环

So, the aromaticity of acenaphthenyl groups in C_2 gum should be the least. In order to explain the reason, quantum chemical calculation is utilized. The optimized geometrical structrures of condensed aromatics in C_1 gum, C_2 gum and C_3 gum are calculated at B3LYP/6-31G* levels. We find that some phenyl groups in acenaphthenyl groups are coplanar and have the largest conjugated structure.

为了解释其原因，我们利用量子力学方法进行了计算，研究了三种稠环基团在B3LYP／6-31G*基组水平下优化得到的几何结构，发现苊式多苯基苯基中的萘环和中间的苯环共面，电子离域性最大，而其他二者所有苯环都不共面，发生了明显地扭曲；同时，在优化几何结构的基础上，对三种化合物进行了前线分子轨道的分析，利用密度泛函理论方法(density function theory，DFT)计算了稠环基团的最高占有轨道和最低未占轨道之间的能量差，即能隙，发现C_2胶上苊式多苯基苯基的Eg最小，解释了C_2胶具有最好的辐射保护效果的原因。

So, by the Diels-Alder reaction of tetraphenylcyclopentadienone, acenaphthenecyclone and benzophenanthrenecyclone with the vinyl groups in C gum, three kinds of polymethylvinylsilicone oil with condensed aromatics are synthesized respectively: polymethylvinylsilicone oil with tetraphenylphenyl groups (called C_1 gum for short), polymethylvinylsilicone oil with acenaphthenyl groups (C_2 gum) and polymethylvinylsilicone oil with benzophenanthrene groups (C3 gum).

根据此原则，利用四苯基环戊二烯酮、苊式环戊二烯酮和菲式环戊二烯酮与C胶上的乙烯基进行Diels—Alder反应，分别合成了三种含稠环基团的乙烯基硅油：四苯基苯基乙烯基硅油(C_1胶)，苊式多苯基苯基乙烯基硅油(C_2胶)和菲式多苯基苯基乙烯基硅油(C_3胶)，并根据~1HNMR谱图上不同氢原子的积分面积计算了三种胶中稠环基团和乙烯基的含量。

METHODS: Mono-6-O-tosyl-β-CD and mono-6-formyl-β-CD were synthesized separately. Silylatedβ-CD was loaded onto polymer chain of PVA by acetalization to produce PVA containingβ-CD linear high polymer.

分别合成单6-对甲基苯磺酰β-环糊精酯和单6-甲酰基β-环糊精，利用缩醛化反应将醛基化β-环糊精固载到聚乙烯醇大分子链上，合成出聚乙烯醇固载β-环糊精的线性环糊精高分子。

During the investigation of the reactivity of O_SCl_2(PPh_3)_2CH=C(PPh_3CHCH=CH_2 and O_SCl_2(PPh_3)_2CH=C(PPh_3C(=CH_2)CH=CH2, several stable osmacycles with novel structure, such as osmabenzenes, osmafurans, osmacycles containing intramolecular-coordinated allene, intramolecular-coordination osmacycles containing osmacarbene, an osmacyclopentadiene, were isolated during the investigation of the reactivity of O_SCl_2(PPh_3)_2CH=C(PPh_3CHCH=CH_2 and O_SCl_2(PPh_3)_2-CH=C(PPh_3C(=CH_2)CH=CH_2.In addition, some convenient and efficient methods to prepare these osmacycles were developed.

首先，合成出两种具有反应活性的金属杂五元环IC配合物OsCl_2(PPh_3)_2CH=C(PPh_3CHCH=CH_2和OsCl_2(PPh_3)_2CH=C(PPh_3C(=CH_2)-CH=CH_2，并对它们进行了系统表征；进而，研究了这些活性五元配合物的反应性，合成出多种稳定的锇杂环配合物，其中包括锇苯、锇呋喃、含配位联烯的锇杂IC环化合化物、含锇卡宾的IC环化物、首例锇杂环戊二烯化合物等多元化的产物。

III. Studies on the total synthesis of macrophllin type of bicyclo[3, 2, 1] octanoid neolignans ( C-4': endo ) The first total synthetic route of macrophllin type of bicyclo[3, 2, 1]octanoidneolignans ( C-4': endo ) was established based on the rearrangement ofbenzofuranoid and bicyclo[3, 2, 1]octanoid neolignans.

