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Mechanism of rearrangement of semipinacone and cycloheptane cation were studied with HF method and STO-3G~* basis set.

用哈特里-福克方法、STO-3G*基组,分别对半片呐醇和环庚烷正离子的重排机理进行了从头算研究,计算了半片呐醇和环庚烷正离子重排过程中的各个状态的几何构型、零点能,同时对反应路径进行了计算。

Study on rearrangement of semipinacone and cycloheptane cation with ab initio method;2. Mechanism of rearrangement of semipinacone and cycloheptane cation were studied with HF method and STO-3G~* basis set.

用哈特里-福克方法、STO-3G*基组,分别对半片呐醇和环庚烷正离子的重排机理进行了从头算研究,计算了半片呐醇和环庚烷正离子重排过程中的各个状态的几何构型、零点能,同时对反应路径进行了计算。

To enable the fabrication of a thermally stable ultralow dielectric constant film, specific precursor materials are used, such as, silane derivatives, for instance, diethoxymethylsilane and organic molecules, for instance, bicycloheptadiene and cyclopentene oxide.

为了制造热稳定的超低介电常数膜,使用特殊的前体材料,如硅烷衍生物例如二乙氧基甲基硅烷和有机分子例如双环庚二烯和环戊烯氧化物。

This paper is studied on a new synthesis method of amino-modified organic silicone micro-emulsion of cationic style by one step with a silane-alkyl coupling,3-(2-aminoethyl)-aminopropyl methyl dimethoxy silane while opening-cyclo polymerization of the octa-methyl cyclo tetra siloxane,thus the optimal manufacturing conditions are determined by comparing test of their properties.

采用硅烷偶联剂氨乙基氨丙基甲基二甲氧基硅烷改性,八甲基环四硅氧烷开环聚合,探索一步合成阳离子型氨基改性有机硅微乳新方法,通过其性能测试得出其最佳工艺条件:反应温度:80℃,反应时间:3 h,十六烷基三甲基溴化铵用量:5%,脂肪醇聚氧乙烯醚用量:5%,预乳液滴加时间:2 h。

The molecule of taxol is an extremely complex diterpene with a taxane ring structure fused with a four-membered oxetane ring, an ester side-chain at position C-13 and a benzoyl side-chain at the C-2 position Fig.

紫杉醇分子是一个极其复杂的四环二萜类化合物:一个紫杉烷环加一个四个元素组成的氧烷环,在C-2和C-13上还分别有一个苯氧基和酯基侧链。

Dihydrojasmone was synthesized from2-hexyl-5-methyl-1,2-oxaborolane,prepared frommethyl vinyl ketone and hexene,via the homologationwith 〓 followed by PCC oxidation and intra-molecular condensation.In stead of the oxidation ofthe C-B bond of 1,2-oxaborolane,fluoride inducedhalogenation of 2-alkoxy-1,2-oxaborolane was found togive 3-halopropanol.

硼氢化甲基乙烯基酮和已烯得到的2-已基-5-甲基-1,2-氧硼杂环戊烷与〓反应,再经PCC氧化,分子内缩合得到二氢茉莉酮。1,2-氧硼杂环戊烷的C-B键除氧化断裂之外,也能够在〓或KF作用下卤化断裂成碳卤键。

A process for preparing clean gasoline features that under existance of epoxidizing catalyst and alkoxylating catalyst, the olefine in gasoline and the oxygen and alcohol take part in epoxidizing and alkoxylating reactions to generate diolmonoether or dioldiether compounds which has higher octane number, so being excellent gasoline component.

本发明公开了一种清洁汽油的生产方法,在一个具有环氧化的催化剂以及同时具有烷氧化催化组分或者催化剂的存在下,汽油中的烯烃与氧、醇、发生环氧化、烷氧基化反应而生成二醇单醚或二醇双醚类化合物,这类化合物具有较高的辛烷值,是优良的汽油组分。

When a solution of cis-1-t-butyl-4-chlorocyclohexane in ethanol is refluxed for several hours, the major product is found to be trans-1-t-buty1-4-ethoxycyclohexane.

答:顺-1-t-丁基-4-氯环己烷在ethanol中回流几小时主要产物得到反-1-t-丁基-4-乙氧基环己烷。

ASpheric FeNi nanoparticles with average diameter of about 70 nm were obtained in the system of cetyltrimethyl ammonium bromide/H_2O,while most of the products were nanofilms/rods with the addition of cyclohexane; nearly monodisperse FeNi nanoparticles with average diameter of about 25 nm were prepared in the system of PEG/cyclohexane/H_2O.With the assistance of ultrasonic,a no-surfactant method to 8.5 nm FeCo nanocrystals with high Ms(>200.5 emu/g)has been developed with economical FeCl_3·6H_2O as iron sources.

a以水合肼为还原剂在十六烷基三甲基溴化铵/H_2O体系中得到了平均粒径约70 nm的FeNi合金球形颗粒,当在此体系中加入环己烷时样品主要形态为纳米膜/棒;于PEG/环己烷/H_2O体系中制备了单分散性较好的平均粒径约25 nm的FeNi合金纳米颗粒,合金纳米颗粒粒径随金属离子浓度减小而减小。

Ethylene Oxide and Dichlorodifluoromethane Mixture, with not

环氧 烷和氧化碳的混合物,环氧烷含量超过9%,但不超过87% 1041

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As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸,那乌黑、忧郁的眼睛,她便会相信,他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失

But because of its youthful corporate culture—most people are hustled out of the door in their mid-40s—it had no one to send.

但是因为该公司年轻的企业文化——大多数员工在40来岁的时候都被请出公司——一时间没有好的人选。