物

The results indicate that the weak election-withdrawing group 4-hydroxymethyl in 4-position of pyridine in 4-HMDPA could weaken the fluorescence intensity of the lanthanide complexes. The contradistinctive experimental results show that the fluorescence intensities of these complexes are related to pH value of the aqueous solution and the dipole moment of solvent molecule: in the neutral aqueous solution,the fluorescence intensities of these complexes were strongest,while the less the dipole moment was,the stronger the fluorescence intensity was.

结果表明，在吡啶4位引入弱吸电子基团4-羟甲基会减弱稀土配合物的荧光强度；在水溶液中稀土配合物与溶液的pH值有着密切的关联，中性水溶液中荧光强度较大；分子偶极矩较小的溶剂中稀土配合物荧光强度较强。

Furthermore, the structures of the complexes are strange. The tripodal ligand H〓L〓 form a 2: 2 ring-like binuclear complexes [Eu〓·L〓·6DMF] ·CH〓OH·DMF with Eu〓 in DMF. Two DMF molecules are accommodated in the ring and coordinate with Eu〓.

此外配合物的结构还比较特殊，三足配体H〓L〓与铕的配合物在配位能力较强的溶剂DMF中形成环状的2：2型双核配合物[Eu〓。L〓·6DMF]·CH〓OH·DMF，环状空腔刚好能够把两个配位的DMF溶剂分子包在里面。

Using a comparative and simulative approach, this study quantitatively explored the effects of macrobenthos (Ilyoplax deschampsin and Corbicula fluminea) on the exchange of nitrogen across the sediment-water interface and the early diagenesis of nitrogen in tidal sediments from the Yangtze Estuary....

研究表明，谭氏泥蟹主要通过掘穴活动增加沉积物-水-气三相接触界面，促进沉积物中的无机氮(NH+ 4- N、NO- 2 -N和NO- 3- N)向上覆水体中扩散，并且也加快了沉积物中氮的氨化作用和硝化作用速率，而河蚬则主要通过生理活动机制影响潮滩生态系统内氮素的迁移转化过程。

Corbicula fluminea however affected the exchange of nutrient nitrogen across the sediment-water interface by the physiologic mechanism such as the excretion. Crabs such as Ilyoplax deschampsin changed the physical structure of the tidal flat sediments by the strong bioturbation, and increased the content of dissolved oxygen in the sediment by enhancing the touched area of sediment and air.

谭氏泥蟹主要通过生物扰动，增加沉积物-水-气三相界面之间的接触面积，促进沉积物界面附近营养盐物质交换过程；而软体动物河蚬则主要通过生理活动，影响潮滩沉积物中氮营养盐的界面扩散过程。

Wherever sediment cores were collected by gravity corer,the length of the cores became shorter than the original length,and this compaction processes take place not only inside the sampling tube but also beneath the bottom of the sampling tube.

其中，采集柱状样是传统的、也是最主要的一种手段[6]，通过分析柱状样沉积物可以获得相关的沉积环境和沉积动力[7]、沉积物组分的的变化[8~9]、沉积物

The gravity or shake corer can be adopt for the soft sediment, and the rotary corer for the hard sediment; 3 carry out the core transfer technique under pressure.

对松软的非岩性沉积物采样时，可采用重力驱动或震动冲击驱动保真采样装置；对硬质岩化的沉积物采样时，可采用回转式保真采样装置。3）重点开展沉积物样品无压降转移技术。

And the preparing method has the steps of: fixing the charge transfer complex on a scanning tunnel microscope, starting up the cut mode of the scanning tunnel, controlling the motion of pointer of the scanning tunnel, applying a voltage pulse between the charge transfer complex and the pointer, writing the information hole array in the charge transfer complex.

按如下过程进行制备：将电荷转移复合物固定于扫描隧道显微镜上，启动扫描隧道显微镜的刻写模式，控制扫描隧道显微镜的针尖的运动，在电荷转移复合物和针尖之间施加电压脉冲，在电荷转移复合物上写入信息孔阵。

The thermolysis of the isomerized products derived from norbornadiene-coordinated carbonyl iron complexes gave two sorts of the thermolytic products based on different substituents on the olefin ligands. One is the corresponding diiron dimer complex, and the other is the complex in which the C-C bond of the cycloolefin ligand is broken.

以降冰片二烯三羰基铁络合物衍生出来铁卡宾络合物的异构化产物的热解，随着烯烃配体上取代基的不同，而分别得到了络合物发生二聚和烯烃配体发生碳碳键断裂的两类热解产物。

The results show that degradation by complexes made from monosacchrides, such as fructose and galactose, and Ce is better than thos e from other saccharides, and that the complex made from cerium and component S4 , which was made from seaweed, can decompound met hamidophos and omethoate best.

结果发现，在各种糖铈配合物中，以果糖及半乳糖的铈配合物对甲胺磷的降解作用较好，达15%以上，其它糖类铈配合物均在5%以下。

These dendritic NOBIN derived Schiff base ligands have been applied to titanium catalyzed hetero-Diels-Alder reaction of Danishefshy's diene and aldehydes, affording the corresponding 2-substituted 2, 3-dihydro-4H-pyran-4-one in quantitative yields and excellent enantioselectivities (up to 97. 2%ee). Comparing the reactivities and enantioselectivities of reaction catalyzed by the titanium complexes of these Schiff base ligands, it was found that a series of ligands L〓 were superior to the other three series of ligands L〓, L〓 and L〓, a significant positive NLE and a dendrimer effect existed in the L〓 dendritic catalyst system. The disposition of the dendritic wedges and the dendron size in the ligands were observed to have a significant impact on the enantioselectivity of the reaction.

NOBIN衍生的树枝状大分子希夫碱手性配体与钛形成的配合物在催化不对称杂Diels-Alder反应中的应用将得到的四个系列NOBIN衍生的树枝状希夫碱三齿手性配体与四异丙氧基钛形成的配合物用于催化Danishefsky's diene与醛的不对称杂Diels-Alder反应，通过反应条件的优化，获得了定量的收率和最高达97.2％ee值的对映选择性；考察了这四个系列NOBIN衍生的树枝状希夫碱钛配合物的催化活性和对映选择性，结果发现它们的活性次序依次为L〓≈L〓＞L〓＞L〓，对映选择性次序依次为L〓＞L〓＞L〓＞L〓。

Plunder melds and run with this jewel!

掠夺melds和运行与此宝石！

My dream is to be a crazy growing tree and extend at the edge between the city and the forest.

此刻，也许正是在通往天国的路上，我体验着这白色的晕旋。