环己醇

The effect of reaction time, the ratio of alcohol and ketone, catalyst amount, and the volume of water-carrying agent on the yield of cyclohexanone 1, 2-propylene ketal were investigated.

考察了反应时间、醇酮物质的量比、催化剂质量、带水剂体积等因素对环己酮1， 2-丙二醇缩酮收率的影响。

Jiangmen City, Czech Run Chemical Trading Co., Ltd. operating chemical raw materials, mainly toluene, xylene, a rough, crude dimethyl, mixed aromatics, mesitylene, crude Sanjia, mixed dimethoxy, methylal, n-butyl, B ester, n-butyl alcohol, isobutyl alcohol, vinyl acetate, styrene, butyl ether, cyclohexanone, 6 #, 120 #, 200 #, titanium dioxide, phthalic anhydride, DOP, isopropanol for Main Product, Quality Assurance , the price advantage of abundant supply.

江门市捷润化工贸易有限公司经营化工原料，主要为甲苯、二甲苯、粗甲、粗二甲、混合芳烃、三甲苯、粗三甲、混二甲、甲缩醛、正丁酯、乙酯、正丁醇、异丁醇、醋酸乙烯、苯乙烯、丁醚、环己酮、6#、120#、200#、钛白粉、苯酐、DOP、异丙醇为主营产品，质量保证，价格优势，货源充足。

Taking Na_2SnO_3·3H_2O as raw material, organic reagent (pentyl alcohol, butyl alcohol, cyclohexane) as dispersant, and adding anion surfactant (sodium dodecyl alkylbenzen sulfonate, ABS), uniform ultrafine SnO_2 powder is prepared by hydrothermal method using Sn_4 deposition as precursor.

以Na2SnO3·3H2O为原料，有机试剂(正戊醇、正丁醇、环己烷)为分散剂，同时加入阴离子表面活性剂(十二烷基苯磺酸钠，ABS)，以氢氧化锡沉淀为前驱体，用水热法制备了粒度均匀的SnO2超细粉体。

Two compounds were synthesized with two methods. The two compounds can be synthesized by two steps with triethylamine as catalyst.

分别用氢氧化钠、三乙胺为缚酸剂，3-氨基-2-丁醇、2-氨基-3-戊醇、环己酮和二氯乙酰氯为原料，采用一步法和分步法合成了两种潜在除草剂安全剂。

For the synthesis reaction of chalcone, cyclohexanone aldolization and biodiesel,γ-Al_2O_3-NaOH-Na solid superacid has a satisfactory catalytic activity. With hypnone and phenylaldehyde as raw material, amount of catalyst 7.5% wt% of material, mole ratio of hypnone and phenylaldehyde 1:1.1, reaction temperature 40℃, after 3 hours, the yield of chalcone can be up to 96.88%. With cyclohexanone as raw material, amount of catalyst 10% wt% of material, reaction temperature 190℃, after 3 hours, dimmer of cyclohexanone can be up to 85.66%.

将该固体超强碱催化剂应用于查尔酮、环己酮自缩合以及生物柴油的合成反应中，该改性固体超强碱催化剂表现出了良好的催化活性：以苯乙酮和苯甲醛为原料，反应温度为40℃，催化剂用量为反应物总质量的7.5％，苯甲醛与苯乙酮摩尔比为1：1.1，反应3h查尔酮产率可达96.88％；以环已酮为原料，催化剂用量为原料总质量的10％，反应温度为190℃，反应3h，二聚物的总收率可达85.66％；以动物油和甲醇为原料，醇油摩尔为9：1，催化剂用量为动物油质量的2％，反应温度为70℃，反应3h后，生物柴油的收率可达91.8％。

Firstly, 3-ethylthiobutanal was prepared from crotonaldehyde reacting with ethanehiol in triethylamine with high yield. Secondly, methyl acetoacetate was converted to 6-ethylthiohept-3-en-2-one by three steps via hydrolysis, condensation with 3-ethyltio-butanal and dehydration, then 6-ethylthiohept-3-en-2-one was cycloco ndensed with dimethyl malonate by Michael addition and Claisen condensation, followed by saponification and decarboxylation to give the intermediate of 5-(2-ethylthiopropyl)-cyclohexane-1,3-dione.

首先，以巴豆醛与乙硫醇为原料，在三乙胺的催化作用下高收率制得3-乙硫基丁醛；然后从乙酰乙酸甲酯出发，通过碱水解、与3-乙硫基丁醛缩合、脱水三步反应合成6-乙硫基-3-烯-2-庚酮，接着6-乙硫基-3-烯-2-庚酮与丙二酸二甲酯通过Michael加成和Claisen缩合成环，再通过皂化和脱羧反应生成中间体5-[2-丙基]-1，3-环己二酮；再与丙酸酐反应丙酰化，最后与0-3-氯-2-丙烯基羟胺肟化，得到目标化合物烯草酮。

Hβ zeolite ; seven-member-ring ketal ; 1; 4-butanediol ; synthesis ; catalyst

Hβ；七元环缩酮； 1； 4-丁二醇；环己酮；合成；催化剂

Thus, in order to attain acetal can be used as precursor of its matrix olefine aldehyde, 2-undecental glycol acetal was synthesized, and the corresponding optimum reaction conditions as: 2-undecental 0.2mol, glycol 0.3mol, cyclohexane as solvent, catalysed by vitamin C, the optium reaction time was 6h, its reaction yield could reach over 77.25%.

为了进一步探求效果更理想的前体化合物，本文继续合成了2-十一烯醛乙二醇缩醛，通过单因素优化实验得到最佳反应条件为：环己烷作溶剂，VC作催化剂，用量0.42%，醛醇物质的量之比0.2：0.3，反应时间6h，此条件下产品收率达77.25%。

The thesis is divided into two areas: The first area investigated using gold, silver complex to catalyze the cyclization of propargyl alcohol molecules to produced the cyclohexanone products in high yield at room temperature.

题目将分成两个部份：第一个部份主要研究金属金和金属银错合物催化丙炔醇类分子的环化反应，在室温下反应产生高产率之环己酮产物。

The effects of different of categories surfactants, the proportion of surfactant and cosurfactant , the chain lengths of alcohol and alkane, temperatures and pH values on the W/O microemulsion phase areas are systematically studied in the dissertation. SEM and laser scatting techniques are used to verify particles'sizes of W/O microemulsion. Consequently, a system TritonX-100/n-C〓H〓OH (weight ratio 1: 1)/C〓H〓/H〓O is obtained which is a stable system with relatively large W/O microemulsion phase area.

本文系统研究了表面活性剂种类、助表面活性剂的链长、表面活性剂和醇的配比、烷烃的链长以及温度、pH值等对W/O微乳液相区域的影响，并用SEM、激光光散射等对微乳液粒度进行了表征，从而获得一种稳定的、W/O微乳液区域较大的体系：壬基苯酚聚氧乙烯醚(TritonX-100)/正戊醇(质量比1：1)/环己烷/水体系。

I can not make it blossom and suits me

我不能让树为我开花

When temperatures are above approximately 80 °C discolouration of the raceways or rolling elements is a frequent feature.

当温度高于 80 °C 左右时，滚道或滚动元件褪色是很常见的特征。