物

It isconfirmed by ~1H NMR,~(13)C NMR and X-ray crystallographic analysis that complexes 60-63are monopyridine complexes and show distorted square pyramid geometries; complexes 64and 65 are bispyridine complexes and show pseudo-octahedral geometries, where twopyridine ligands are in cis arrangement and trans to the NHC and the benzylidene ligandrespectively, the bond length between ruthenium and pyridine ligand trans to the benzylideneligand is 16 pm longer than the bond length between ruthenium and pyridine ligand trans tothe NHC ligand.

1H NMR、~(13)C NMR及X射线单晶衍射分析证明，配合物60-63是单吡啶衍生物配位的钌卡宾配合物，具有变形的四方锥构型；配合物64、65为双吡啶衍生物配位的钌卡宾配合物，具有变形的八面体构型，其中两个顺式配位的吡啶衍生物分别处于氮杂环卡宾和苯亚甲基的反位，处于苯亚甲基反位的吡啶衍生物对应的钌-氮键长要比处于氮杂环卡宾反位的长出16 pm。

In the same time, water-soluble bidental phosphines ligand BISBIS sulfonated 2,2''-bis(diphenylphosphinomethyl-1,1''-biphenyl was synthesized, and water-soluble rhodium complex Cl was synthesized in situ. This complex which was used as catalysts to catalyze the hydrogenation of avermectin was also tested. Although the rhodium complex containing bidentate phosphine BISBIS showed a higher catalytic activity than one containing TPPDS, the selectivity for ivermectin was lower. How to improve the selectivity will be needed to studied in futur.

同时我们用磺化的2，2''-二-- 1，1''--联苯，以及它们的水溶性威尔金森型铑配合物和环辛二烯的阳离子铑配合物，在利用这些配合物作催化剂，考察它们在各种反应条件下对阿维菌素的选择加氢，由于反应条件以及复合催化剂体系的组成还需要进一步优化，虽然双齿膦配合物显示了较高的活性，然而选择性还有待进一步提高。

Extracts with higher antioxidant abilities, including hot water and ethanol extracts of Boehmeria nivea leaves and roots, were screened and then added into soy bean oil to study effects on oil stabilities of oxidation during storage and also to develop new XO paste products containing Boehmeria nivea leaves and roots. The extents of oil oxidation in XO paste were evaluated by measuring POV and TBA values. Results indicated that after 8 day storage at 70℃, the POV values of soy bean oil with addition of 0.1% of ethanol extracts of leaf and root were 56.27± 0.12 meq/kg and 57.13± 0.50 meq/kg respectively, which were both greater than that of control samples(53.33 ±0.31 meq/kg), showing that extracts of leaf and root do not have the abilities to inhibit oxidation of soy bean oil.

第二部分将抗氧化能力较高的萃取物，包括苎麻叶与根的热水及乙醇萃取物添加於大豆油中，探讨其对油脂贮藏安定性之影响及开发加入苎麻叶或根的XO酱产品，并藉由测定油脂中过氧化价(peroxide value，POV)和硫巴比妥酸值(thiobar-bituric acid value，TBA)值评估其油脂氧化程度，结果贮存在70℃下第8天时，添加0.1 %苎麻叶与根乙醇萃取物，其POV值分别为56.27±0.12 meq/kg与57.13±0.50 meq/kg，皆较对照组(53.33 ±0.31 meq/kg)高，显示以0.1 %的苎麻叶和根萃取物添加大豆油中并不具抑制油脂氧化作用。

They are derived from the condensation of salicylaldehyde with naphthalidine, 2-cyano-4-chloroaniline, o-Toluidine, N-aminoethylmorpholine, benylamine, butylamine, cyclopentylamine and 3-carboxysalicylidene with N-aminoethylmorpholine, benylamine, 2-hydroxyaminoethylamine, ethylenediamine, respectively.

得到了HL1、HL2和HL3配体的单晶；培养出了HL3～HL6、H2L11的Cu配合物，HL7～H2L11的Co配合物和H2L11的Ni配合物的单晶。此外，以5-溴水杨酸(5-bsa)、2-氨基苯甲酸(2-aba)、六次甲基四胺等为原料，合成了3种过渡金属Ag配合物，并培养出了其单晶。

A total of 614 sediment samples at an interval of about 1.5 m from all 5 sites of the Integrated Ocean Drilling Program Expedition 311 on Cascadia Margin, northwestern Pacific were analyzed using a Beckman Coulter LS230 Particle Analyzer. The grainsize data were then plotted against depth and compared with other potential proxies of gas hydrateoccurrence such as soupy/mousselike fabrics in sedimentary textures, gas hydrate concentration derived from LWD data using Archie's relation, IR core images and the recovered samples of gas hydratebearing sediments.

