环烯

We have had the extensive studies on theα-acetyl-α-carbamoyl ketene--acetals and its further applications, for example, their adols condensations with aldehydes giveα-alkenoyl-α-carbamoyl ketene--acetals which can be utilized as the 1,5-bielectronic five-carbon components to react with various binucleophlilic species in a [5+1] annulation.

我们小组在以前的工作中对α-乙酰基-α-胺甲酰基二硫缩烯酮在合成中的应用进行了深入的研究，如与醛缩合生成α-烯酰基-α-胺甲酰基二硫缩烯酮，将其作为1，5-双亲电五碳合成子的[5+1]成环策略等。

Enaminones are also valuable precursors for α-iodol enaminones, 3-amino sugar derivatives, azo-compounds,β-aminoketone, as well as tetrahydropentalenes, tetrahydroindenes, and hexahydroazulenes.

烯胺酮类化合物同时也是α-碘代烯胺酮类化合物、3-氨基糖衍生物类化合物、氮杂化合物、β-氨基衍生物类化合物和四氢并环戊二烯类化合物和四氢茚类化合物的重要前体。

Two classes of specific binding sites in the polymer matrix were investigated by Scatchard analysis, which indicated that two kinds of complexes between functional monomers and templates were formed before the polymerization process. Comparing with the structure of TNT and acrylamide, one kind of complex between TNT and acrylamide was strongly charge-transfer complexing interaction by p-πcomplex between electron-rich amino group of acrylamide and electron-deficiecy-benzene ring of TNT, the other was hydrogen bonding interaction between amino group (-NH_2) of acrylamide molecule nitro group (-NO_2) of TNT.

Scatchard分析结果表明，在TNT印记聚合物微球中存在两类结合位点，这表明在聚合反应之前，TNT与功能单体丙烯酰胺分子之间存在两种不同类型的作用力而自组装成两类的模板分子-功能单体复合物，一类可能是由于富电子的丙烯酰胺和缺电子的TNT的苯环通过p-π配键而形成的电荷转移复合物，另一类可能是由于丙烯酰胺的胺基与TNT的硝基之间的氢键作用而形成的复合物。

Contained acrylamide propenyl disulfide and II and II propenyl disulfide and cyclic sulfide Alliin are higher than white garlic more than doubled.

所含丙烯二硫化物和二丙烯基二硫化物和二丙烯基硫化物及环蒜氨酸都高出白皮大蒜一倍以上。

Three new ferrocenylmethyl-substituted indenes and cyclopentadienes were synthesized by the addition of hydrogen anion and carbon anion to fulvene and benzofulvene respectively, moreover, their structures were characterized by NMR and MS.

本文以二茂铁基富烯和二茂铁基苯并富烯为前体，通过负氢和负碳对双键的加成，合成了3个新型的二茂铁基甲基取代的茚及环戊二烯，并对其结构进行了核磁及质谱表征。

Based on studies of RCM reaction of 50 and CM reaction ofacrylonitrile with 1-octene or 1-decene catalyzed by pyridine derivative-coordinatedruthenium benzylidene complexes, it can be concluded that ruthenium benzylidene complexwith the more labile dissociating ligand exhibits the higher initial activity and better catalyticperformance.

吡啶衍生物配位的钌卡宾配合物催化含氰基烯烃50闭环交互置换反应和丙烯腈与1-辛烯、1-癸烯交叉交互置换反应表明，催化剂中吡啶衍生物配体越易解离，其初活性越高，催化活性越好。

In order to solve the problems with heavy turpentine, such as complex constituents, vicinal boiling point, difficult to separation and hard to comprehensive utilization, the α-santalene was converted to natural structure similar product α-santalol by light-oxidize reaction, and caryophyllene epoxide was obtained at the same time.

摘要为了解决重质松节油组成复杂、沸点相近导致分离困难、难以深加工综合利用等问题，利用光氧化反应技术，将其中的α-檀香烯转化为与天然α-檀香醇结构相似的檀香型新香料－α-檀香烯醇，同时可得到环氧石竹烯。

The searching result indicated that many components such as 2-Heptenal,-, Hexadecanal, Octadecanal, Megastigma-4, 6, 8-triene and Megastig-matrienone were identified the first time in studies of aroma components of Chaenomeles fruits.

检索结果表明，试验检测出的-2-庚烯醛、十六醛、十八醛、甲酸叶醇酯、辛酸环己酯、4，6，8-巨豆三烯、巨豆三烯酮等多种化合物，在木瓜果实香气成分研究中尚属首次发现。

Present status and application of isoprene,cyclopentadiene and m-pentadiene in cracking C_5 fraction products were reviewed.

重点介绍了国内外裂解C5分离产物异戊二烯、环戊二烯和间戊二烯利用近况，提出C5综合利用具有很广阔的发展前景和现实意义。

By simulation, the optimal operation conditions were gained in every step in the separation process, and polymerization-class isoprene was gained by the process. And to improve the economy of process, the process was studied by simulation, 99% cyclopentene and 1, 3-pentadiene were gained by continuous separation process. All were the base of the process industrialization.

通过模拟研究，得到分离各步的最佳塔高，进料位置和各种操作条件；并进行了全流程的模拟优化得到聚合级的异戊二烯的各种工艺参数；通过模拟研究对分离工艺进一步深化，得到了从C5中分离出环戊烯和间戊二烯的优化工艺条件，对工艺经济性进一步优化，给过程工业化提供了依据。

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失