环

The invention is characterized in that phthalide of general formula, wherein n and X have the meaning cited in the description, is reacted with nitrogen heterocycles of general formula: H-Z, wherein Z has the meaning cited in the description, or with nitrogen heterocycle metal salts of general formula in the presence of an aprotic polar diluent and optionally in the presence of a basic auxiliary reaction agent.

本发明涉及制备通式的2－杂环基甲基苯甲酸衍生物的新的方法，其中n、X和Z具有说明书中给出的意义，该方法提供高收率和高纯度，其特征是，通式的2－苯并呋喃酮，其中n和x具有说明书中给出的含义，与通式的氮杂环：H－Z，其中Z具有说明书中给出的意义，或与通式的氮杂环的金属盐在质子惰性极性稀释剂中并任选在碱性反应助剂存在下反应。

Gabriel reaction was adopted to synthesis 2-(0ctahydro-1-azocinyl)ethylamine, N-(β-Heptamethyleniminoethy1)phthalimide was prepared by treating Heptamethylenimine with N -(β-bromoethy1) phthalimide. N -(β-bromoethy1) phthalimide was easily prepared from phthalic anhydride in two steps.

我们采用Gabriel伯胺合成法制备2-环庚亚胺基乙胺，从邻苯二甲酸酐经过两步反应很容易地得到N-邻苯二甲酰亚胺，然后与环庚亚胺发生亲核取代反应，产物再水解制得伯胺2-环庚亚胺基乙胺。

The molecular designs and synthesis of triarylamine-based picolinic acid derivatives used as ancillary ligands, and their cyclometalated iridium complexes used as red-and green-emitters, as well as optoelectronics properites of these compounds were investigated in order to solve current problems of organic/polymeric electroluminescent materials and devices.

本论文针对目前有机/聚合物电致磷光材料和器件存在的问题，开展了新型三芳胺吡啶羧酸类辅助配体及其红光和绿光环金属铱配合物电致磷光材料的分子设计、合成和光电性能研究，主要包括：(1)设计、合成了三种新型的三芳胺吡啶羧酸类双齿阴离子型辅助配体；(2)以三芳胺吡啶羧酸衍生物作为双齿阴离子型辅助配体，合成得到了两个系列的红光和绿光环金属铱配合物；(3)研究了三芳胺吡啶羧酸类辅助配体分子结构对环金属配合物的紫外吸收和光致发光性能的影响；(4)以环金属配合物为客体，聚芴和恶二唑衍生物为主体，制作了聚合物电磷光器件，研究了含三芳胺吡啶羧酸类辅助配体、环金属配合物客体材料和聚合物主体材料等分子结构对电致发光性能的影响。

A colorimetric method for epoxides, based on the reaction of the oxirane group with picric acid, is reportedly more sensitive than the oxirane test and is not subject to the shortcomings mentioned.

据报导以环氧乙烷与苦味酸的反应为基础的一种测定环氧化物的比色法比环氧乙烷试验敏感，并不具有所提到的缺点。

And the ability of antioxidant of polyhydroxy benzamides don't have too many differences with Trolox (IC50 =13.90 μg/ml), the substition of hydroxy group at amino benzene ring doesn't affect the whole ability of antioxidant apparently, but while the single hydroxy group at carboxylic acid benzene ring, they are apparently decrease to scavenge the ability of free radical, as a result, the hydroxy at amino benzene ring substitutes its function, without the hydroxy group, the ability of antioxidant is worst, but it upgrades its function while the hydroxy and amino are in the ortho-position or para-position.

而当多酚醯胺化合物其抗氧化能力与Trolox差不多时(IC50 =13.90 μg/ml)，胺基苯环上之羟基取代对整体抗氧化能力影响不明显，但在羧酸苯环上具单羟基时，其清除自由基能力明显下降，使得胺基苯环上羟基取代发挥了影响力，无羟基取代时，抗氧化能力最差，而羟基与胺基互为邻位或是对位时较间位有提升效果。

We predict the optimized structures of macrocyclic ligands of cyclononane and cyclododecane systems in different environments; furthermore, we analyze the protonated sites, preorganization, conformational changes and calculated energies.

利用此模拟方法，我们针对不同环境下之九员环以及十二员环系列的大环配位子进行结构最佳化之预测，进而可分析 protonation sites 、配位子是否会发生 preorganization 与结构的变化，以及能量的计算。

Synthesis with carbocyclic compounds, such as cyclodienylsilane, quinic acid and norbornene etc, as starting materials is discussed in detail.

重点介绍了以环二烯基硅烷、奎宁酸、降冰片烯等碳环化合物为原料合成碳环糖的进展。

The comparison of petrology, lithofacies, petro-geochemistry and tectonic environment of the rapakivi granite both from Qinling-Kunlun and world shows that the rapakivi granite has same or consistent characteristics: rapakivi structure, sub-aluminous, high-potassic, alkali-rich magma, two-peak magma assemblage and formed in post-collision environment. However, there are some certain differences in some geochemical index, forming age of magma, and geotectonic position of outcropping.

通过秦岭－昆仑造山带中的环斑花岗岩同世界元古宙环斑花岗岩的岩石学、岩相学、岩石地球化学和构造环境等方面的对比研究发现，二者具有相同或一致的特征：具环斑结构，属准铝、高钾、富碱岩浆，具双峰式岩浆组合，形成于后碰撞环境，但其地球化学的某些指标、岩浆形成时代和出露的大地构造位置等有一定差异。

Having or consisting of rings or ringlike segments.

环状的，由环构成的有环或环形部分的，由环或环形部分构成的

A ringlike figure, part, structure, or marking, such as a growth ring on the ''.

环状物环状物、部分、结构或标志，如鱼鳞上的生长环

What would he tell Judith and the children?

他将怎样告诉朱迪丝和孩子们呢？

I this is at that time, the opinion with peacockish true girl is full of in a heart.

这就是当时的我，一个心中布满虚荣的女孩子真实的想法。