环二酯

Additionally, the quantum chemical study on the isomeriaation mechanism of the enol ester of 2-acyl-l,3-cyclohexanedione was performed, which was discovered by Yang when he synthesized the derivate of 2-acyl-l,3-cyclohexanedione.

第三部分工作是对杨定亚在合成2-酰基-1，3-环己二酮类化合物的衍生物时意外发现的烯酯异构化反应机理进行了研究。

As compared with the lactide ring-opening polymerization, the direct melting copolymerization of LA and CL is proved more practicable and simpler.

与丙交酯开环聚合二步法相比，LA与CL直接熔融共聚的合成工艺简单易行。

O-(1-Arylseleno-3-azido)isopropyl-O-2-(N3-tegafur)alkyl thiophosphate (3a～3f) were obtained via nu-cleophilic ring-opening of sodium azide to 2a～2f in dry DMF at room temperature, and their antitumor activities were tested.

以无水N，N-二甲基甲酰胺作溶剂，室温下，叠氮化钠中对2a～2f进行亲核开环，得到O-(1-芳硒基-3-叠氮基)异丙基-O-2-(N3-替加氟)乙基硫代磷酯。

Formyl-3-acetyl-4-methyl-5-carbobenzoxypyrrole (6) was synthesized via the selective oxidation of 2,4-dimethyl-3-acetyl-5-carbobenzoxypyrrole (5), which was produced from acetylacetic benzylester (1) via nitrosation, reduction and addition-cyclization with acetylacetone. The total yield of the product was about 34%.

以乙酰乙酸苄酯(1)为原料，经过亚硝化、还原、与乙酰丙酮加成环化生成2， 4-二甲基－3-乙酰基－5-苄氧羰基吡咯(5)，通过选择性氧化反应制得目标化合物2-甲酰基－3-乙酰基－4-甲基－5-苄氧羰基吡咯(6)，反应的总收率约为34%。

4R,5S,6R-5,6-Bis-allyl-6-aldehyde-γ-hexanelactone I-145 was prepared from D-arabinose by six steps. Compound I-145 underwent Mukaiyama-type intramolecular aldolization to produce bicyclooctane I-147 stereospecifically.

我们以D-阿拉伯糖为起始原料，经六步反应，得到(4R，5S，6R)-5， 6-二烯丙氧基-6-醛基-γ-己酸内酯I-145，然后I-145发生分子内的Mukaiyama式aldol缩合反应，完全立体专一性地得到环化中间体I-147。

The result indicated that the reacting mixture containing dioxane 11.3mL/g HDCA which had been added ethyl chloroformate drop wise should be keep at 10℃ for 30min, then, rising to 15℃ for another 20min in the step of forming mixed anhydride ,and 1.5mol/L NaOH was used to dissolve taurine before aminolysis, and crude product was recrystalled by acetone in purifying process.

结果表明，形成混酐时，二氧六环用量为11.3ml/g HDCA，滴加氯甲酸乙酯后先在10℃反应30min，再在15℃下反应20min；用1.5mol/L的NaOH水溶液溶解牛磺酸后再进行氨解；粗产品用丙酮重结晶。

One synthetic strategy started fromγ-butyrolactone 38, from which a cyclohexadiene intermediate 30 was prepared in an overall yield of 44% in a 7-step procedure after y-butyrolactone underwent a-bromination, dehydrobromination, Diels-Alder reaction, aminolysis, benzylation, bromination and dehydrobromination, with the key step being the Diels-Alder reaction under harsh condition.

其中一个路线从γ-丁内酯38开始，连续经过α-溴化、脱溴化氢、Diels-Alder反应、胺解、苄基化、溴化和脱溴化氢共7步反应，制备了一个环己二烯衍生物30，总产率44％，关键步骤是高温高压下Diels-Alder反应。

The results showed the different fluorescence property with naphthalene due to the interaction, congruence of the molecules and formation of inter- or intramolecular exciplex.;A series of dithioesters with different aromatic rings such as naphthally, anthracyl and pyrene in R groups were synthesized. The polymerizations of MMA using these dithioesters as the RAFT agents were investigated.

结果表明：在NMNDT和它获得的聚合物溶液中，由于分子间的相互作用、叠合，激发态分子与基态分子形成了激基缔合物，引起了萘环荧光的淬灭，使其发光特性与原来萘的发光特性不同；探索了二硫代酯中R基团的立体和电子等性能对MMA的RAFT聚合的影响。

Moisturizer:Water,propylene glycol,saccharide isomerate,chondrus crispus,peg-40 hydrogenated castor oil,imidazolidinyl urea,methylparaben,sodium hyaluronate,pentadecalactone,citrus aurantium dulcisoil,lactic acid,iris germanica root extract,sodium hydroxide,citrus aurantium amara oil,yellow 6(CI 15985),limonene,linalool

保湿精华：水，丙二醇，天然异构寡糖，卡拉胶，PEG-40氢化蓖麻油，尿素醛，羟苯甲酯，透明质酸钠，环十五内酯，甜橙油，乳酸，鸢尾花根萃取，氢氧化钠，苦橙油，黄 6(CI 15985)，柠檬精油，芳樟醇

This thesis makes up the direction for Cu-Zn-Al-O catalyst, explores the perparation method and technological conditions、the reduction method and technological conditions of Cu-Zn-Al-O catalyst, investigates Cu-Zn-Al-O catalyst activity, and studies the kinetics of γButyrolactone synthesis reaction by the liquid phase dehydrocyclization from 1, 4-Butanediol on Cu-Zn-Al-O catalyst in the batch reactor.

研究了Cu-Zn-Al-O催化剂的配方、制备方法和工艺条件、活化方式和工艺条件，考察了催化剂的活性，并在全混釜反应器中研究了1，4—丁二醇在Cu-Zn-Al-O催化剂上液相脱氢环化合成γ—丁内酯的反应动力学特性。

Breath, muscle contraction of the buttocks; arch body, as far as possible to hold his head, right leg straight towards the ceiling (peg-leg knee in order to avoid muscle tension).

呼气，收缩臀部肌肉；拱起身体，尽量抬起头来，右腿伸直朝向天花板（膝微屈，以避免肌肉紧张）。

The cost of moving grain food products was unchanged from May, but year over year are up 8%.

粮食产品的运输费用与5月份相比没有变化，但却比去年同期高8％。