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Methods The target compounds were synthesized from cyclopentanone via Stork reaction, Mannich condensation, amine exchange and selective reduction. Xylene-induced mice ear edema assay was used to evaluate their anti-inflammatory activity.

以环戊酮为起始原料,通过Stork烯胺反应、Mannich缩合反应、胺交换反应和选择性还原制备目标化合物;以二甲苯致小鼠耳肿胀模型测试目标化合物的抗炎活性。

Methods The target compounds were synthesized from cyclopentanone via Stork reaction, Mannich condensation , amine exchange and selective reduction. Xylene-induced mice ear edema assay was used to evaluate their anti-inflammatory activity.

以环戊酮为起始原料,通过Stork烯胺反应、Mannich缩合反应、胺交换反应和选择性还原制备目标化合物;并以二甲苯致小鼠耳肿胀模型测试目标化合物的抗炎活性。

The main compositions of LP are shorter chain carboxylic acid and their ethyl esters, furan derivatives, cyclopentanone, phenol derivatives, benzene derivatives, aromatic ketone, aromatic acid derivatives, longer chain carboxylic ethyl esters and sterides. After upgrading, the main indexes reach the standard of fuel oil.

结果表明,LP的主要成分包括短链或环状脂肪酸及其酯、呋喃衍生物、环戊烯衍生物、苯酚衍生物、苯衍生物、芳酮、芳酸及其乙酯、长链脂肪酸乙酯和甾族化合物,经提质其主要指标达到了燃料油的标准。

A novel one-step green process for synthesis of glutaric acid by selective oxidation of cyclopentene was investigated.

研究了以环戊烯为原料、草酸为有机络合剂、H2O2为氧化剂,在催化剂钨酸(H2WO4)的作用下一步合成戊二酸的绿色新过程,考察了氧化剂的含量、反应物配比、催化剂用量、反应温度、反应时间等对反应的影响。

The present invention belongs to the field of chemical technology, and is a kind of supported tungstic acid catalyst for multiphase catalytic oxidation and synthesis of glutar aldehyde from cyclopentene.

本发明属于化工技术领域,是一种新型的环戊烯多相催化氧化合成戊二醛的负载型钨酸催化剂。

The method of one-step cyclopentene oxidation with hydrogen peroxide as oxidizer is the trend of research and development of glutaraldehyde in the future because its raw materials are cheap and easy obtainable.

指出吡喃法是目前国内外合成戊二醛普遍采用的方法,以过氧化氢为氧化剂的环戊烯一步氧化法具有原料价廉易得等特点,是今后研究开发的方向。

Glutaraldehyde was prepared by oxidation of cyclopentene with aqueous solution of hydrogen peroxide.

用过氧化氢水溶液氧化环戊烯制得戊二醛。

Under the optimized reaction conditions: n (H2O2)/n/n=2/0.04/1,V/V=8.75, reaction temperature 35℃, and reaction time 28 h, the highest yield of glutaraldehyde could reached 78% with a cyclopentene conversion of 99.99%.

在最佳工艺条件:n(H2O2):n:n=2:0.04:1,V/V=8.75,反应温度35℃,反应时间28h下,环戊烯转化率达99.99%,戊二醛的收率最高可达78%。

Cyclopentene catalytic oxidation synthesis techniques which had good prospect were introduced with great emphasis,and positive significance of establishing large-scaled chemical plant of glutaraldehyde near the locality of raw material specially in north of China,was pointed out.

着重介绍了前景看好的环戊烯催化氧化合成工艺方法,指出在接近原料产地,特别是中国北方地区建立规模化戊二醛生产装置,具有积极的意义。

Using W-HMS molecular sieve synthesized from the tungsten source of (NH4) 2WO4 as catalyst and hydrogen peroxide as oxidant, the effects of reaction time, temperature, dosage of catalyst, solvent type and volume, and oxidant concentration on the catalytic oxidation of cyclopentene to glutaraldehyde were investigated.

对以(NH4)2WO4为钨源合成的W-HMS分子筛为催化剂,过氧化氢为氧化剂,环戊烯合成戊二醛的多相催化反应进行了研究,考察反应时间、反应温度、催化剂用量、溶剂种类和用量以及氧化剂浓度等因素对戊二醛收率的影响。

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