspiro [5, 5] undecane was synthesized and its volume change during polymerization is about +3.04%. Its prepolymer was also synthesized by toluene 2, 4-diisocyanide with it.

由三经甲基丙烷合成了螺环原碳酸酯单体3'、9'－二羟甲基－3'，9'-二乙基－1，5，7，11－-四氧杂螺环[5、5]十一烷单体（体积膨胀率＋3.04%）以及它的预聚物，并用其来改性环氧树脂B-63。

Quantum chemical method was employed to investigate the mechanism of the reaction catalyzed by acid.

在此条件下环己酮的转化率和主产物2-羟甲基-1，4-二氧杂螺环[4， 5]癸烷的选择性分别为99.5%和98.5%。

Smells caused from the burning of cyclohexane saponification waste alkali liquor in the cyclohexanone production and fouling of the evaporator are analyzed.

分析了环己酮生产环己烷皂化废碱液焚烧排放烟气时有臭味及蒸发器列管严重结垢的原因和机理。

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失