环烯

A novel butterfly-shaped fullerene-diporphyrin triad was designed and synthesized,in which 〓 is in the mid of two porphyrin rings and this structure feature enables it to be apotential candidate for the manufacture of Gr〓tzel solar cell and unimolecular logicalcircuit.

设计并合成了一个新的蝴蝶形富勒烯-双卟啉三元分子并确定了结构，两个卟啉环将〓夹在中间，这样的结构有利于探索增加电子／能量给体数目对电荷／能量向富勒烯传递速率的影响，并且这个分子可望被用于太阳能电池制造和单分子逻辑电路的设计上。

Under high dilution,the cross-coupling reactions of 4,5-dicyano-1,3-dithiol-2-one(6) and dithia crown-ether annulated tetrathiafulvalenes(3a～3c) in toluene gave asymmetrical dicyano tetrathiafulvalene derivatives(7a～7c) in the presence of triethyl phosphite.The compounds 7a～7c were characterized by(~1HNMR,EA,MS and IR.

在甲苯溶液中，在亚磷酸三乙酯存在下，采取高度稀释的方法，使4，5-二氰基-1，3-二硫杂环戊二烯-2-酮分别和多缩硫杂冠醚进行交叉偶联反应，成功地得到了不对称的2，3-二氰基四硫富瓦烯衍生物。

In part one, the reactions of some active fluorine-containing compounds such as 2, 2-dihydropolyfluoroalkanoic acids and ethyl 2-hydropolyfluoroalkenoates were studied and various fluorine-containing heterocyclic compounds were synthesized. Using 2, 2-dihydropolyfluoroalkanoic acids as the starting material, 4-fluoroalkyl quinolin-2-ols, 2- [ -1-hydropolyfluoro-1-alkenyl] -4H-3, 1-benzoxazin-4-ones, 1-aryl -4, 9-dihydro-3-fluoro-alkyl-1H-pyrazo [3, 4-b] quinolin-4-ones, 5-fluoroalkyl-12H-quin olino [2, 1-b] quinazolin-12-ones, 4-fluoroalkyl-1, 3-dihydro-1, 5-benzodiazepin-2-ones and 4-fluoroalkyl-2H-pyrido [1, 2-a] pyrimidin-2-ones were synthesized through its condensation reaction with anilines, anthranilic acid, N'-aryl-o-aminobenzamides, o-nitro aniline, o-amino pyridine and their derivatives and the subsequent transformations. 5-Fluoroalkyl isoxazolidines, 3-fluoro-3-fluoroalkylisoxazolidino [4, 3-c] quinolin-4-ones, 3-fluoroalkylisoxazolino [4, 3-c] quinolin-4-ones and 2-aryl-3per fluoroacylindoles were synthesized by inter-and intramolecular 1, 3-dipolar cycloaddition of fluorine-containing olefins and nitrones.

第二部分，我们研究了α，α-二氟苄基卤类化合物的亚磺化脱卤反应、产物的转化及全氟烷基亚磺酸盐与芳环化合物的全氟烷基化反应，发现全氟苄基碘或溴及α，α一二氟苄基溴在保险粉等亚磺化脱卤试剂引发下可生成相应的亚磺酸盐；全氟苄基亚磺酸盐与氯气或溴反应可生成全氟苄基磺酰氯或磺酰溴；在烯烃存在下，全氟苄基碘则与烯烃发生加成反应，生成相应的1：1加成产物；在三价醋酸锰的作用下，部分芳香化合物如茴香醚，二甲氧基苯，吡啶，喹啉等可以和过量的全氟烷基亚磺酸盐发生双全氟烷基化反应，反应表现出一定的区域选择性，产率良好。

Water,c12-20 acid peg-8 ester,octyldodecanol,cetearyl isononanoate,butylene glycol,biosaccaride gum-1,peg-40 hydrogenated caster oil,ethylhexyl menthoxycinnamate,phenoxyethanol,potassium cetyl phosphate,macadamia ternifolia seed oil,dimethicone,carbomer,propylene glycol,glyceryl stearate,cocoglycerides,butyrospermum parkii,c12-13 alkyl lactate,methylparaben,benzophenone-3,pentadecalactone,sorbic acid,citrus aurantium dulcis oil,sodium hydroxyde,tocopheryl acetate,disodium edta,iris germanica root extract,retinyl palmitate,equisetum arvense extract,butylparaben,peg-8,propylparaben,ethylparaben,sodium hyaluronate,chlorhexidine digluconate,citrus aurantium amaraoil,tocopherol,ascorbyl palmitate,citric acid,ascorbic acid,limonene,linalool

