环烯

Recently, we have detailed a new series of furan-containing teraryl cyclophene derivatives 40a-f and 67. And two keys to syntheses were one-pot furan annulation and the McMurry reaction.

过去我们已成功地利用呋喃成环反应，与McMurry反应合成到一系列的含呋喃之[n.2]环芃烯40a-f与环芃双烯67。

Ophenyl phenol,ophenyl phenol sodium salt tetrahydrate,7ADCA,2ethyl phenyl hydrazine hydrochloride,2,3dihydrofuran,7ethyl3(2hydroxy ethyl)indole,methyl ester of etodolac; 1,8diethyl1,3,4,9tetrahydropyrano[3.4b] indole1acetic acid methyl ester,5chloro2methoxy benzoic acid,4(2aminoethyl)benzene sulfonamide,5cyano phthalide,phthalhydrazide,9thioxanthenone,n[(1,4benzodioxane2yl)carboxyl]piperazine HCL,2chloro4amino6,7dimethoxyquinazoline,2chloro benzimidazole,1(4fluorobenzyl)2chlorobenzimidazole,2methylthio4pyrimidone,5amino4imidazole carboxamide HCL,6chloro2hexanone,11oxo6.11hydrodibenzothiepin,6,11dihydrodibenzooxepin11one,10,11dihydrodibenzocyclohepten5one;dibenzosuberone,dibenzo cyclohepten5one;dibenzosuberenone,3,5dihydroxy benzoic acid,3,5dihydroxy benzyl alcohol,2mercapto benzimidazole,3,4dihydroxy benzaldehyde,3,4dihydroxy benzonitrile,2amino5chloro benzonitrile,2(4chlorophenoxy)ethyl chloride,2(4chloro phenoxy)tert,butane,ditrimethylol propane;DTMP,2,2bis(4hydroxyphenyl)butane; bisphenol B,1,1'bis(4hydroxyphenyl)cyclohexane;bisphenol Z,tetrabromobisphenolS,3,5ditertbutyl salicylic acid,3,4,5trihydroxy benzoic acid stearyl ester,1,2,4trimethoxybenzene.

华业公司产品：邻苯基苯酚，邻苯基苯酚钠盐，7氨基3去乙酰氧基头孢烷酸，邻乙基苯肼盐酸盐，2，3二氢呋喃，7乙基色氨醇，依托度酸甲酯，5氯2甲氧基苯甲酸，4(2氨乙基)苯磺酰胺，5氰基苯酞，双酮酞嗪，9噻吨酮，N〔(1，4苯并二恶烷2基)羰基〕哌嗪盐酸盐，2氯4氨基6，7一二甲氧基喹唑啉，2氯苯并咪唑，1(4氟苄基)2氯苯并咪唑，2甲硫基4嘧啶酮，5氨基咪唑4 甲酰胺盐酸盐，6氯2已酮，11氧6.11二氢苯并〔b.c〕虑平，11氧代6，11二氢二苯并氧杂卓，10，11二氢二苯并环庚烯5酮，二苯并环庚烯5酮，3，5二羟基苯甲酸，3，5二羟基苯甲醇，2巯基苯并咪唑，3，4二羟基苯甲醛，3，4二羟基苯腈，2氨基5氯苯腈，2(4氯苯氧基)1氯乙烷，2(4氯苯氧基)叔丁烷，双丙烷，2，2二(4羟基苯基)丁烷；双酚B，1，1'双(4羟基苯基)环己烷；双酚Z，2[3，5二溴4(2，3二溴丙氧基)]苯砜，3，5二叔丁基水杨酸，3，4，5三羟基苯甲酸十八烷基脂，1，2，4三甲基氧基苯。

Compareing with essential oil of the steam distillation method and the bensine solvent extraction method through GC-MS analysis .The result showed that:the essential oil principal constituent extracted by benzine is camphene,a-pinene,bornyl acetate, limonene, 1-methyl-4-(1-methylethyl)-1,4-cyclohexadiene, myrcene, caryophyllene, borneol.

