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物相变化

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The oscillation of the base level results in their relative variation of accommodation space and sedimentary alimentation. The variation rates of them have also changed, then lead to the difference of facies sequence, the degree of stratigraphic preservation and stacking pattern at the same territory in different ages, or the difference of phase area at different territories at the same age.

由於基准面的升降变化引起了可容纳空间与沉积物供给量的相对变化,相对应的可容纳空间变化率和沉积物供给率同时也发生变化,因而导致了在不同时期同一地区的地层在相序、保存程度和叠加样式上的差异,以及在同一时期内不同地区在相域上的差别。

On the basis of the kinetic equation of substrate reaction in the presence of urea or guanidine hydrochloride, all microscopic kinetic constants for the free enzyme and enzyme-substrate binary and ternary complexes have been determined. The results of the present studies indicate that:①In the presence of urea or guanidine hydrochloride, enzyme-substrate complexes lose their activity less rapidly than the free enzyme. Therefore, both substrates, NADPH and 7, 8-dihydrofolate, protect dihydrofolate reductase against inactivation.②The denaturation of dihydrofolate reductase by urea follows single-phase kinetics, and changes in enzyme activity and tertiary structure proceed simultaneously in the unfolding process, so it may be an"all or none"process.③The GdnHCl-induced unfolding of the dihydrofolate shows a biphasic transition, while the change in the enzyme activity is a single exponential process. The rate constant of inactivation is consistent with that of the fast conformational change. Therefore, the kinetic intermediate of protein unfolding should be a partially folded and inactive form.

我们根据在脲或盐酸胍存在下的底物反应动力学方程求得游离酶和酶底物二元、三元复合物的微观动力学常数,结果表明:①酶-底物二元、三元复合物的失活速度明显慢于游离酶,说明两个底物二氢叶酸和NADPH对酶的失活都具有一定程度的保护作用;②在脲作用下,酶的失活和构象变化均为单指数项过程,而且酶的活力丧失和三级结构变化是同时发生的,说明二氢叶酸还原酶的脲变性可能是一个"全或无"的两态过程;③在盐酸胍作用下,酶的构象变化为两相过程,而失活则是单指数项过程,酶分子构象变化的快相速度常数与失活速度常数基本一致,因此我们认为二氢叶酸还原酶的盐酸胍变性过程中存在一个没有活力、但仍具备一定空间结构的变性中间体。

According to the natures of the 3rd-sequence, two kinds of facies-change surfaces and two kinds of diachrononism in stratigraphical records, the sequence stratigraphic framework can be established.

在前人岩相古地理研究的基础上,根据三级层序的两大特征——"空间上相序的有序性和时间上环境变化的同步性",并考虑到地层记录中的两种相变面和两种穿时性――"静态相变面及其相变面穿时、动态相变面及其间断面穿时",建立研究区域志留系的层序地层格架,并在此基础上从沉积物的时间演化序列和沉积相的空间展布形式入手,恢复其古地理背景。

The above method can be used as a general method of determining molecular weight distribution of polymers.4.Solid-state ~1H wide-line NMR and ~(31)p magic angle spinningNMR were applied to a series of PEI/DNA complex samples with different PEI molecular weights and nitrogen/phosphatemolar ratios,in order to disclose the influence of various structural factors on the interactions and morphology.The results of ~1H NMR spectra showed that the linewidth of the PEI signal was greatly broadened with increasing the N/P ratio.Meanwhile,in the ~(31)p M_AS experiment,the signal was found to shift upfield with the increase of the N/P ratio.Both ~1H and ~(31)P NMR experiments demonstrated that the interaction between two constituents and subsequently the morphology of the complexes vary with the N/P ratio.

首次将固体核磁共振应用到聚合物/DNA复合物体系,观察复合物体系中不同N/P比对其相互作用和相结构的影响,研究表明N/P比的变化对聚乙烯亚胺/DNA基因递送体系分子水平上相互作用有着很大的影响;另外,还发现不同分子量的聚乙烯亚胺聚合物载体在N/P比为3的情况下对复合物中DNA的微观尺度没有明显影响;通过氢的自旋扩散实验,首次测得在PEI/DNA复合物体系中DNA相尺寸的大小,并发现在体系中N/P比达到3以上的复合物中DNA和PEI达到了分子水平上的相容。

With the rich sediments supplied by the Pearl River, under the paleogeography sedimentary background of Baiyun Sag continuously subsiding, with sedimentary sequences related to relative transgressive sea level change ,contrary to regressive eustasy, the Pearl River Deepwater Fan System has specific evolution characteristics, which left the sedimentary record controlled by peripherical significant geological events. The sharp change of deposition rate and lithologic geochemical characteristics about 23.8Ma sequence boundary demonstratesd that sediment source had changed, perhaps related to the uplift of Tibet plateau and spreading of the South China Sea, which led the paleoPearl River drainage to expand to western China plateau , maybe much broader than present.

珠江深水扇系统以珠江为沉积物源、以持续深沉降的白云凹陷为沉积古地理背景、以与全球海退型海平面相反的相对海侵型海平面变化的沉积层序构成了其发育演化的特殊性,并留下了控制沉积的周边重要事件的记录。23.8 Ma等界面沉积速率和岩石地球化学特征均有突变,反映出物源区的变化,可能折射出与青藏高原隆升、南海扩张有关的重要事件,使得古珠江骤然向西部高原拓展,甚至较今天的珠江流域范围还广阔;承载珠江深水扇系统的白云凹陷持续沉降形成了陆坡内盆地,导致21~10.5 Ma BP多个层序深水扇垂向叠置充填的特殊沉积建造;根据60多口井资料建立的相对海平面变化曲线,具有与全球海平面变化相一致的三级旋回和不一致的二级旋回。

With the rich sediments supplied by the Pearl River, under the paleogeography sedimentary background of Baiyun Sag continuously subsiding, with sedimentary sequences related to relative transgressive sea level change ,contrary to regressive eustasy, the Pearl River Deepwater Fan System has specific evolution characteristics, which left the sedimentary record controlled by peripherical significant geological events.