水，c12-20 acid peg-8 ester，辛基十二烷醇，鲸蜡硬脂醇异壬酸酯，丁烯二醇，多醣物质，PEG-40氢化蓖麻油，4-甲氧基肉桂酸-2-乙基己基酯，苯氧乙醇，十六烷基磷酸钾，澳洲胡桃子油，地美司康，卡波姆，丙烯乙二醇，甘油硬脂酸，椰油脂酸甘油酯类，牛油果，c12-13烷醇乳酸酯，对羟基苯甲酸甲酯，二苯甲酮-3 ，环十五内酯，山梨酸，甜橙油，氢氧化钠，维生素E醋酸酯，乙二胺四乙酸二钠，鸢尾花萃取，维他命A酯，问荆萃取，对羟基苯甲酸丁酯，聚乙二醇- 8，羟苯丙酯，羟苯乙酯，透明质酸钠，洗必泰葡萄糖酸盐，苦橙油，维生素E ，维生素C棕榈酸酯，柠檬酸，抗坏血酸，柠檬精油，沉香醇水：几乎所有护肤品成分第一位都是水。辛基十二烷醇：界面活性剂、乳化剂、稠化剂，有一定刺激性

Methylpyridine-coordinated ruthenium benzylidene complex 62 shows thehighest catalytic activity. TOF=960 h~(-1) is achieved during RCM reaction of 50, TOF=4 h~(-1)is obtained during the CM reaction of acrylonitrile with 1-decene.

其中，2-甲基吡啶配位的钌卡宾配合物62的催化活性最高，在催化烯烃50闭环交互置换反应时TOF可达960 h~(-1)；催化丙烯腈与1-癸烯交叉交互置换反应时TOF达到4 h~(-1)。

The results showed that:1 78 volatile constituents were identified in the oil,which were mainly caryophyllene,1,5,9,9-tetramethyl-1,4,7-cycloundecatriene,germacrone,eudesmol and furfural,etc.2 The aroma quality and intensity of cigarette were improved,irritation was reduced,and a...

结果表明：①满山红挥发油中共鉴定出78种挥发性成分，主要有石竹烯、1，5，9，9四甲基-1，4，7环十一碳三烯、杜鹃酮、桉叶醇和糠醛等；②该挥发油具有提高B2F和C3F等香气质和香气量，降低刺激性和改善余味的作用。

These results were veryreasonable considering the fact that cyclohexene and 1-octene can not bepolymerized with Ziegler-Natta catalyst.

产物的FD-MS分析结果表明：〓和辛烯-l的加成物为加成数从1到16的混合物；〓和环己烯主要生成加成数为9的加成物。

To establish a method for determination of cyclopentadiene,dimethylformamide and N-methylpyrrolidone simultaneously in isoprene by GC.

用毛细色谱法建立异戊二烯中各组分定性分析方法及环戊二烯，N-甲基吡咯烷酮，N，N-二甲基甲酰胺的测定方法。

In addition to cyclopropanation, the typical Diels-Alder reaction between cyclopentadiene and N-acryloyl-l,3-oxazolidinine-2-one with Ll-L8/metal complexes have also been studied.

对于新配体在Diels-Alder反应中的对映选择性的研究，我们采用环戊二烯与3-丙烯酰基-2-噁唑啉酮的反应。

P-Isopropylphenol was synthesized by catalytic transfer dehydrogenation with 5% Pd/C using 4-isopropylcyclohexenone as the material and the hydrogen offer, industrial dipentene as the hydrogen acceptor and the solvent.

采用5%Pd/C作为转移氢催化剂，4-异丙基环己烯酮为氢给予剂，工业双戊烯为氢接受剂和溶剂进行反应，合成了对异丙基苯酚。

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失