环丙烷

The catalytic effect of basic lithium phosphate on the preparation of allyl alcohol by isomerization of propylene oxide was studied in this dissertation.

本论文主要研究了碱性磷酸锂在环氧丙烷异构化制烯丙醇反应中的催化作用。

At present,the main methods to produce epichlorohydrin chlorination are through allyl chloride route at high temperature or allyl alcohol route.

目前，世界上环氧氯丙烷工业的生产方法有两种：氯丙烯高温氯化法和烯丙醇法。

The isomerization reaction of propylene oxide to produce allyl alcohol catalyzed by basic lithium phosphate was studied.

研究了环氧丙烷在碱性磷酸锂催化作用下异构化生成烯丙醇反应过程，考察催化剂的制备条件，异构化温度对催化性能的影响，以及催化反应机理和动力学特性。

Allyl glycidyl ether was synthesized from allyl alcohol and epichlorohydrin by phase transfer catalysis.

以烯丙醇和环氧氯丙烷为原料，采用相转移催化法，合成了烯丙基缩水甘油醚。

At first,the intermediate of sodium 3-chloro-2-hydroxy propanesulfate was synthesized from epichlorohydrin and sodium bisulfite;And then,using NaOH as a catalyst,the title compound has been synthesized from intermediate and allyl alcohol to reach the yield of about 70%.

先由环氧氯丙烷和亚硫酸氢钠合成中间体3-氯-2-羟基丙磺酸钠，然后中间体再与丙烯醇在氢氧化钠催化下生成目标产物2-羟基-3-烯丙氧基丙磺酸钠。

Sodium allylate was prepared from solid sodium hydroxide and allyl alcohol under mild conditions, and then the solid sodium allylate was reacted with epichlorohydrin in anhydrous system to produce allyl glycidyl ether in high yield and purity.

以固体NaOH和烯丙醇为原料在温和条件下制得烯丙醇钠，再以固体烯丙醇钠为原料，与环氧氯丙烷在无水条件下高产率地得到高纯度的烯丙基缩水甘油醚。

It is possible to achieve the conversion of allyl chloride and selectivity for epichiorohydrin as high as 99% on Ti-MWW.

在Ti-MWW催化剂上烯丙基氯的转化率和环氧氯丙烷的选择性都能达到99%以上。

The yield of allyl glycidyl ether can reach up to 96% at 30 ℃ for 3 h at a molar ratio of 1 to 1.5 of sodium allylate to epichlorohydrin.

醚化反应中固体烯丙醇钠与环氧氯丙烷摩尔比为1：1.5，在无水条件下于30℃反应3 h，烯丙基缩水甘油醚的收率达96%以上。

Propylene epoxidation to propylene epoxide is one of the most important challenges in catalysis because this reaction possesses both industrial significance and academic importance.

中文摘要：丙烯环氧化制环氧丙烷具有重大的工业应用背景和重要的学术意义，开拓该反应的高效催化体系和催化剂是催化领域的最重要的挑战之一。

Glycidyl benzoate,glycidyl propionate,glycidyl acetate were obtained respectly through a phase-transfer catalytic methodology using sodium benzoate, sodium propionate, sodium acetate and epichlorohydrin as raw materials, and pure products were obtained though vaccum distillation.β-cyclodextrin and glycidyl benzoate, glycidyl propionate, glycidyl acetate, reacted in organic solvent and goal product were

先以苯甲酸钠、乙酸钠、丙酸钠和环氧氯丙烷为原料在相转移催化剂的作用下分别合成了苯甲酸缩水甘油酯、乙酸缩水甘油酯和丙酸缩水酯，经过减压蒸馏，得到相应的纯品；β-环糊精和苯甲酸缩水甘油酯、乙酸缩水甘油酯、丙酸缩水甘油酯在有机溶剂中反应，经过硅胶色谱柱分离，得到了相应的产品，产品经过TLC、IR、1H NMR、MS表征，并研究了温度、反应时间、催化剂等几个因素对反应工艺的影响，结果表明温度和催化剂对反应的快慢有较大影响。

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失