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Three kinds of novel N-heterocyclic carbene allyl palladium complexes (Catalyst 1, 2 and 3) were synthesized. Norbornene polymerizations were carried out using three catalysts activated with methylaluminoxane in toluene.

研究了以3种N-杂环卡宾螯合烯丙基钯配合物1、2和3为催化剂,甲苯为溶剂,甲基铝氧烷为助催化剂催化降冰片烯的聚合。

This invention discloses an intermolecular charge transfer chromogen with triphenylamine group, with a formula indicated by (1), wherein: R1 is hydrogen atom or methyl group or methoxyl group, R2 is hydrogen atom or 2-(5,5-dimethyl-3-vinylcyclohexenyl-2-enylidene)propanedinitrile group.

本发明公开的含三苯胺基团的分子内电荷转移生色团,具有式1所示的结构式,其中R 1 为氢原子或甲基或甲氧基,R 2 为氢原子或2-(5,5-二甲基-3-乙烯环己烯基-2-烯亚基)丙二腈基。

This invention applies mild condition uses substituent group triphenylamine aldehyde or triphenylamine dialdehyde as raw material to react by heating with 2-(5,5-dimethyl-3-vinylcyclohexenyl-2-enylidene)propanedinitrile group to produce the intermolecular charge transfer chromogen with high decomposition temperature, non-coplanar structure, and triphenylamine group.

本发明采用温和的手段,将取代基三苯胺单醛或取代基三苯胺双醛为原料与2-(3,5,5-三甲基环己烯-2-烯亚基)丙二腈共热生成具有高的热分解温度、非共平面空间结构的含三苯胺基团的分子内电荷转移生色团。

Gasolinecontained 67.8% aromatic hydrocarbons, 21.47% olefins and a small quantityof alkanes and cycloparaffin hydrocarbons. The enlarging study on blending feed of vegetable oil and petroleumfraction was performed in a Two-Stage Riser.

通过优化各种因素,植物油的转化率达到81.18%,丙烯产率达到19.52%;汽油的产率为30.58%,其中含有67.87%的芳烃、21.47%的烯烃,以及少量的烷烃和环烷烃,其研究法辛烷值为90.3,抗爆指数为83.9。

Systematic studies on the Hetero-Diels-Alder reaction between the o-Quinone methidesand different enol ether dienophiles for the construction of the spiroketal skeleton was described.

较系统地研究了邻甲基苯醌与不同的烯醇醚亲双烯体之间的Hetero-Diels-Alder反应对螺环缩酮结构的构筑及其应用。

Based on our early work, we will discuss the coupling the Nazarov cyclization-halogenation reaction ofα-alkenoyl ketene dithioacetals under Vilsmeier conditions.

基于以上的研究,本文着重讨论了(来源:ABacC论文cece网www.abclunwen.com)α-烯酰基二硫缩烯酮在Vilsmeier试剂作用下的Nazarov环合反应。

No reactions were observed for reactions of benzodiazepines with ketene atroom temperature; but the reaction of benzothiazepines with monochloroketene gave[2+2] cycloadducts .

发现在室温下苯甲酰基苯并二氮杂卓与烯酮没有反应,而苯并硫氮杂卓与一氯烯酮形成了正常的β-内酰胺环产物。

Effect of reaction parameters such as temperature, propylene pressure, time, catalyst amount etc.

考察了反应温度、丙烯压力、催化剂用量、反应时间等反应参数的影响,找到了较佳的丙烯环氧化反应条件。

The biosynthesis of the quinoid nucleus are the same in all coenzyme Qs. The biosynthesis of the isoprenoid side chain determine the kind of coenzyme Q.

芳香环的合成在所有的辅酶Q族物质中都是相同的,异戊烯基侧链的长度则决定了辅酶Q的种类,这里存在一个关键酶,即异戊烯焦磷酸合成酶。

The auxiliary can be recovered in high yield (81%) only by filtering and recrystallization. Besides, some other aldehydes have been chosen to test the enantioselectivity of N,N\'-dibenzyl tartamide, in comparison with two other allylaborates reagents developed previously by Roush and Brown, respectively. The results show that %e.e. of homoallylic alcohol is superior to that of the former, and approaches the Brown reagent.

产物经S_N2反应得瑞格列萘中间体-甲基烯丙基-2-氯苯基-叠氮甲烷(17);同时,将筛选出的新型手性配体N-苄基酒石酸二酰胺用于其他几种醛(正丁醛,异戊醛和环己醛)的不对称烯丙基化反应,并与广泛应用的Roush配体(22)和Brown配体(27)相比较,发现其立体选择性优于Roush配体,并接近Brown配体,但明显具有可回收利用的优势。

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As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸,那乌黑、忧郁的眼睛,她便会相信,他一定作过不幸的爱情的受害者。

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也许他们将在壶穴里消失

But because of its youthful corporate culture—most people are hustled out of the door in their mid-40s—it had no one to send.

但是因为该公司年轻的企业文化——大多数员工在40来岁的时候都被请出公司——一时间没有好的人选。