对巴山冷杉针叶水蒸气蒸馏和石油醚萃取所得精油的GC-MS 分析对比研究结果表明：石油醚萃取精油主要成分为：莰烯，a-蒎烯，乙酸龙脑酯，柠檬烯，1-甲基-4-异丙基-1，4-环己二烯，月桂烯，石竹烯，龙脑。

A novel monomer the 1-methyl-4,5-bis(4-chlorobenzoy) cyclometer containing cyclohexene were prepared,so a group of novel polys containing the cyclohexene and phthalazinone moieties was prepared by the nucleophilic displacement reaction of 1-methyl-4,5-bis(4-chlorobenzoyl) cyclohexene and 4,4′-dichlorodiphenyl sulfone and 4-(3,5-dimethyl-4-hydroxyphenyl)-2,3-phthalazin-1-one.

用新型聚合单体1-甲基-4，5-二(4-氯代苯甲酰基)环己烯与4-(4-羟基苯基)-2，3-二氮杂萘-1-酮、4，4′-二氯二苯砜单体经亲核共缩聚反应，成功地合成了含环己烯结构的杂环联苯型聚醚系列聚合物。

A novel monomer the 1-methyl-4,5-bis (4-chlorobenzoy) cyclometer containing cyclohexene were prepared,so a group of novel polys containing the cyclohexene and phthalazinone moieties was prepared by the nucleophilic displacement reaction of 1-methy l-4,5-bis(4-chlorobenzoyl) cyclohexene and 4,4'-dichlorodiphenyl sulfone and 4-(3,5-dimethyl-4-hydroxyphenyl)-2,3-phthalazin-1-one.

用新型聚合单体 1-甲基-4，5-二(4-氯代苯甲酰基)环己烯与 4-(4-羟基苯基)-2 ，3-二氮杂萘-1-酮、4，4′-二氯二苯砜单体经亲核共缩聚反应，成功地合成了含环己烯结构的杂环联苯型聚醚系列聚合物。

By the mechanism of the electrocyclic reaction, three groups of 4-hydroxy-2-cyclobutenones 4 were designed and synthesized to investigate their behaviors underthe thermolysis conditions Meanwhile, a new procedure for preparation of 2(5H)-furanone 5 Was discovered.

根据电环化反应机理，我们设计了三组不同类型的4-羟基-2-环丁烯酮(4)。通过对4-羟基-2-环丁烯酮(4)进行热解，发现了一种制备2(5H)-呋喃酮类化合物(5)的新方法。

An alicyclolic epoxy resin with endocyclic structure,namely hydrogenated terpinene-maleic ester type epoxy resin, was synthesized from the raw material hydrogenated terpinene-maleic anhydride.

以氢化萜烯马来酸酐为原料与环氧氯丙烷反应合成一种含桥环结构的饱和脂环基环氧树脂——氢化萜烯酯型环氧树脂。

Other methyl nucleophiles includingMeMgBr, MeCeCl2, MeTiCl3, Me3Al, Me3ZnMgCl, MeMnClwere tried, but in all these cases no detectable amount of exo-C8-methylated product was obtained. Although protecting C3-carbonyl as 1,3-dioxolanes could be achieved, the serious enolization of C8-carbonyl was still problematic. Converting C9-furan ring to α,β-butenolide did depress the enolization, but desired C8-methylation was completely replaced by migration of the double bond of the butenolide.

在本论文的早期阶段，主要着眼于解决二环[3.2.1]-C8-羰基加成甲基所遇到的C9-呋喃环差向异构化和C3与C8两个羰基之间化学选择性的问题：通过引入不同金属降低甲基试剂的碱性并没有取得甲基化的成功；通过不同的方法将C3-羰基掩蔽，但是C8-羰基的烯醇化依然无法抑制；虽然通过将呋喃环转化为α，β-不饱和-γ-丁内酯可以抑制烯醇化，但内酯环上的双键迁移又成了新的竞争反应。

Synthesis with carbocyclic compounds, such as cyclodienylsilane, quinic acid and norbornene etc, as starting materials is discussed in detail.

重点介绍了以环二烯基硅烷、奎宁酸、降冰片烯等碳环化合物为原料合成碳环糖的进展。

Bromo-2-sulfolene (2) reacted with substituted benzoic acid salt s 3a～3c or alizarin yellow (3d) to give four novel allylic substitution products 4a～4d by esterification reaction, respectively.

以3，4-二溴环戊砜(1)为原料，在无水吡啶作用下发生消除反应，得到反应中间体4-溴-2-环戊烯砜(2)，再分别与一系列取代苯甲酸盐3a～3c以及茜素黄GG(3d)发生酯化反应，合成出4种新环戊烯砜衍生物4a～4d，并用IR，1HNMR，MS，元素分析等表征了它们的结构。

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失