环氧乙烷

The results showed that the main product was benzaldehyde and a little by-products were styrene oxide and phenylacetaldehyde.

发现该工艺中主要生成苯甲醛，少量副产物是环氧苯乙烷和苯乙醛等。

Being combining with products distribution in styrene oxidation, we propose the styrene epoxidation carry out with Ti metallacyclo intermediates, And at the same time Ti-ZSM-5 have properties both catalytic epoxidation and acid-catalysis, namely the skeletal Ti can catalyze styrene epoxidation to styrene oxide and the skeletal Ti and Al can provide Lewis acid site to cause the rearrangement of styrene oxide to phenylacetaldehyde rapidly, the solvolysis to glycols and the cleavage of C=C double bond. Ti-ZSM-5 can also provide Bronsted acid site simultaneously, which is also catalytic center for the solvolysis to glycols.

同时结合Ti-ZSM-5催化选择性氧化苯乙烯反应的产物分布结果，提出苯乙烯环氧化反应可能是通过金属有机环机理进行；Ti-ZSM-5同时具有催化环氧化和酸催化两种功能，其骨架钛可催化苯乙烯环氧化生成环氧苯乙烷，而骨架钛和骨架铝等可提供Lewis酸位使环氧苯乙烷迅速发生重排生成苯乙醛从而使其成为反应的主要产物，同时还可发生加成以及碳碳键的裂解等副反应：Ti-ZSM-5也提供Bronsted酸位，它也是生成加成产物的活性中心。

Using pentaerythritol as initiator, boron trifluoride diethyl etherate as catalyst.dichloroethane as dispersion agent, the chloride polyether polyol is synthesized based on the mechanism of cationic ring-opening polymerization of epiclilnrohyclrin.The azide polyether polyol is synthesized, in DMF through A and sodium azide, and the non-reported azide energetic curing agent is synthesized through the adduction of B and IIDI.

以季戊四醇为起始剂，三氟化硼乙醚为催化剂，1，2—二氯乙烷为分散剂，环氧氯丙烷经阳离子开环聚合反应制成氯化聚醚多元醇，A在N，N—二甲基甲酰胺中与叠氮化钠反应制得叠氮聚醚多元醇，B与六亚甲基二异氰酸酯加成反应制得未见文献报道的叠氮固化剂。

The selectivity of phenylacetaldehyde is increased when Br〓nsted acidity is getting stronger. The selectivity of benzaldehyde can be increased by increasing the amount of extraframework titanium species.

分子筛的B酸中心强度对产物分布有着显著的影响，B酸越强，苯乙醛的选择性越高，B酸位是催化环氧苯乙烷定向重排生成苯乙醛的催化活性中心；非骨架钛物种的增加有利于苯甲醛的生成。

Initially, we studied the ring opening of various epoxides such as styrene oxide, propylene oxide, epichlorohydrin and cyclohexene oxide with pyrazole and excellent results were obtained.

最初，我们研究了开环的各种氧化物，如环氧苯乙烷，环氧丙烷，环氧氯丙烷和环氧环己烷与吡唑和优异的成绩获得。

These catalysts were employed in the HKR of epichlorohydrin, styrene oxide and phenyl glycidyl ether.

研究了其对环氧苯乙烷、环氧氯丙烷以及苯氧基环氧丙烷等的水解动力学拆分的催化作用。

Underoptimal conditions, in toluene / dimethyl phthalate / TBP, after EAHQ was oxidizedwith 〓, then the catalyst and styrene were added, the conversion of styrene basedon EAHQ is 68%, the selectivity for styrene oxide based on styrene is 92% and theTON of the catalyst is 500; in toluene / phenyl ether / TBP, epoxidation of styrenewas performed with 〓 generated in situ, the conversion is 46%, the selectivity is94% and the product can be separated by distillation under reduced pressure.

优化条件下，甲苯／邻苯二甲酸二甲酯／TBP(2／2／1，体积比)中，EAHQ先用〓氧化完全后，再加入催化剂A和苯乙烯进行环氧化反应苯乙烯相对于EAHQ的转化率为68％，生成环氧苯乙烷的选择性为92％，催化剂A的TON达到500；甲苯／二苯醚／TBP(1／3／1，体积比)中，原位生成〓条件下苯乙烯相对于EAHQ的转化率为46％，生成环氧苯乙烷的选择性为94％，产物可通过减压蒸馏分离。

Styrene epoxidation was carried out using styrene as the row material, molecular oxygen as the oxidant, and modified vanadium phosphorus oxide as the catalyst.

以苯乙烯为原料，分子氧为氧化剂，改性的钒磷氧化物为催化剂合成环氧苯乙烷。

Ethylene oxide, chlorine dioxide, the compound aldehydes, quaternary ammonium compound category, surfactant, the activity factor, the chelating agent.

环氧乙烷、二氧化氯、复合醛类、复合季铵盐类、表面活性剂、活性因子、螯合剂。

Lauryl alcohol;Epoxy ethane; Modification; Surface modification

江西省新余高等专科学校，江西新余 338000 月桂醇；环氧乙烷；改性；表面活性

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。