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ROMP of DCPD initiated by the well-definined carbene complex RuCl〓 was conducted for the first time. Influence of polymerization conditions was investigated.

首次以结构明确、组分单一的催化剂〓催化双环戊二烯活性ROMP反应,考察了聚合反应条件对反应结果的影响。

Water,glycerin,rosa centifolia flower water,butylene glycol,centaurea cyanus flower water,peg-40 hydrogenated castor oil,propylene glycol,ppg-26-buteth-26,phenoxyethanol,methylparaben,sorbic acid,benzophenone-4,pentadecalactone,citrus aurantium dulcisoil,panthenol,menthyl lactate,sodium hydroxide,glycyrrhiza glabraroot extract,aesculus hippocastanumseed extract,citrus aurantium amaraoil,allantoin,limonnene,linalool,blue 1(ci 42090),yellow 5ci 19140

水,甘油,千叶蔷薇花水,丁烯二醇,矢车菊花水,PEG-40氢化蓖麻油,丙二醇,PPG-26-丁醇聚醚-26,苯氧乙醇,对羟基苯甲酸甲酯,山梨酸,二苯甲酮-4,环十五内酯,甜橙油,泛醇,乳酸孟酯,氢氧化钠,甘草根萃取,七叶树籽萃取,苦橙油,尿囊素,柠檬精油,芳樟醇,蓝,黄水:几乎所有护肤品成分第一位都是水。

And the optimum pH was 4-6 for the dechlorination reaction of 2,4-D, and pH between 2 and 8 were all suited for the reaction in Pd/Fe systems. Intermediate and final products of 2,4-D, HCH and chlordane with Pd/Fe were determined by GC/MS, and the possible dechlorination pathways were concluded: 2,4-D can be converted to phenoxyacetic acid through gradual hydrogenolysis, and HCH can be transformed to cyclohexatriene through dichloroelimination or dehydrochlorination.

通过GC/MS定性定量分析了三种目标污染物在Pd/Fe体系中发生还原脱氯反应过程中的反应物及最终产物,并根据反应产物推测分析了这三种有机污染物在催化还原反应体系中可能的反应途径:2,4-D主要通过逐级氢解最终生成彻底脱氯产物苯氧乙酸;而六六六则可能通过逐步双氯消除反应或脱氯化氢反应,最后生成环己三烯。

At present, the industrial production of PO includes mainly Chlorohydrin process and Halcon process.

在本论文中,利用分子氧为氧化剂在几种银和铜催化剂上进行了丙烯环氧化反应的探索研究。

For developing an immunoassay for multiple residues of pyrethroid pesticides, the hapten N-2- carbanmoyl-(3"-phenoxyphenyl) methyl 3-(2"-Cldoro-3",3",3"-trifluoropropenyl)-2, 2-dimethylcyclopropane- carboxylate was synthesized from cyanohydrin and 3-(2"-Chloro-3",3",3- trifluoropropenyl)-2, 2-dimethylcyclopropanecarboxylic acid via hydrolysis and esterification. The synthesis of the hapten was foundation of preparaing anti- cyhalothrin polyclonal antibodies.

为了制备对单一拟除虫菊酯高特异性的抗体,以菊酸和氰醇为起始原料,通过水解、酯化反应合成了半抗原N-2-氨甲酰-(3-苯氧基苄基)甲基-3-(2-氯-3,3,3-三氟丙烯基)-2,2-二甲基环丙烷羧酸酯,为进一步制备抗三氟氰菊酯的特异性抗体奠定基础。

Finasteride has been facilely synthesized from 4-androstene-3, 17-dione by oxidation, ammoniumation, cyanohydrin, dehydration, Ritter reaction, hydrogenation and dehydrogenation.

本文参考有关文献,以雄烯二酮为起始原料,经氧化开环、内酰胺化、氰醇化、Ritter反应引入叔丁基酰胺、氢化还原、最后氧化脱氢制得非那雄胺。

The research program in our group is mainly on the cyclization of functionalized allenes.

我们小组在官能化的联烯的环化反应方面也作了一些研究。

As the success of benzene partial hydrogenation to prepare cyclohexene developed by Asahi Chemical Industry Co.,Ltd.,cyclohexanol prepared through cyclohexene is...

这一工艺关键是催化剂的设计及选择,因此本文主要对环己烯水合催化剂进行了考察,并进行了反应工艺条件的优化。

The easy recovery of chiral auxiliary, good selectivity and high yield of this reaction make it a potential method in the synthesis of multifunctional optically active cyclopropane derivatives.

手性硫叶立德控制的高对映选择性合成多取代烯基环丙烷衍生物。

Furthermore, a theoretical Molecule-In-Molecule approach was used to rationalize the excited state delocalization pathway of cyclophandiene molecules.

透过分子内分子(Molecule-In-Molecule)的方法,可以进一步解环芃二烯在激发态非定域化的途径。

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