环烯

We researched on the prepartion of pivotal intermediate 2 and 3 for 1 P-methyl carbapenem antibiotics from intermediate 1, which is subjected to Reformastky reaction, N-alkylation, Dieckmann-type cyclisation, enolization, ester condensation etc. in sequence. The synthesis route of document is optimized by us.

我们研究了1β-甲基碳青霉烯类重要中间体的合成，从中间体1出发经Reformastky反应、水解反应合成出中间体2；经Reformastky反应、烷基化、Dieckmann环合、烯醇化、酯化合成出中间体3，并对其中各步反应作了优化和探索。

Totally 17 new type of fulvene ligands have been synthesized by the reaction of substituted-benzoyl chloride with Cp and substituted Cp anions. All the new compounds are fully characterized by infrared spectroscopy,!

我们利用含芳香取代基的环戊二烯丛负离子与含-CN、-I、-CO_2CH_3等配位有机基团的芳酰氯反应成功地合成了17个既含芳香基团又含杂原子配位基团的刚性共轭富烯类配体。

As the results showed that the significant relation between TCBA and calcium or magnesium, mainly between glycocholic, glycochenocholic or taurocholic acids and calcium or magnesium, could be found in all three groups but there was not any obvious relation between TCBA and ferrum or zinc except between glycocholic acid and zinc in gallbladder stone group.

由此可见前列腺素在胆结石形成中占有重要地位。花生四烯酸是合成前列腺素的前体，它在环氧化酶作用下形成前列腺素。本研究证实在成石性胆囊胆汁中花生四烯酸的含量（0.09%）和阳性率（71.74%）明显高于对照组（0.02%，21.42%），P.05。说明成石性胆汁为合成前列腺素提供了前体物质。

Firstly, Copolymerization of acrylamide and styrene was carried out in a microemulsion system, in which AM aqueous solution was the continue phase and St was the dispersed phase using ST-80 as surfactants respectively, then hydroxamic functions were prepared with hydroxylamine salt at temperatures of from 60℃ to 90℃.

首先以丙烯酰胺水溶液为连续相，以苯乙烯为分散相，ST-80为乳化剂制成微乳液，在15℃~35℃合成丙烯酰胺与苯乙烯的共聚物；然后采用程序控温方式，在60℃~90℃用硫酸羟胺将共聚物羟肟化合成了一种带有苯环结构的嵌段型氧肟酸类聚合物材料。

In searching for novel and high active fungicides with pyridyl moiety, with Dimethomorph as a model compound and isonicotinic acid as the main starting material, twenty-seven title compounds were designed and synthesized through chlorination, Friedel-Crafts acylation, Wittig-Horner reaction and other steps. All the target structures were confirmed via 1H NMR and elementary analysis.

为了寻找具有高活性的含吡啶杂环杀菌剂，以烯酸吗啉为模板化合物，以异烟酸为起始原料，通过卤代反应、Friedel-Crafts酰基化反应、Wittig-Homer反应等，将吡啶－4-基或2-氯吡啶－4-基引入到模板结构中，设计合成了27个4-［3-（吡啶－4-基）－3-取代苯基丙烯酰］吗啉类化合物，其结构通过1H NMR和元素分析确证。

The dissertation mainly consists of two parts:1. The Reaction Chemistry of Alkynes under Palladium Catalysis Part 1 studies the reaction α,β-unsaturated carbonyl compounds with alkenylpalladium intermediate generated by nucleopalladation, and discovered 1 the Pd-catalyzed tandem addition reaction of halides, alkynes and α,β-unsaturated carbonyls,2 the four-component tandem addition reaction of halides, alkynes and α,β-unsaturated carbonyls, 3 the tandem intramolecular oxypalladation-conjugate additionreaction of alkynoic acids with α,β-enals. These new reactions provide notonly efficient highly stereoselective methods for the synthesis of γ,δ-unsaturated,polyunsaturated carbonyl compounds and γ-lactonic aldehydes, but also thebasic transformations for a number of C-C bond formation reactions which can be usedto design synthesis of many acyclic, cyclic or polycyclic compounds.

本论文的主要工作分为两个部分：一、钯催化下炔烃的反应化学在本小组前人工作的基础上，我们详细研究了炔烃亲核钯化产生的烯基钯中间体与α，β-不饱和羰基化合物的反应，发现两价钯催化下卤离子-炔烃-α，β-不饱和醛酮的串联加成反应、卤离子-炔烃-α，β-不饱和醛酮的西组分串联加成及炔酸分子内氧钯化-串联Michael型加成反应；由此发展了γ，δ-不饱和醛酮、多不饱和羰基化合物和带有醛酮基侧链的γ-丁内酯衍生物的高立体选择性合成方法，这一过量卤离子存在下的烯基钯对α，β-不饱和羰基化合物共轭加成反应的发现，为大量碳-碳键形成反应的实现提供了基础，使我们能够从这一基本反应出发，设计和开发多种分子内、分子间的碳碳成键反应，以好的立体、区域选择性组建开链、环状及多环类型的化合物。

The DielsAlder reaction of myrcene and acrolein over ZnCl2/NaY prepared by solidstate interaction under microwave irradiation, conventional heating physical mixture, and over ZnNaY prepared by ion exchange in solution was studied.

比较了微波固相法、普通加热法和简单混合法制备的ZnCl2／NaY及溶液离子交换法制备的ZnNaY在月桂烯与丙烯醛DielsAlder反应中的催化性能，发现微波固相法制备的催化剂表现出最高的环加成选择性和区域选择性。

Kinetics characteristics of α- pinene isomerization catalyzed by activated carbon supported phosphotungstic acid was studied .

研究了活性炭固载磷钨酸催化α－蒎烯的异构化反应的动力学特征，研究表明，以环己烷作溶剂，α－蒎烯在活性炭固载磷钨酸上的异构化服从准一级动力学模型，其反应的表观活化能为100。

Pyridazine was prepared by hydrogenolysis of 3,6-dichloro pyridazine obtained via chlorination of 3,6- pyridazine diol with phosphorus oxychloride.

以顺丁烯二酸酐与盐酸肼为原料经缩合成环反应生成顺丁烯二酰肼，再用三氯氧磷氯化合成3，6-二氯哒嗪，最后经催化加氢制得标题化合物哒嗪。

Determination of tartaric acid and maleic acid by high performance liquid chromatography

含有顺丁烯二酸酐与丁二烯或环戊二烯等加成物结构的不饱和聚酯树脂。

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。