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Based on major and trace elements and isotope geochemical data, it is inferred that Sandouding suite is formed by magma melting of Late Archeozoic continent tholeiite source, and its geochemical variation is controlled by hornblende fractional crystallization. Besides fractional crystallization, the geochemical variation of Huanglingmiao suite is related to the mixing between dacitic magma and felsic magma. Dalaoling suite is probably derived from early Precambrian volcanics.

根据岩石化学和同位素组成推断,三斗坪岩套的源岩主要是晚太古代大陆拉斑玄武岩,母岩浆相当于英安质,岩套内的成分变化主要受角闪石分离结晶作用控制;黄陵庙岩套除受分离结晶作用影响外,成分变化主要与英安质母岩浆和某种长英质岩浆的混合有关;大老岭岩套的源岩亦为早前寒武纪火山岩。

In this paper, the petrology, mineralogy and geochemistry of basic-ultrabasic volcanic rock, granite and skarn related to the Sn-Cu skarn-type ore and the vein-type ore in Laochang ore field have been researched systematically, some conclusions are summarized as follows:In Gejiu tin-polymetallic district, the middle Triassic volcanic rocks belonging to calc-alkaline basalt-tholeiite serie, mainly consist of pyroxene, hornblende, feldspar, chlorite and phlogopite; All the granites are peraluminous granites related to the Yanshanian collision-orogeny. Laoka granite closely related to the tin-polymetallic deposits emplaced in the post- orogenic.The metal elements show obviously vertical zones with the variety of skarn types in dimensional extension; The occurrence of garnet skarn and diopside skarn alternately developed in the horizontal zones of the contact between granite and carbonatite are mainly related to two factors: one factor is the infiltration metasomatism of post-magmatic hydrothermal solution, the another is the metrical strata of marble and calcic-dolomite developed in country rocks.

本文重点以老厂矿田中的接触带锡铜矿床和脉状矿床为研究对象,采用化学分析、ICP-MS、X射线粉晶衍射分析、电子探针等测试手段,对本区与成矿相关的基性-超基性火山岩、花岗岩、夕卡岩、电气石-石榴石等进行了系统的地质地球化学研究,研究表明:个旧矿区中三叠纪个旧组地层中的火山岩为钙碱性玄武岩-拉斑玄武岩系列,岩石为辉石-角闪石-长石-绿泥石-金云母组合;本区的花岗岩为过铝质花岗岩,主要与燕山期碰撞造山作用有关,锡多金属成矿与形成时代最晚、分异较好的花岗岩关系密切;本区夕卡岩中的有用共生组份随着夕卡岩类型及其矿物组合的不同具有明显的分带性。

To No. 20 are respectively black mudstone, black mudstone ( Caitun mining area of Benxi Basin,Paleozoic), dark grey gangue (Caitun mining area of Benxi Basin, Paleozoic), brown shale(Caitun mining area of Benxi Basin, Paleozoic), brown grey shale(The West Opencut Coal Mine of Fushun Basin, Cenozoic), grey silty mudstone(Haizhou Opencut Coal Mine of Fuxin Basin, Mesozoic), black grey gangue(Haizhou Opencut Coal Mine of Fuxin Basin, Mesozoic), grey yellow clay(Jianping County, Chaoyang City, its era to be determined), grey silicon slate( Qianshan Mountain of Anshan City, pre-Paleozoic), grey phyllite(Qianshan Mountain of Anshan City, pre-Paleozoic), granite-gneiss(Qianshan Mountain of Anshan City, pre-Paleozoic), granite(Mount Yiwulu, its era to be determined), diorite(Mount Yiwulu, its era to be determined), black basalt(The West Opencut Coal Mine of Fushun Basin, Cenozoic), dark purple andesite( Mount Guiyunhua of Zhuanghe City, Mesozoic), fragment of brick-tile-pottery-porcelain( from the building site of Panjin City), coal cinder( from the boiler room of Heji Road of Panjin City), cement( from the building site of Panjin City) and slag (from Bohai Stockroom of Liaohe Oilfield produced in Anshan City).

2-20号样品分别是黑色泥岩、黑色泥岩、深灰色煤矸石、褐色页岩、褐灰色油页岩、灰色粉砂质泥岩(阜新海州露天矿、中生代)、黑灰色煤矸石(阜新海州露天矿、中生代)、灰黄色膨润土、灰色硅质板岩、灰色千枚岩、花岗片麻岩、花岗岩、闪长岩、黑色玄武岩、暗紫色安山岩、砖瓦陶瓷碎片、粉煤灰、水泥、矿渣(鞍山产、取自辽河油田渤海库),这19个样品用来代表工业、采矿、冶炼、建筑等行业产生的固体废弃物。

The ophiolites can be divided into two groups at least; one lies in the Kuhai complex and intersected by Caledonian island granite, which may be attributed to Caledonian or pre-Caledonian ophiolite association; the other lies in the Early Permian — Early Triassic Ma'erzheng Fm. of Buqingshan Gr., including ultramafic rock, basalt, diabase dike and pelagic siliceous-argillaceous association, and Early Permian radiolarian are found in the silicates, which reflect that the time is Hercynian.

