环烯

In comparison with acetyl acetate method we found that in the reaction process the concentration of enol-like compound had some effect on the reaction rate.

通过与乙酰丙酮法的比较，认为在反应过程中，成环物质的烯醇型的化合物含量对反应速度有影响，烯醇型的化合物含量越高，反应温度越低。

The production methods of glutaraldehyde,including those of addition reaction of acraldehyde , oxidation of 1,5-pentadiol,reduction of glutaryl chloride and oxidation of cyclopentene,are summarized.

综述了丙烯醛加成、 1，5 -戊二醇氧化、戊二酰氯还原和环戊烯氧化等戊二醛的合成路线和制备方法，考察了目前戊二醛的生产厂家及其在皮革鞣剂、油田注水杀菌剂和医药杀菌等领域的应用市

At present,the main methods to produce epichlorohydrin chlorination are through allyl chloride route at high temperature or allyl alcohol route.

目前，世界上环氧氯丙烷工业的生产方法有两种：氯丙烯高温氯化法和烯丙醇法。

Allyl glycidyl ether was synthesized from allyl alcohol and epichlorohydrin by phase transfer catalysis.

以烯丙醇和环氧氯丙烷为原料，采用相转移催化法，合成了烯丙基缩水甘油醚。

At first,the intermediate of sodium 3-chloro-2-hydroxy propanesulfate was synthesized from epichlorohydrin and sodium bisulfite;And then,using NaOH as a catalyst,the title compound has been synthesized from intermediate and allyl alcohol to reach the yield of about 70%.

先由环氧氯丙烷和亚硫酸氢钠合成中间体3-氯-2-羟基丙磺酸钠，然后中间体再与丙烯醇在氢氧化钠催化下生成目标产物2-羟基-3-烯丙氧基丙磺酸钠。

The yield of allyl glycidyl ether can reach up to 96% at 30 ℃ for 3 h at a molar ratio of 1 to 1.5 of sodium allylate to epichlorohydrin.

醚化反应中固体烯丙醇钠与环氧氯丙烷摩尔比为1：1.5，在无水条件下于30℃反应3 h，烯丙基缩水甘油醚的收率达96%以上。

Excited triplet state of [60]fullerene containing piperidinoxanthate dyad is at 690nm, which has lifetime of 23.7xs in Ar-saturated benzonitrile, whereas that ofparent C60 is at 750nm, with lifetime of 50s, indicating that excited triplet state of

富勒烯C_(60)哌啶黄原酸酯稠合体激发三线态的最大吸收峰在690nm，相对于纯C_(60)发生蓝移用532nm激光激发后，富勒烯C_(60)哌啶黄原酸酯稠合体激发三线态的最大吸收峰在690nm，相对于C_(60)的750nm发生蓝移，在氩气饱和的苯腈中寿命23.7μs，比C_(60)的55μs短，表明环加成反应连接的哌啶黄原酸酯部分具有吸电子性质。

The reaction of cyclic b-keto esters with CF3CO2ZnCH2I provides the corresponding ring-expanded products with the advantage of mild condition in moderate to good yields. A simple and efficient procedure has been developed for a variety of 1,3-diketones converted into the corresponding 1,4-diketones and trans-1,2-disubstituted cyclopropanols in high yields. In conclusion, this new type of organozinc reagents has been developed for many useful reaction in organic synthesis.

利用有机锌试剂所具有的双重特性，在新型的Baylis-Hillman反应中，可以直接与炔基酮和醛反应一锅制得多官能团的三取代的顺式烯；在b-酮酯化合物的扩环反应中，取得了重要进展，得到了增加一个碳的扩环产物，&一步法&合成，反应条件温和、环境友好；在1，3-二酮分子中成功地插入1个碳，合成出1，4-二酮和环丙醇，为现代有机合成提供了新的合成方法，具有良好的应用前景。

Yet, completely differ from the cases of 〓-H, the 〓-dihydroxyl group was introduced after subsequent epoxidation and oxane ring opening of the 〓 tricyclic olefin.

在〓-β-H三环烯31基础上的环氧化和环氧开环反应引入的两个羟基，为双直立的〓，不同于〓类。

In addition, we found that 4-phenyl-l,2,4-triazolinium N-ylides reacted withvarious electron-deficient olefins to afford pyrrole derivatives in good yields via 1,3-dipolar cycloaddition oxidative ring fission, In some cases, tetrahydropyrrolo[1,2-b]triazole and pyrrolo[1,2-b]triazole, which are stable and are not aromatized orcleaved in the reaction conditions, could be isolated, This is a facile and novel route forthe synthesis of pyrrole derivatives.

此外，本文研究了五员三氮杂环化合物4-苯基1，2，4-三氮唑的N-叶立德，发现在氧化剂存在下与缺电子烯烃发生1，3-偶极环加成反应生成的吡咯并[1，2-b]三氮唑，在大多数情况下开环生成吡咯衍生物，反应条件温和，收率良好，是合成吡咯衍生物的一个新的途径。

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失