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环己烯

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This invention discloses an intermolecular charge transfer chromogen with triphenylamine group, with a formula indicated by (1), wherein: R1 is hydrogen atom or methyl group or methoxyl group, R2 is hydrogen atom or 2-(5,5-dimethyl-3-vinylcyclohexenyl-2-enylidene)propanedinitrile group.

本发明公开的含三苯胺基团的分子内电荷转移生色团,具有式1所示的结构式,其中R 1 为氢原子或甲基或甲氧基,R 2 为氢原子或2-(5,5-二甲基-3-乙烯环己烯基-2-烯亚基)丙二腈基。

This invention applies mild condition uses substituent group triphenylamine aldehyde or triphenylamine dialdehyde as raw material to react by heating with 2-(5,5-dimethyl-3-vinylcyclohexenyl-2-enylidene)propanedinitrile group to produce the intermolecular charge transfer chromogen with high decomposition temperature, non-coplanar structure, and triphenylamine group.

本发明采用温和的手段,将取代基三苯胺单醛或取代基三苯胺双醛为原料与2-(3,5,5-三甲基环己烯-2-烯亚基)丙二腈共热生成具有高的热分解温度、非共平面空间结构的含三苯胺基团的分子内电荷转移生色团。

Using cobalt chloride and ferromanganese as precursor of cobalt-based catalyst, the performance of the catalyst for hydroformylation of cyclohexene was studied.

以氯化钴和锰铁合金粉为钴基催化体系的前驱体,研究了该催化剂体系对环己烯氢甲酰化反应制备环己烷基甲醛的催化性能;并考察了溶剂、温度、压力等反应条件的影响。

The different catalytic systems are discussed. The results show that sodium tungstate has effective catalytic ability.

实验结果表明,钨酸钠和双季铵盐催化体系能在温和的条件下,催化稀过氧化氢溶液氧化环己醇、苯甲醇、环己烯

Aiming at demand of national economy and linking the actual condition of domestic refinery chemical , a routine with cyclohexene as main raw material was developed in the thesis.

本文针对国民经济发展的需求,结合我国精细化工行业的实际,进行了以环己烯为主要原料,合成1,2-环己二醇的研究。

The results reveal that the supported catalyst has high catalytic activity and good selectivity of epoxide for the epoxidation of cyclohexene and styrene, respectively.

上述结果表明该负载催化剂对环己烯和苯乙烯的空气环氧化具有很高活性和环氧化物选择性。

A series of 3 - aryl - 3 -( 5,5 - dimethyl - 3 - hydroxy - 2 - cyclohexene - 1 - one - 2 - yl) propanoic ester s were synthesized by reaction between aromatic aldehydes ,5,5- dimethyl -1,3-cyclohexanedione and isopropylidene malonate catalyzed by KF - Al2O3 in alcohols.

在KF-Al_2O_3催化下,将芳香醛3,5-二甲基-1,3-环己二酮及丙二酸亚异丙酯在醇中反应,一锅式合成了一系列的3-芳基-3-(5,5-二甲基-3-羟基-2-环己烯-1-酮-2-基)丙酸酯。

Diels-Alder reaction between β-myrcene and maleic anhydride catalyzed by SO(superscript 2- subscript 4)/TiO2-ZrO2 solid superacid was investigated.

研究了SO(上标 2-下标 4)/TiO2-ZrO2型固体超强酸催化剂的制备及其催化β-月桂烯与马来酸酐的Diels-Alder反应,通过GC、GC-MS和红外分析,确定其主产物为4-(4-甲基-3-戊烯基)-4-环己烯-1,2-酸酐。

Synthesis and Structural Analysis of New Monoterpene Derivatives from β-myrcene ;2. Diels-Alder reaction between β-myrcene and maleic anhydride catalyzed by SO2-4/TiO2-ZrO2 solid superacid was investigated.

研究了SO42-/TiO2-ZrO2型固体超强酸催化剂的制备及其催化β-月桂烯与马来酸酐的Diels-Alder反应,通过GC、GC-MS和红外分析,确定其主产物为4-(4-甲基-3-戊烯基)-4-环己烯-1,2-酸酐。

Niobic acid; catalytic synthesis; di-2-ethylhexyl phthalate; di-n-octyl phthalate; di-2-ethylhexylmaleate; di-n-octyl maleate; cyclohexene; modification of catalyst; dynamics of esterification

工程科技I,化学,有机化学铌酸;催化合成:邻苯二甲酸二辛酷;邻苯二甲酸二异辛酯;顺丁烯二酸二辛酯:顺丁烯二酸二异辛酯:环己烯;改性;动力学

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