其中蛇绿岩组合至少可分出两套,其一就位于变质的苦海杂岩中,被加里东期岛弧型花岗岩侵入切割,可能属加里东期或前加里东期的蛇绿岩组合;其二就位于早二叠世—早三叠世布青山群马尔争组中,包括超镁铁质岩、玄武岩、辉绿岩墙及远洋硅泥质岩组合,其中硅质岩中发现有早二叠世放射虫,说明其形成于海西期。

The basalt is belong island arc tholeiite and series of the calc-alkaline,and have character of island arc in rare earth element and trace element.

玄武岩属岛弧拉斑玄武岩和钙碱性系列,属太平洋型钠质类型,稀土、微量元素显示具岛弧特征,大地构造位置为岛弧中心靠近大洋一侧,与南侧那拉提晚泥盆—早石炭世侵入岩共同组成火山弧,同为古亚洲洋向北俯冲的产物。

Basalts plot in tholeiite in A.I-Al〓O〓 diagram. They have enriched LREE patterns without negative Eu anomaly. Their Zr/Y=4.4~6.5,〓=0.70790~0.70146, Th>>Ta,εNd values are between -1.8 and +3.7, indicating continental contamination. Pb isotope characteristics are close to that of typical tholeiitic flood basalt in the world.

Al〓O〓图上落入拉斑玄武岩区;稀土配分为LREE富集型,均无负Eu异常,Zr/Y=4.4-6.5,〓=0.70790~0.70146;Th>>Ta,ε〓介于-1.80~+3.7之间,都显示了陆壳混染的影响,Pb同位素与世界上典型拉斑质溢流玄武岩比较接近。

Studies of petrology and petrochemistry indicate that such suit of volcanic rocks dominated by lattite belongs to shoshonite series to potassic alkali basalt series. Considering the stability of rocks and their associations, gentle stratum occurrence, fresh degree of rocks and comparatively clarity of horizons. this potassic volcanic stratum distributed over the Sailipu area is named as Sailipu Formation, and the age of which is early middle Pleistocene of Quaternary.

岩石学、岩石化学研究表明,这套火山岩是以安粗质熔岩为主的钾玄岩系列-钾质碱性玄武岩系列火山岩,岩石类型及岩石组合稳定,岩层产状平缓,岩石新鲜,层位相对清楚,故将其命名为赛利普组,属第四纪早-中更新世。

The original alkalic series of basalic magma evolutes into trachybasalt through crystallization differentiation of olivine and pyroxene, and the trachybasalt is transformed into alkalic rhyolite with remarkable Eu, Sr, Ba, Ti, P nagetive abnormalities through strong crystallization differentiation of plagioclase and also pyroxene Ti Fe oxides and apatite, all together leading to the loss of neutral (SiO 2=57%~63%) andesite and trachyandesite in the volcanic rocks in this area and appearance of bimodal volcanic rock combination feature.

原始碱性系列玄武质岩浆经橄榄石、辉石的结晶分异,向粗面玄武岩演化;粗面玄武岩经斜长石强烈的结晶分离作用,还有辉石、钛铁氧化物和磷灰石的分离结晶作用形成具显著Eu、Sr、Ba、Ti、P负异常的碱性流纹岩,导致本区火山岩缺失中性(SiO2=57%~63%)的安山岩和粗安岩,呈现双峰式火山岩组合的特点。

Over one hundred sixty volcanic cones,pyroclastic sheet,river valley lava and eight maars with phreatomagmatic eruption genesis distribute of Longgang volcano,Jilin Province.The volcanic rock of Longgang volcano is trachybasalt with very similar chemical composition(SiO2=48-50%).

龙岗火山区分布160多个玄武质火山渣锥,以及火山碎屑席、河谷熔岩和8个射气岩浆喷发的低平火山口-龙湾,所有火山岩为单一钾质粗面玄武岩(SiO2变化于48-50%)。

According to the research of Pb isotopic, the metallogenetic material mainly originated from the Permian basalts; the study of sulfur isotopic find that the sulfur of the basalt-type copper deposits and carbonaceous sedimentary interlayers-type copper deposits originated from both Permian basalts and evaporate of sedimentary section, S in bauxitic mudstone-type copper deposits originated from evaporate of sedimentary layers.

研究区三种类型铜矿的铅同位素示踪研究,成矿物质主要来自于邻近的二叠纪玄武岩;硫同位素研究结果显示,玄武岩型铜矿和含碳沉积岩夹层型铜矿中的硫有两种来源:二叠纪玄武岩和蒸发岩中的硫;而铝土质泥岩铜矿中的硫主要来源于沉积地层中蒸发岩的硫。

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