环二酯

In this paper , two fluorocarbon amphoteric phosphate surfactants were synthesized and their performances were determined.

首先，磷酸二氢钠与环氧氯丙烷开环加成合成2-羟基-3-氯丙基磷酸酯钠，分离提纯后，分析其红外。

The yields were better when DHPCE with nitro group in meta or ortho position of the benzene ring were hydrolyzed in basic conditions, while the hydrogenolysis and acidic reactions gave very poor yields.

当苯环的间位和对位存在硝基，碱性水解时，在二氢吡啶环的3位引入氯乙醇的酯能得到较好的收率；酸性水解和氢解法则不宜用来合成ADHPA。

A catalyst composition for the polymerization of propylene comprising one or more Ziegler-Natta procatalyst compositions comprising one or more transition metal compounds and one or more esters of aromatic dicarboxylic acid internal electron donors; one or more aluminum containing cocatalysts; a selectivity control agent comprising at least one silicon containing compound containing at least one C1-10 alkoxy group bonded to a silicon atom, and one or more activity limiting agent compounds comprising one or more aliphatic or cycloaliphatic carboxylic acids; alkyl-, cycloalkyl- or alkyl-ester derivatives thereof; or inertly substituted derivatives of the foregoing.

一种用于丙烯聚合的催化剂组合物，所述催化剂组合物包括：一种或多种齐格勒-纳塔主催化剂组合物，该主催化剂组合物包括一种或多种过渡金属化合物和一种或多种芳族二羧酸酯内部电子给体；一种或多种包含铝的助催化剂；选择性控制剂，该选择性控制剂包括至少一种包含硅的化合物，该化合物包括至少一种与硅原子连接的C 1-10 烷氧基；和一种或多种活性限制剂化合物，该活性限制剂包括一种或多种脂族或脂环族的单或聚羧酸类、其烷基-、环烷基-或烷基-衍生物、或上述惰性取代的衍生物。

The star shaped block copolymers were prepared by ring opening polymerization of ε caprolactone in the presence of multiarm PEG using stannous octoate as a catalyst.

以辛酸亚锡为催化剂，通过星型聚乙二醇引发ε己内酯开环聚合，制备了PEG b PCL嵌段共聚物，进一步以丙烯酸酯封端，合成了 3种水溶性大分子单体。

The star-shaped block copolymers were prepared by ring-opening polymerization of ε-caprolactone in the presence of multiarm PEG using stannous octoate as a catalyst.Based on these star-shaped PEG- b -PCL,soluble macromers terminated with acrylate groups were synthesized.

以辛酸亚锡为催化剂，通过星型聚乙二醇引发ε-己内酯开环聚合，制备了PEG- b -PCL嵌段共聚物，进一步以丙烯酸酯封端，合成了3种水溶性大分子单体。

In order to check the corresponding compound at 31P NMR –45.4 ppm, stable pentacoordinate spirobicyclic 2-phenoxy-1,3-phenylene-dioxo-1,3,2-iminoacetoxyphosphoranes were synthesized through a new and efficient method whereby phosphorus pentachloride was displaced stepwise by catechol, N,O-bisamino acid and phenol, or catechol, phenol and N,O-bisamino acid, their 31P NMR chemical shifts are at about 31P NMR –45.0 ppm, the results showed that the compound 4 at 31P NMR –45.4 ppm was pentacoordinate phosphorane containing amino acid residue.

采用磷谱跟踪来研究上述成肽反应机理。例如在氮气保护下，0.1mmol O，O-亚苯基磷酰氯（1）和0.15mmol N，O-二苯丙氨酸（2）苯溶液加入0.6ml核磁管中，混合均匀，反应过程用磷谱检测。反应1分钟后，起始原料1(δp=19ppm)很快转变成N-磷酰苯丙氨酸的三甲基硅基酯（3）(δp=19.8ppm)，在8分钟内，3完全转变成苯丙氨酸磷烷4(δp =-45.4ppm)，同时出现环磷三酯（6）(δp=3.5ppm)。随着反应的进行，对应于化合物4的峰逐渐变小，而6逐渐变大。

A novel polymer of Poly(diglycidyl maleate-co-stearyl methacrylate) was synthesized and its structure was characterized by ~1H NMR. Its self-assembly behavior was studied in different solvents. It was found that vesicles and tubule-liked aggregates can be obtained through self-assembly of P(DGMA-co-SMA)/THF/EtOH system. And spheral aggregates were obtained in P(DGMA-co-SMA)/THF/H_2O system while the spheral aggregates were converted into rod-liked aggregates and line-liked aggregates after aged for different time.

合成了带含环氧基侧链和十八烷基侧链的聚(马来酸二缩水甘油酯-co-甲基丙烯酸十八酯)，用~1H NMR对所得的共聚物进行了表征；研究了其在选择性溶剂中的自组装行为，发现P(DGMA-co-SMA)／THF／EtOH体系可以通过自组装形成囊泡形自组装体和支化的管状自组装体，P(DGMA-co-SMA)／THF／H_2O体系最初自组装形成球形自组装体，随着陈化时间的延长，球形自组装体逐渐融合成长条形自组装体和线形自组装体；探讨了自组装过程的机理，建立了可能的自组装过程模型。

Flame—retardant resin was prepared by the condensation and polymerization of phosphoric acid, trihydroxy methyl propane and epoxy chloropropane,the resin was then reacted with hexane diacid and diglycol under certain condition ,resulting in polyol containing 1.5% P and 17— 18% polyester polyol, which was foamed with polyisocyanate, water and catalyst by one— step method, producing fire...

通过磷酸、三羟甲基丙烷和环氧氯丙烷的缩合和聚合反应制得阻燃树脂，然后将它与己二酸、一缩二乙二醇在一定条件下反应制得含P1.5%和含Cl17～18%的聚酯多元醇，再将它与多异氰酸酯、水、催化剂等组分采用一步法发泡工艺制得阻燃聚氨酯软泡塑料。

Flame— retardant resin was prepared by the condensation and polymerization of phosphoric acid, trihydroxy methyl propane and epoxy chloropropane,the resin was then reacted with hexane diacid and diglycol under certain condition ,resulting in polyol containing 1.5% P and 17— 18% polyester polyol, which was foamed with polyisocyanate, water and catalyst by one— step method, producing fire—resistant PU soft foam.

通过磷酸、三羟甲基丙烷和环氧氯丙烷的缩合和聚合反应制得阻燃树脂，然后将它与己二酸、一缩二乙二醇在一定条件下反应制得含P1.5%和含Cl17～18%的聚酯多元醇，再将它与多异氰酸酯、水、催化剂等组分采用一步法发泡工艺制得阻燃聚氨酯软泡塑料。

By synthesizing the hapten LBc starting from the metabolite of bifenthrin (2-methyl-3-phenylbenzyl alcohol), LBs (2-methyl[1,1-biphenyl]-3-ylmethyl 3-carboxyl-2,2-dimethylcyclopropane carboxylate and Lby (2-methyl[1,1-biphenyl]-3-ylcarboxylic acid , Three haptens were praparaed which were used in next step.

利用联苯菊酯的代谢物联苯醇合成了联苯菊酯的半抗原LBc(2-甲基-3-苯基苄基氧基羰基丙酸)、LBs(2-甲基-3-苯基苄基-3-羧基一2，2-二甲基环丙烷羧酸)和LBy(2-甲基-3-苯基苯甲酸)。

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。