环烯

Components were identified which represented 85.1% of the total essential oil by the silica gel column separately.Conclusion 10 components were identified which included Bicyclo (6,3,0) undeca-dien-3-one, 5,5-dimethyl ect. of the essential oil from Angelica acutiloba Kitag were analyzed for the first time.

结果超临界CO2萃取物为黄棕色油状物，得率为0.9%，用GC-MS联用技术从中鉴定出亚油酸乙酯、5，5-二甲基-双环（6，3，0）-1，7-十一烯-3-酮等30种成分，占挥发油总含量65.66%；萃取物经硅胶柱色谱分离纯化，从中鉴定出十八酸乙酯等11种成分，占总含量的85.1%。

Components were identified which represented 65.66% of the total essential oil includding 9.12-octadecadienoic acid, ethyl ester and ect. 11 components were identified which represented 85.1% of the total essential oil by the silica gel column separately.conclusion 10 components were identified which included bicyclo (6,3,0) undeca-dien-3-one, 5,5-dimethyl ect.

结果超临界co2萃取物为黄棕色油状物，得率为0.9%，用gc-ms联用技术从中鉴定出亚油酸乙酯、5，5-二甲基-双环（6，3，0）-1，7-十一烯-3-酮等30种成分，占挥发油总含量65.66%；萃取物经硅胶柱色谱分离纯化，从中鉴定出十八酸乙酯等11种成分，占总含量的85.1%。

In the same time, water-soluble bidental phosphines ligand BISBIS sulfonated 2,2''-bis(diphenylphosphinomethyl-1,1''-biphenyl was synthesized, and water-soluble rhodium complex Cl was synthesized in situ. This complex which was used as catalysts to catalyze the hydrogenation of avermectin was also tested. Although the rhodium complex containing bidentate phosphine BISBIS showed a higher catalytic activity than one containing TPPDS, the selectivity for ivermectin was lower. How to improve the selectivity will be needed to studied in futur.

同时我们用磺化的2，2''-二-- 1，1''--联苯，以及它们的水溶性威尔金森型铑配合物和环辛二烯的阳离子铑配合物，在利用这些配合物作催化剂，考察它们在各种反应条件下对阿维菌素的选择加氢，由于反应条件以及复合催化剂体系的组成还需要进一步优化，虽然双齿膦配合物显示了较高的活性，然而选择性还有待进一步提高。

Three kinds of CpTiCl had been synthesized when was catechol , 2, 2′-biphenol , or 2, 2′-binaphthol , respectively. In the case of CpTiCl〓, was 8-hydroxylquinoline , 2-methyl-8-hydroxyl-quinoline , and 8hydroxyl-5-nitro-quinoline , respectively.

研究表明，这三类半茂钛配合物在助催化剂MAO作用下，于30℃、0.1MPa乙烯压力下均可催化乙烯聚合，并显示较高的活性，远高于未引入非茂配体的CpTiCl〓及不含茂环的相应非茂配合物的活性，这说明同时含一个茂配体和一个非茂配体的半茂配合物是烯烃聚合的优良催化剂。

Methyl-2,3,5,6-tetrafluoro-benzene methanol was synthesized by chlorination, acylation, fluorination, esterifica- tion, reduction, bromization, reduction from terephthalic acid. Tefluthrin was obtained from-(1RS,3RS)-3-(2-chloro-3,3,3-trifluoro-1-propenyl)-2,2-dimethyl cycolpropa-necarboxylate acid by reacting with 4-methyl-2,3,5,6-tetrafluoro-benzene methanol.

以对苯二甲酸为原料，经氯化、酰氯化、氟化、酯化、还原、溴化、还原七步反应合成了4-甲基-2，3，5，6-四氟苄醇，甲基苄醇与-(1RS，3RS)-3-(2-氯-3，3，3-三氟丙-1-丙烯基)-2，2-二甲基环丙甲酸一步酯化合成了七氟菊酯。

Titanium silicalite 1(TS 1)with different crystal size s were synthesized in the system of TPABr n butylamine by adjusting the formation of gel and the method of crystallization.

在四丙基溴化铵正丁胺体系中合成不同晶粒大小的TS 1沸石，采用IR、XRD UV Vis、SEM、2 7AlMASNMR对其进行表征，并以丙烯环氧化反应为探针考察其催化性能。

The result indicates that those four resuscitation-inducing aromatic herbs mainly contain volatile oil ,and all contain alicyclic compounds; the volatile oil of Borneolum Syntheticum and Styrax both contain Sesquiterpenes of caryophyllene; as resin herbs , Styrax and Benzoinum both contain vanillin, resin ester and balsamic acid .

结果表明，四味芳香开窍药主含挥发油，均含有脂环化合物，并存在一些共有成分，如龙脑冰片与苏合香挥发油中均含有倍半萜类成分石竹烯；苏合香和安息香皆为树脂类中药，两者均含有香荚兰醛成分，尚含树脂酯，香脂酸等。中国论文联盟http：//www.lwlm.com

Mimetic peroxidase of high catalytical activity and selectively is very important in bio-analytical field.

建立一系列关于这些酶的模拟体系将为以下三个方面的研究工作提供非常重要的工具：（1）工业或者精细化工方面重要反应新型催化剂的开发，例如烷烃的选择性氧化以及具有立体选择性的烯烃环氧化；（2）新的生物活性物质，例如药物的氧化机理的研究和预测；（3）具有合适底物的高活性过氧化物酶模拟酶在生化分析领域的前景。

The elaboration of systems that are able to mimic those enzymes should provide very important tools for three main purposes:(1) the development of new catalysts for important reactions in industrial and fine chemistry, such as the selective oxidation of alkanes and the stereoselective epoxidation of alkenes;(2) the prediction of the oxidative metabolism of new biologically active molecules such as drugs.(3) mimetic peroxidase of high catalytical activity and selectively is very important in bio-analytical field.

建立一系列关于这些酶的模拟体系将为以下三个方面的研究工作提供非常重要的工具：（1）工业或者精细化工方面重要反应新型催化剂的开发，例如烷烃的选择性氧化以及具有立体选择性的烯烃环氧化；（2）新的生物活性物质，例如药物的氧化机理的研究和预测；（3）具有合适底物的高活性过氧化物酶模拟酶在生化分析领域的前景。

In this thesis, several novel reaction-controlled chiral phase-transfer catalysts were designed and synthesized from readily available materials, and were used in the asymmetric epoxidation of unfunctionalized olefins and chalcone.

本文以有机合成方法学为目标，从廉价的原料出发，合成出几个新的反应控制的手性相转移催化剂，并且检验了他们在催化烯烃的不对称环氧化中的催化效果。

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。