珠江深水扇系统以珠江为沉积物源、以持续深沉降的白云凹陷为沉积古地理背景、以与全球海退型海平面相反的相对海侵型海平面变化的沉积层序构成了其发育演化的特殊性,并留下了控制沉积的周边重要事件的记录。23.8 Ma等界面沉积速率和岩石地球化学特征均有突变,反映出物源区的变化,可能折射出与青藏高原隆升、南海扩张有关的重要事件,使得古珠江骤然向西部高原拓展,甚至较今天的珠江流域范围还广阔;承载珠江深水扇系统的白云凹陷持续沉降形成了陆坡内盆地,导致21~10.5 Ma BP多个层序深水扇垂向叠置充填的特殊沉积建造;根据60多口井资料建立的相对海平面变化曲线,具有与全球海平面变化相一致的三级旋回和不一致的二级旋回。

The results show that molecules of PEO〓 have priority to locate at the interface of PVF〓/PVC to reforce their interaction when content of PEOx was less than saturated concentration in the interface , and PEOx joined into the PVF〓 phase and /or the PVC phase; the particles size of dispersed phase, PVC, became larger when C was more than Cs; the blend became miscible when C was much more than Cs.

结果表明,aPS与sPS的非晶区相容,共混物中不存在aPS的独立相区;共混物的熔点及长周期不随共混物aPS含量的变化而有所改变;sPS的纤晶结构单元没有变化,共混物结晶度下降,aPS处于sPS的纤晶之间;sPS为α-晶型,其晶胞结构参数在共混前后不变,aPS没有进入到sPS的晶胞中。

Second is studying the traumatic condition changes in a choosey pressure at different post-PT phases. Moreover, we detected model PLA_2 activity, express of PLA_2 subtype mRNA by fluorescent quantitative RT-PCR technique, protein express and site by Western blot and IHC at different post-PT phases. At last, we studied the PLA_2 inhibited effects and model protection of Variabilin in vivo.

研究在不同压强的外力作用下,模型指定时相点的一般情况和存活率、大体、光镜及电镜下胰腺组织的病理变化和常规酶学变化,得到稳定建模致伤压强;然后,固定致伤压强,研究胰腺创伤后不同时相点的伤情变化(包括一般情况、胰腺组织的病理变化、AMS和LPS活性变化、血常规、血生化、胰腺细胞凋亡以及胰腺组织细胞生长周期变化情况);再次,采用3H-花生四烯酸标记大肠杆菌膜作为底物的方法检测大鼠胰腺创伤后不同时相点的PLA_2活性,利用荧光定量RT-PCR技术检测其亚型mRNA的表达,利用Western blot和IHC技术检测其蛋白表达量和蛋白组织定位;最后,将Variabilin体内应用于急性胰腺创伤大鼠模型,研究其对模型的保护作用和对PLA_2的抑制效应。

At certain temperature and hydrogen flow rate, the weight changing of tungsten trioxide during the reduction was investigated by thermo balance, and the phase transformation analyzed by means of XRD.

在一定的温度和氢气流量条件下,用热分析天平精确测量WO3 还原反应过程中,不同时间的质量变化,并用X射线衍射分析进行物相鉴定,绘制纳米级WO3 (粒径≤ 5 0nm)的还原动力学曲线。

Based on the study of chronology and geochemistry of Cd in sediments of the Dongting lake area, we have established an ARIMA model of Cd and Cd/Ca in Quaternary and Holocene period respectively, and discussed Cd evolutionary regularity according to the fitted value and predicted value of the model The results revealed that the Cd evolution has remarkable periodicity of ecogeochemistry cycles, and is correlated with the climate change of alternative cold and warm Cd/Ca is changed with climate, from which the evolutionary history of regional ecogeochemistry can be inferred The changes of Cd and Cd/Ca are basically simultaneous, which showed that the change of Cd is mainly a natural evolution Cd in sediments will rise in the next 30 years and then tend to decrease From the regularity of ecogeochemistry indexes and global environment variation, it is concluded that the natural environment is the dominant factor affecting the Cd deposition

在对洞庭湖区沉积物钻探取样的年代学和地球化学研究基础上,分别建立第四纪和全新世时期Cd和Cd/Ca的时间序列演化ARIMA模型,并据模型的拟合值及未来预测值对区域地球化学环境中Cd的演化规律进行了探讨,结果显示区内Cd的演化有较显著的周期性--环境地球化学旋回,与气候多次冷暖的交替有关;沉积物Cd/Ca受气候环境等控制,分析该比值的变化规律可推测区域环境地球化学的演变历史;Cd和Cd/Ca两者的变化基本同步,说明该区Cd的演化主要为自然演化;未来30年内沉积层的Cd含量仍有逐渐增高的趋势,之后转为降低。从本区环境地球化学指标的时间变化规律及其与全球环境变化的相关联中说明自然条件是区域镉等元素沉积的主控因素。

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Lugalbanda was a god and shepherd king of Uruk where he was worshipped for over a thousand years.

Lugalbanda 是神和被崇拜了一千年多 Uruk古埃及喜克索王朝国王。

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