环烯

There are many reports related to the synthesis of azelaic acid, such as oxidation of oleate with nitric acid or ozone (9); oxidation of castor oil with potassium permanganate (10), as well as some other synthetic methods using 1, 9-nonadialdehyde〔11〕or 1,5-cyclooctadiene 〔12〕as the materials.

有关壬二酸合成的研究报道很多，例如用硝酸或臭氧氧化油酸〔9〕；高锰酸钾氧化蓖麻油〔10〕以及以1，9-壬二醛〔11〕、1，5-环辛二烯为原料〔12〕等方法制得。

A compound 2-(3-hydroxyphenyl)[60] fullerene pyrrolidine was synthesized by the 1,3-dipolar cycloaddition reaction of the fullerene(C60) and azomethine ylide (prepared from glycine and 3-hydroxybenzaldehyde). The product was characterized by UV-Vis,1H-NMR ,FT-IR and MS. The reaction conditions affecting the yields of product were investigated and the optimum reaction conditions with product yield 75%(based on consumed C60) were:molar ratio of C60∶3-hydroxybenzaldehyde:glycine 1∶3∶6,reaction temperature 95℃,reaction time 18h.

利用甘氨酸和3-羟基苯甲醛与C60发生1， 3-偶极环加成反应，合成分离得到了2-(3-羟基苯基)[60]富勒烯吡咯烷，用UV-Vis、1H-NMR、FT-IR、MS等测试手段表征了产物的结构，并通过单因素方法，探讨了反应条件对产物产率的影响，得到最佳工艺条件：反应物摩尔比1∶3∶6，温度95 ℃，反应时间18 h，产物的产率可达75%（以消耗的C60计）。

Chapter 4: Synthesis of 1,5-diary 1-1,4-pentadien-3-ones from acetone or benzalacetone with aromatic aldehydes results in 86-97% yield with potassium hydroxide as catalyst under ultrasound irradiation in 5-60min.

为合成氰基环己醇找到一条方便高效的合成方法。第四章：研究了超声辐射下，以氢氧化钾为催化剂，芳香醛与丙酮及亚苄基丙酮之间反应合成1，5-双苄基-1，4-戊二烯-3-酮。

Accordingly, in the original reaction (formation of B from cyclopentadiene and benzoquinone) Diels and Alder found only one of the following six conceivable stereoisomers of B.

因此，在该原始反应中(即通过P-苯醌和过量的环戊二烯生成B)，Diels and Alder发现在他们推测的六个立体异构中，只有一个出现。

Two key compounds butenonitrile and benzothiazole were found.

GC-MS检测解析结果为雪里蕻腌菜的挥发性成分主要为烃、醇、酯、腈及含硫和氮的杂环化合物，其中丁烯腈及苯并噻唑与雪里蕻腌菜的特征风味有关。

This paper studied the catalytic transformation performances of hydrocarbon model compounds (such as n-Hexane,cyclohexane,1-Hexene) and sulfur-containing model compounds (such as thiophene,3-methylthiophene and benzothiophene) on ZSM-5 catalysts.

以正己烷、环己烷、1-己烯3种烃类和噻吩、3-甲基噻吩和苯并噻吩三种硫化物为模型化合物，考察了烃及含硫模型化合物在ZSM-5分子筛催化剂上的催化转化性能。

Various alcohols are tolerable under the present conditions including benzylic alcohols,allylic alcohols as well as simple aliphatic alcohols.

醇的范围非常广，二苯甲醇、1-苯乙醇、烯丙醇衍生物等含苄醇结构的地物能够以最高接近定量的产率得到产物。普通烷基醇如环己醇，甚至最简单的甲醇和乙醇也能顺利反应，产率中等。

Moreover,the selective oxidation of primary and secondary alcohols to corresponding carbonyl compounds with the multinuclear copper complexes Cul-Cu4 as catalysts have been conducted using TBHP and O_2/TEMPO,respectively.Among them,the copper complex Cu3 showed the best performance.On the performances of the two classes of oxidants,benzylic and heterocyclic alcohols could be effectively oxidized to carbonyl compounds.Specifically,the secondary alcohols could be effectively oxidized to ketones with excellent selectivity up to 100%in the presence of TBHP and the allylic alcohols could be effectively oxidized to aldehydes in the presence of O_2/TEMPO system.

实验结果还表明，在TBHP或O_2/TEMPO存在下，各配合物催化剂均能使各种取代芳香伯/仲醇以及杂环醇等以不同程度的转化率和选择性转化成相应的醛或酮，其中，配合物Cu3在O_2/TEMPO存在下可使苯甲醇和烯丙醇等以较高转化率和近100%的选择性转化成相应的醛，而对其它芳香醇和脂肪伯/仲醇等的催化性能则较差；在TBHP存在下，配合物Cu3则可使1-苯乙醇和其它仲醇以较高转化率和近100%的选择性转化为相应的酮，但对各类其它伯醇选择氧化的性能相对较差。

RCM reactions of 49 and 50 are chosen to evaluate the catalytic performance ofthe complexes 46-48 because they are informative and simple to manipulate. The resultsindicated that ruthenium benzylidene complexes 46 and 48 possess significant thermalstability and cyano group tolerance.

由于烯烃49、50的闭环交互置换反应简单、清晰，故用来考察新钌卡宾配合物的催化性能，结果表明配合物46、48具有良好的热稳定性及耐氰基性能。

Several attempts on epoxidation, oxymercuration and dihydroxylation of this bicyclic system were turn out to be unsuccessful.

尝试了环氧化、羟汞化等方法，但没有能够成功将C8-端烯转化成对应的叔醇。

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。