环丙烷

Moreover, we found that N-heterocyclic carbene could served as an efficient and novel catalyst for the reactions of aziridines with silylated nucleophiles or acid anhydrides.

随后，我们发现氮杂环卡宾也可以作为一种有机小分子催化剂，分别催化各类硅试剂或酸酐对氮杂环丙烷化合物的开环。

General approaches involve the nucleophilic cycloalkylation, carbenoids addition of certain amino acid derivatives and derivatization from simple cyclopropane compounds.

制备方法包括对简单氨基酸衍生物的亲核环烷基化、卡宾加成以及简单环丙烷化合物的衍生化合成等。

We also discussed this unusual reaction process and proposed a reasonable "one method,two paths" mechanism.These novel iodine-mediated oxidative cycloadditions provide a rapid and efficient route to the preparation of a variety of spiro dihydrofuran and cyclopropane derivatives.

该反应不使用昂贵的催化剂；反应过程中不使用有毒有害的有机溶剂，对环境友好；反应时间短，收率高；在相同条件下得到不同结构的产物，这提供了一种新型的合成二氢呋喃和环丙烷结构的环化反应。

The oxidation reaction, the addition of nucleophiles to C-C multiple bonds, cyclization of enynes and cyclopropane compounds catalyzed by gold were intrduced.

第二章：介绍了环丙烷亲核开环反应，总结了以往亲核开环反应的优缺点。

The cis novel bisoxazoline ligands L1-L4 have been synthesized through the treatment of new cis dihydroxy diamide with p-toluenesulfonyl chloride in the presence of catalytic quantity of 4--pyridine, and the cis dihydroxy diamide could be achieved from the condensation of the amino alcohols and cis cyclopropane dicarbonyl chloride prepared via oxidation and halogenation from cis-2,2-dimethyl-3-formylcyclopropanecarboxylate with DCC.

我们以蒈醛酸内酯为起始原料，经过氧化反应、酰氯化反应得到顺式环丙烷二酰氯，然后在二环己基碳二亚胺的催化下与相应的氨基醇反应合成了顺式二羟基酰胺，再用对甲苯磺酰氯将羟基活化，最后在二甲氨基吡啶的催化下关环合成顺式双噁唑啉配体L1～L4。

Within this study, we found some interesting results, for example, the type of ring opening mode of methylene cyclopropyl ketones was changed from distal to proximal under the catalysis of palladium with the addition of two equivalents of sodium iodide.

我们发现了一个非常有趣的现象：亚甲基环丙烷基酮的开环方式可以得到有效的调控：在没有外加卤离子的情况下，开环方式为distal断裂，从而得到了4—氢吡喃化合物，而在两当量的碘化钠的存在下却发生了proximal断裂，从而能够得到2，4—双取代的呋喃。

In this paper isopropyl -γ- chlorobutyrate was prepared from γ- butyrolactone by one - step. The effects of molar ratio of reactants, reaction temperature, reaction time on the yield of product were discussed, the optimum reaction condition was obtained.

一氯代丁酸异雨酯是合成新型拟除虫菊酯中间体环丙烷较酸及高效抗菌新药丙氟见酸和环丙氟院酸中间体环丙胺的重要原料［''］。

Chapter 1: The reactions of methylenecyclopropanes with phenylsulfenyl chloride or phenylselenyl chloride give cyclobutene derivatives along with ring-opened products in good total yields at 0 °C in various solvents. The reactions of methylenecyclopropanes with diphenyl diselenide give the di-phenylselenyl substituted ring-opening products which can be transformed to 2,5-dihydrofuran derivatives under the oxidation with hydrogen peroxide at room temperature.

在第一章中，我们发现亚甲基环丙烷类化合物在0℃时即可很快与苯硫氯或苯硒氯发生反应生成取代环丁烯类化合物和正常的开环产物；而与二苯基二硒的反应则需加热到150℃以上才能进行反应，生成的二苯硒基开环产物在双氧水氧化下可以转化为取代二氢呋喃类化合物。

The compoud 1 can be converted to intramolecular coupled cyclic olefine (2) as a main product in the presence of iron catalyst.

控制反应条件，在铁催化下可以生成偶联烯烃化的环烯产物(2 )为主要产物；不加催化剂，加热回流反应得到分子内亲核取代反应产物环丙烷化合物 3

Group A = atmospheres containing acetylene; Group B = atmospheres containing hydrogen; Group C = atmosphere containing ethyl-ether vapors, ethylene, or cyclopropane; Group D = atmospheres containing gasoline, hexane, naphtha, benzene, butane, propane, alcohol, acetone, benzol, lacquer, solvent vapors or natural gas.

组A =大气中含有乙炔；组B =大气中含有氢；组C =大气中含有乙醚蒸汽，乙烯，或环丙烷；组D =大气中含有汽油，乙烷，石脑油，苯，丁烷，丙烷，酒精，丙酮，不纯苯，漆，溶剂蒸汽，或天然气。

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失