环

3 Recently, we reported an efficient tin-free version of this reaction involving thiophenol for the preparation of cyclopentane derivatives through a 1,5-hydrogen transfer/cyclization sequence [Eq.(1); AIBN=azobisisobutyronitrile].

最近，我们报道了高效的、不使用锡试剂而使用苯硫酚的反应，这个反应是通过1，5-氢转移/环化步骤制备环戊烷衍生物的[化学反应式(1)；AIBN=偶氮二异丁腈][4]。

Whereas the tin hydride is used, for preparing functional fivemembered rings ,to induced alkenyl radical translocation/ cyclization process ——oxidaton process by selective activation of a C H bond——developed by Curran et al., thiophenol, non-tin chemical, is used in this new synthetic method for preparing cyclopentane derivatives through a 1,5-hydrogen transfer/cyclization sequenceEq.

在这些目标中，发展无毒、环保试剂实施有效的自由基反应是一具有挑战性的目标。Curran等发明了用氢化锡介导的自由基易位/环化过程是一种通过C H键的选择性氧化制备功能五元环的高效的方法。

Therefore, the mechanism of the ring-opening process for electron-deficient cyclopropane derivatives was fully confirmed by the intermediates monitored.

因此，贫电子三元环衍生物的开环反应过程的机理因检测到的中间体得到了很好的证明。

Diacylhydrazine cyclopropane compounds were synthesized from cyclopropane carboxylic acids which have comparable characters in the structures.

以结构上有可比性的环丙烷羧酸为原料，合成了环丙烷双酰肼化合物，结构经红外和核磁验证。

Cyclopropane compounds areimportant reaction intermediates of organic systhesis and cyclopropane subunits arefound in many natural or unnatural products.

环丙烷衍生物是有机合成中常用的一类重要的反应中间体，手性的环丙烷衍生物在不对称合成中很有价值。

The conjugations between cyclopropane ring andoxazole rings were found and the reason why these compounds have low fluorescence quantum yieldswas explicated.

我们发现恶唑环与三元环间存在一定程度的共轭，并解释了上述化合物荧光量子产率较低的现象。

The hapten can be synthesized with a spacer attached at the aromatic moiety of the pyrethroid, through the middle of the molecule and at the cyclopropane moiety.

半抗原的合成入手点主要为菊酯分子的三碳环、中间和芳环部分，连接一个连接臂作为半抗原。

General approaches involve the nucleophilic cycloalkylation, carbenoids addition of certain amino acid derivatives and derivatization from simple cyclopropane compounds.

制备方法包括对简单氨基酸衍生物的亲核环烷基化、卡宾加成以及简单环丙烷化合物的衍生化合成等。

We also discussed this unusual reaction process and proposed a reasonable "one method,two paths" mechanism.These novel iodine-mediated oxidative cycloadditions provide a rapid and efficient route to the preparation of a variety of spiro dihydrofuran and cyclopropane derivatives.

该反应不使用昂贵的催化剂；反应过程中不使用有毒有害的有机溶剂，对环境友好；反应时间短，收率高；在相同条件下得到不同结构的产物，这提供了一种新型的合成二氢呋喃和环丙烷结构的环化反应。

Jiangsu Agrochem Laboratory, Changzhou 213022, Jiangsu, China Abstract: Diacylhydrazine cyclopropane compounds were synthesized from cyclopropanecarboxylic acids which have comparable characters in the structures. Their structures were confirmed by IR spectrum and 1H NMR.

江苏省农用激素工程技术研究中心，江苏常州 213022 摘要：以结构上有可比性的环丙烷羧酸为原料，合成了环丙烷双酰肼化合物，结构经红外和核磁验证。

Breath, muscle contraction of the buttocks; arch body, as far as possible to hold his head, right leg straight towards the ceiling (peg-leg knee in order to avoid muscle tension).

呼气，收缩臀部肌肉；拱起身体，尽量抬起头来，右腿伸直朝向天花板（膝微屈，以避免肌肉紧张）。

The cost of moving grain food products was unchanged from May, but year over year are up 8%.

粮食产品的运输费用与5月份相比没有变化，但却比去年同期高8％。