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Seven major methods and their reaction characteristics for the synthesis of primary vicinal diamines starting from epoxides, and alkenes etc.

详细综述了从环氧化合物、烯烃等为起始原料合成一系列一级邻二胺的七条主要路线,并比较了各条反应路线的特点。

The reaction takes place as soon as 3a is dissolved in solution. With the presence of a tethering terminal vinyl group bound to the vinylidene ligand, the [2+2] cycloaddition of two C=C double bonds readily occurred.

当有一乙烯基键结在丙二烯基上,分子内的两个碳碳双键会马上发生[2+2]的环化加成反应。

The present invention relates to a thermoplastic interpolymer product comprising an alpha -olefin interpolymerized with at least one vinyl or vinylidene aromatic monomer and/or at least one hindered aliphatic or cycloaliphatic vinyl or vinylidene aromatic monomer and, in at least one aspect, is characterized as having substantially synergistic thermal properties.

本发明涉及一种包含与至少一种乙烯基或亚乙烯基的芳族单体和/或至少一种受阻的脂族或环脂族的乙烯基或亚乙烯基芳族单体共聚的α-烯烃热塑性共聚体产物,及至少一方面,其特征为具有实质协同热性质。

WARNING: Do not grasp the body of thesyringe because the heat of your hand will cause the cyclopentadiene to volatilize.

警告:不要抓住注射器的躯干,因为你的手所产生的热量会使环茂二烯挥发。

A method to synthsis a - methylene - r - butyrolactones was reported by the substituted (a - carbethoxyvinyl) cuprate intermediates, generated by the addition of higer order cuprate to acetylenic ester,traping with epoxides stereoselectively.

本文报道了通过以高序铜代替低序铜对炔酸酯加成得到的取代铜与端基或环状环氧化合物的立体选择性反应,较高产率的合成α,β-取代烯酯,进而可合成α-亚烷基-γ-丁内酯类衍生物。

The aconitic acid-acrylic acid copolymer, itaconic acid homopolymer and polyepoxysuccinic acid which were non-phosphorus scale and dispersing inhibitors were synthesized with the fermentation products citric acid, itaconic acid and maleic anhydride.

以生物发酵产品柠檬酸和衣康酸为主要原料,分别合成了无磷阻垢分散剂丙烯三羧酸-丙烯酸共聚物和衣康酸均聚物,利用马来酸酐合成了聚环氧琥珀酸。

Various synthetic method of 1,3-propanediol were introduced and compared, including hydration and hydrogenation of acrylaldehyde, carbonylation of epoxy ethane , microbiological fementation, the process starting from methyl aldehyde, etc.

介绍了1,3-丙二醇的几种制备方法,即丙烯醛水合-氢化法、环氧乙烷羰基化法、微生物发酵法和以甲醛等为原料的方法。

4R,5S,6R-5,6-Bis-allyl-6-aldehyde-γ-hexanelactone I-145 was prepared from D-arabinose by six steps. Compound I-145 underwent Mukaiyama-type intramolecular aldolization to produce bicyclooctane I-147 stereospecifically.

我们以D-阿拉伯糖为起始原料,经六步反应,得到(4R,5S,6R)-5, 6-二烯丙氧基-6-醛基-γ-己酸内酯I-145,然后I-145发生分子内的Mukaiyama式aldol缩合反应,完全立体专一性地得到环化中间体I-147。

Also useful are oil-soluble copper dithiocarbamates of the general formula Rc Rd z Cu, where z is 1 or 2, and Rc and Rd are the same or different hydrocarbyl radicals containing from 1 to 18, and preferably 2 to 12, carbon atoms, and including radicals such, for example, as alkyl, alkenyl, aryl, aralkyl, alkaryl and cycloaliphatic radicals.

化学通式为Rc Rd z Cu的油溶性二硫代氨基甲酸铜也适用,式中,z为1或2,Rc和Rd是含1~18(以2~12为宜)个碳原子的相同或不同的烃基,这类烃基的实例包括烷基、烯基、芳基、芳烷基、烷芳基和脂环基。

Also useful are oil-soluble copper dithiocarbamates of the general formula Rc RdzCu, where z is 1 or 2, and Rc and Rd are the same or different hydrocarbyl radicals containing from 1 to 18, and preferably 2 to 12, carbon atoms, and including radical s such, for example, as alkyl, alkenyl, aryl, aralkyl, alkaryl and cycloaliphatic radicals.

通用化学式为RcRdzCu的油溶性二硫代氨基甲酸铜,也非常有用。式中,z为1或2,Rc和Rd是含有1到18个碳原子(最好含有2-12个碳原子)的相同或不同的烃基根,并且包括烷基、链烯基、芳基、芳烷基、烷芳基和环脂基等。

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I didn't watch TV last night, because it .

昨晚我没有看电视,因为电视机坏了。

Since this year, in a lot of villages of Beijing, TV of elevator liquid crystal was removed.

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我比喻得过头了。