三、Macrophllin型双环[3，2，1]辛烷类新木脂素(C-4'桥环为endo)的全合成研究利用氢化苯骈呋喃类新木脂素和双环[3，2，1]辛烷类新木脂素的重排关系，首次建立了macrophllin型双环[3，2，1]辛烷类新木脂素(C-4'桥环为endo)的全合成路线。

In this thesis, we shall study the isomorphism property of chordal ring networks and we shall find out the diameter of some directed chordal ring networks and the diameter of some mixed chordal ring networks.

在这篇论文里，我们首先推导「有向的弦环式网路」以及「混合的弦环式网路」的同构性质；我们接著得出某些特殊的「有向的弦环式网路」以及「混合的弦环式网路」的直径，与之前文献不同的是，我们并不需要先计算出对应的「双环式网路」的直径来得出这些直径。

The author found that the chromone ring could be cleaved at high temperature in PPA, and the change of the ratio of ring-opened product versus the target one with the change of reaction time and temperature was investigated in details.

我们采用了两条不同的合成路线合成了第Ⅳ类化合物，对部分反应条件进行了优化，在研究过程中发现了色酮化合物在高温下的开环反应及多聚磷酸的水解作用，并对前者进行了详细研究了，获得了不同反应温度和时间下未开环产物和开环产物的比例，得到了制备相应的未开环产物和开环产物的最佳反应条件。

Photoinduced Electron Transfer [2+2] Cycloaddition Reactions ofBenzannelated Isoquinolin-1-ones with Electron Deficient Alkenes Photoinduced [2+2] cycloaddition reactions of 11H-benzoxazolo[3,2-b]isoquinolin-11-one 8 and 11H-benzothiazolo[3,2-b]isoquinolin-11-one 13 with electron deficient alkenessuch as acrylonitrile, methyl acrylate, dimethyl fumarate and dimethyl maleate afforded a group of polycyclic isoquinoline derivatives bearing cyclobutane moieties ingood to excellent yields and resulted in the Schenck isomerization of the alkenes.

3苯并增环异喹啉-1-酮与缺电子烯烃的光诱导电子转移[2+2]环加成反应 11H-苯并恶唑[3，2-b]异喹啉-11-酮8和11H-苯并噻唑[3，2-b]异喹啉-11-酮13与缺电子烯烃如丙烯腈，丙烯酸甲酯，富马酸二甲酯及马来酸二甲酯的光诱导[2+2]环加成反应以高产率给出一系列含有环丁烷结构单元的多环异喹啉衍生物并导致烯烃的Schenck异构化作用。

A synthesis of 2-pentylidene cyclopentanone starting from cyclopentanone and n-valeraldehyde through aldol condensation, followed by dehydration, was studied, and the yield reached 85.6%. 2-Pentenyl cyclopentanone was prepared in a yield of 95.0% from 2-pentylidene cyclopentanone with a hydrogenation methodology. Through Baeyer-villiger oxidation,δ-decalactone was synthesized in a yield of 63.9% from 2-pentenyl cyclopentanone with hydrogen peroxide.

研究了以正戊醛和环戊酮为起始原料，经羟醛缩合、脱水反应合成2-戊叉环戊酮，产率达到85.6%，2-戊叉环戊酮加氢制备2-戊基环戊酮，产率为95.0%，2-戊基环戊酮在双氧水作用下经Baeyer-villiger氧化重排反应合成δ-癸内酯，反应产率为63.9%，合成δ-癸内酯的总产率为52.0%，气相色谱分析纯度为98.7%。

After an investigation on the epoxidation of 33 and subsequent oxane ring opening, the 〓,〓-dihydroxyl group was successfully introduced, in accordance with the diaxial rule.

考察了33的环氧化和环氧开环反应，利用环氧开环的双直立规律，成功引入了符合设计要求的〓双羟基。

Shop assistant: Please check at the door.

店员：请您到门口柜台交费。

In the end, transportation of PAHs in the environmental matrix was preliminarily investigated and discussed according to PAHs data of soils and sediments from a certain region in Shanghai. The result indicated that there are two or more pathways on PAHs transportation in the environmental matrix.

最后，对上海特定地区内PAHs在环境介质中的迁移径途进行了分析讨论，结果表明上海市土壤和沉积物等环境介质中PAHs的迁移存在多种途径。