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环戊烯

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They were eucalyptol, bicyclo[2.2.1]heptan-2-one,1,7,7-trimethyl-,(1R)-, borneol, 1-methyl-2-(1-methyl ethenyl)-(1R-cis)-cyclobutaneethanol, limonene, 1-hydroxymethyl-7,7-dimethy lbicyclo[2.2.1]heptan-2-one,-spathulenol, 3,7,11,15-Tetramethyl-2-hexadecen-1-ol, isocitronellol,-9-Octadecenoic acid, heneicosane, respectively.

阿给中共有11个阿给炭没有检测出的成分,包括桉油精、D-樟脑、冰片、(1R-cis)- 1-甲基-2-(1-甲基乙烯基)环丁基乙醇、二戊烯、1-羟甲基-7,7-二甲基-双环[2.2.1]庚-2-酮、-匙叶桉油烯醇、3,7,11,15-四甲基-2-十六碳烯-1-醇、异香茅醇、-9-十八碳烯酸和廿一烷。

In the end, a Novel and facile method has been used to synthesize functionalized cyclopentadienes by Nazarov cyclization ofα-alkenoyl ketene dithioacetals under Vilsmeier conditions.

从合成的α-烯酰基二硫缩烯酮类化合物出发,经过Vilsmeier试剂作用下的Nazarov环合反应,合成了官能化环戊二烯类化合物。

The biosynthesis of the quinoid nucleus are the same in all coenzyme Qs. The biosynthesis of the isoprenoid side chain determine the kind of coenzyme Q.

芳香环的合成在所有的辅酶Q族物质中都是相同的,异戊烯基侧链的长度则决定了辅酶Q的种类,这里存在一个关键酶,即异戊烯焦磷酸合成酶。

During the investigation of the reactivity of O_SCl_2(PPh_3)_2CH=C(PPh_3CHCH=CH_2 and O_SCl_2(PPh_3)_2CH=C(PPh_3C(=CH_2)CH=CH2, several stable osmacycles with novel structure, such as osmabenzenes, osmafurans, osmacycles containing intramolecular-coordinated allene, intramolecular-coordination osmacycles containing osmacarbene, an osmacyclopentadiene, were isolated during the investigation of the reactivity of O_SCl_2(PPh_3)_2CH=C(PPh_3CHCH=CH_2 and O_SCl_2(PPh_3)_2-CH=C(PPh_3C(=CH_2)CH=CH_2.In addition, some convenient and efficient methods to prepare these osmacycles were developed.

首先,合成出两种具有反应活性的金属杂五元环IC配合物OsCl_2(PPh_3)_2CH=C(PPh_3CHCH=CH_2和OsCl_2(PPh_3)_2CH=C(PPh_3C(=CH_2)-CH=CH_2,并对它们进行了系统表征;进而,研究了这些活性五元配合物的反应性,合成出多种稳定的锇杂环配合物,其中包括锇苯、锇呋喃、含配位联烯的锇杂IC环化合化物、含锇卡宾的IC环化物、首例锇杂环戊二烯化合物等多元化的产物。

In order to decrease copolymerization loss of isoprene during thermal dimerization of cyclopentadiene in C5-fraction,the effect of three inhibitors,diethylhydroxylamine,p-tert-butylcatechol and o-nitrophenol,on dienes' polymerization in the process was investigated by experiment with sealed glasstube.

为减少C5馏分环戊二烯热二聚过程中异戊二烯的聚合损失,采用封管实验方法考察了添加阻聚剂二乙基羟胺、对叔丁基邻苯二酚、邻硝基苯酚对热二聚过程中各二烯烃组分聚合程度的影响。

Enynes with an aryl ring at the alkyne give 2,3,9,9a-tetrahydro-1H-cyclopentanaphthalenes by a 5-exo-dig cyclization followed by a Friedel-Crafts-type ring expansion.

带有芳环的1,6-二烯体和炔作用,并通过5-exo-dig路径环化,再紧接着Friedel-Crafts扩环,可以得到2,3,9,9a-四羟基-1H-环戊二烯并萘。6-endo-dig途径的环化在一些例子中作为副反应被观察到,尽管,这在一些具体的反应中,是作为主反应出现的。

Advances in Research on Plants Reactions under Phosphate Starvation;2. Topics discussed in this article includes synthesis and structures of R2M24, the reactions of its metal-metal triple bond with various reagents such as nucleophiles, carbon-carbon mu.

本文对一类重要的ⅥB族金属叁键化合物R_2M_2_4(R为环戊二烯基及类环戊二烯基)近年来的研究成果进行了综述,综述重点是这类化合物的官能团M≡M参键的化学活性,全文包括R_2M_2_4的合成及结构,M≡M叁键与亲核试剂、与碳-碳重键,与氧或与金属羰基物等试剂的反应及其应用。

Topics discussed in this article includes synthesis and structures of R2M24, the reactions of its metal-metal triple bond with various reagents such as nucleophiles, carbon-carbon mu.

本文对一类重要的ⅥB族金属叁键化合物R_2M_2_4(R为环戊二烯基及类环戊二烯基)近年来的研究成果进行了综述,综述重点是这类化合物的官能团M≡M参键的化学活性,全文包括R_2M_2_4的合成及结构,M≡M叁键与亲核试剂、与碳-碳重键,与氧或与金属羰基物等试剂的反应及其应用。

Synthesis of tricyclopentadiene Two methods of polymerization were analyzed in the synthesis of TCPD: thermal polymerization of DCPD, Diels-Alder reaction of DCPD and cyclopentadiene.

三环戊二烯的合成采用两种方式对TCPD的合成进行了研究:DCPD直接热聚法、DCPD与环戊二烯双烯加成法。

This dissertation is concerned with the approaches to a new high density liquid fuel, tetrahydrotricyclopentadiene, which can be synthesized with dicyclopentadiene as raw materials by three steps: Diels-Alder reaction, separation and hydrogenation. The main points of the paper are listed as follows.

本文以双环戊二烯为原料,通过双烯加成、分离、加氢反应得到目的产物——新型高密度液体燃料四氢三环戊二烯,主要研究内容包括: 1。

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As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸,那乌黑、忧郁的眼睛,她便会相信,他一定作过不幸的爱情的受害者。

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但是因为该公司年轻的企业文化——大多数员工在40来岁的时候都被请出公司——一时间没有好的人选。