对取自IODP 311航次（东北太平洋Cascadia大陆边缘）所有5个站位、采样间距约为1.5 m的614件沉积物样品，利用Beckman Coulter LS230激光粒度仪进行了沉积物粒度分析，获得了沉积物粒度随深度变化特征，进而与水合物层位的替代指标进行了位置对比，这些指标包括特殊沉积构造（soupy和mousselike构造）、测井数据推算出来的水合物饱和度、岩芯红外图像和实际钻取的含水合物沉积物等。

A total of 614 sediment samples at an interval of about 1.5m from all 5 sites of the Integrated Ocean Drilling Program Expedition 311 on Cascadia Margin, northwestern Pacific were analyzed using a Beckman Coulter LS-230 Particle Analyzer. The grain-size data were then plotted against depth and compared with other potential proxies of gas hydrate-occurrence such as soupy/mousse-like fabrics in sedimentary textures, gas hydrate concentration S(subscript h derived from LWD data using Archie's relation, IR core images and the recovered samples of gas hydrate-bearing sediments.

对取自IODP311航次（东北太平洋Cascadia大陆边缘）所有5个站位、采样间距约为1.5m的614件沉积物样品，利用Beckman Coulter LS-30激光粒度仪进行了沉积物粒度分析，获得了沉积物粒度随深度变化特征，进而与水合物层位的替代指标进行了位置对比，这些指标包括特珠沉积构造（soupy和mousse-like构造）、测井数据推算出来的水合物饱和度S(下标 h、岩芯红外图像和实际钻取的含水合物沉积物等。

Sn with the content of 0.004% in the lithosphere is almost in presence of cassiterite and little in presence of Sn-contained sulfide. Since 1980s, the anticancer active study on organic complex compounds has attracted considerable attentions, it becomes another hot issue after the study on Pt. When time up to the year 1989, the anticancer active measurement of more than 2000 kinds of Sn-contained complex compounds have been carried out by Cancer Academy, U.S, with the results showing half of these Sn-contained complex compounds posses antileucocythemia(P388) activity. Thereafter, Sn-contained complex compounds synthesized by hydrothermal reaction also become a hot issue people focus on.

Sn在地壳中的含量为0.004%，几乎都以锡石的形式存在，此外还有极少量的Sn的硫化物。20世纪80年代以来，人们对Sn有机配合物抗癌活性的研究产生了浓厚兴趣，成为继顺铂之后又一活跃的研究热点，到1989年，美国国家癌症研究所对2000多种Sn的配合物进行了抗癌活性测定，结果表明，50%的配合物具有抗P388白血病活性，故水热溶剂热合成锡的配合物也成为人们的研究热点。

Our purpose is simulating the catalytical action of enzyme in biologic system, so we can directly investigate the factors relating to the functions of enzyme by studying the catalyzing behavior of model molecules imitating enzyme\'s functions. And it is a base of synthesizing high performance model enzyme.

从得到的实验数据我们可以看出：锌是酯水解反应的活性中心；并且金属中心相同时，配位数相同的配合物，结构越简单，其催化酯水解效果越好；含有配位不饱和金属中心的锌配合物表现出更好的催化效果；配合物中咪唑基团的存在可有效的增强这个配合物催化酯水解的效果。

The invention is characterized in that the molecule of the polymer adsorption material has a structure in formula I: in the formula, R is selected from the natural polysaccharides with amino groups and hydroxyls and the derivatives thereof or the chemosynthetic polymers, the molecular weight of which is from 6 KD to 500 KD; X is selected from a C0 to C6 paraffinic chain with O atoms, N atoms or OH groups; R1, R2 and R3 are selected from a C1 to C4 alkyl group.

生物医学材料领域中的水溶性阳离子多聚物吸附材料及其应用，包括采用带有氨基或羟基的天然多糖及其衍生物或者化学合成多聚物季铵化反应合成，其特征在于该多聚物吸附材料分子具有式的结构：式中，R选自粘均分子量范围为6KD～500KD的带有氨基或羟基的天然多糖及其衍生物或者化学合成多聚物；X选自含有O原子、N原子或者OH基团的C 0 ～C 6 烷链；R 1 、R 2 、R 3 选自C 1 ～C 4 的烷基。

Excitation-Emission Matrix Fluorescence Spectroscopy was employed to study fluorescence characteristics of chromophoric dissolved organic matter readily released from sediment particles during episodes of resuspension, and bottom waters and surface sediment pore waters were compared in all corresponding sites.

对采自厦门湾九龙江入海河口的4个沉积物样品进行了室内再悬浮模拟实验，利用荧光激发－发射矩阵光谱研究了再悬浮过程中从沉积物中释放出的有色溶解有机物的荧光特征，同时通过与相应站位沉积物间隙水和底层水的对比分析，探讨了河口近岸海域的沉积物再悬浮作用作为水体中溶解有机物来源之一的可能性。

I am accused of being overreligious," she said in her quiet, frank manner,"but that does not prevent me thinking the children very cruel who obstinately commit such suicide.""

客人们在卡罗利娜·埃凯家里，举止就文雅一些，因为卡罗利娜的母亲治家很严厉。

Designed by French fashion house Herm è s, this elegant uniform was manufactured in our home, Hong Kong, and was the first without a hat.

由著名品牌 Herm è s 设计，这件高贵的制服是香港本土制造，是我们第一套不配帽子的制服。