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This paper introduced the relationship of microcrystal structure of coke and its macroscopical properties, and the effects of coal rank and pyrogenation process on microcrystal structure etc.

对于焦炭,前者是指焦炭中的气孔、裂缝以及焦炭光学组织结构,后者则指焦炭的显微结构,包括类石墨片层的微晶单元及其空间排列方式等。

Coke properties has been studied by high temperature SiC oven、infrared gas analyzer and X-ray diffraction. First set forward the relationship between UPC and coke reactivity, strength, fine coke and coke graphitization, and creatively find the graphitization degree of coke tends to 100% when temp. reaches to 1350℃ UPC is profitableness to coke properties;②The effect of UPC on liquid slag distribution and flow functions in experiment oven has been studied by mathematics simulation The effect of UPC on taking shape and dropping of high titanium-bearing B. F. slag has been studied by using high temp. oven simulation cohesive zone and dropping zone of blast furnace.

为了弄清楚这部分UPC对高炉冶炼钒钛磁铁矿过程的影响,①在实验室利用高温SiC炉、红外线气体分析仪、X—射线衍射仪等进行了一系列UPC对焦炭性能及石墨化度的影响研究,提出了UPC与焦炭反应性、抗压强度、粉化性能及焦炭石墨化度之间的关系,创造性的发现高炉内1350℃以上,焦炭的石墨化度已达100%,UPC对焦炭性能的影响有益而无一害;②采用数学模拟方式研究了UPC对实验炉内液态渣分布及流函数的影响,并利用高温熔滴炉模拟高炉软熔带、滴落带研究UPC对高钛渣滴落性能的影响,采用旋转式粘度计测定滴落渣性能并通过高倍矿相显微镜观察了滴落渣的矿物结构。

The result showed when tail gas was burnt off, coke thermal reactivity was the highest, and the strength after reaction was the lowest, the burning of tail gas deduced with alcohol lamp was in the middle; when tail gas was bled, the thermal reactivity of coke was the lowest and the strength after reaction was the highest.

摘 要:研究了3种不同的尾气处理方式对焦炭热反应性和反应后强度的影响,结果表明,尾气在炉盖处大火烧掉时焦炭热反应性最高,反应后强度最低;尾气导出用酒精灯烧掉次之;尾气放散时焦炭的热反应性最低,反应后强度最高。

The experimental result shows that sulfuring rate from coke to hot metal reduces with witherite and CaCl2 addition in coke making, but the sulfuring rate increased with lime stone.

结果表明,在实验条件下,加入毒重石和CaCl2的焦炭能降低焦炭向铁水渗硫率,减少进入铁水中的硫含量;而加入石灰石的焦炭中硫进入铁水中含量较多。

But the CRI and CSR index of coke, used at present, is measured under the atmosphere of no alkali. In the different conditions, alkaline or not, the results of the selective reaction of coke microstructure are different,especially sometimes just opposit...

有碱或无碱存在,对焦炭显微结构的选择性反应序列有时是相反的,并发现∑ISO具有比各向异性结构更强的高温抗碱侵蚀的能力,而前者主要来自气煤类煤,后者主要来自强粘结性煤,因此认为,为了增加焦炭中∑ISO的含量,适当降低对M40(M25)、M10的要求,以达到多用气煤类煤,并改善焦炭的实际质量是可行的。

Using hydrotreated gas oil as solvent, under the conditions of a reaction temperature of 400 C, a hydrogen partial pressure of 10 MPa and a reaction time of 1 h, a portion of coke deposits could be removed yet without the function of hydrogenating coke.

采用溶剂萃取法除去工业失活催化剂上沉积的焦炭和金属的研究结果表明,用四氢呋喃、吡啶和喹啉这3种含杂原子的有机强溶剂常温萃取催化剂,其去除焦炭能力很弱,而且会因这些溶剂的强吸附作用污染催化剂;盐酸洗涤能有效去除催化剂表面的钙、铁沉积层,但不能去除焦炭;低芳香性的加氢瓦斯油在400 C、H2压力为10MPa、反应1h的条件下可部分去除催化剂上的焦炭,但不具备强的氢化焦炭作用;1,2,3,4-四氢化萘因具有供给原子氢的能力,可以有效地氢化和去除催化剂上的焦炭

Based on the recent practice on controlling coal ash content to improve coke quality, the possibility of increasing the ratio of weakly caking coal in blends is studied.

研究表明,在宝钢配煤中,当弱粘比由47%增加到63%,焦炭的冷强度几乎保持同一水平,同时由于增加了弱粘煤配比,相应增加了焦炭中抗高温碱侵蚀能力强的各向同性结构,有利于在高炉中保持焦炭结构、缓解焦炭劣化。

The combustion of coke sampling from a boiler of ethylene plant was studied on a laboratory unit. The effects of combustion temperature and oxygen flow rate on coke combustion were investigated. Four combustion promotors were prepared and added into the coke for proceeding the combustion test.

摘 要:采用国内某乙烯厂余热锅炉生成的焦炭为原料,在自行设计的焦炭燃烧试验装置中,对乙烯装置余热锅炉焦炭的燃烧过程进行研究,考察了温度、氧气流量等主要因素对焦炭燃烧的影响,并研究配制了4种具有良好助燃效果的助燃剂组分进行焦炭催化燃烧试验。

The combustion of coke sampling from a boiler of ethylene plant was studied on a laboratory unit. The effects of combustion temperature and oxygen flow rate on coke combustion were investigated. Four combustion promotors were prepared and added into the coke for proceeding the combustion test.

采用国内某乙烯厂余热锅炉生成的焦炭为原料,在自行设计的焦炭燃烧试验装置中,对乙烯装置余热锅炉焦炭的燃烧过程进行研究,考察了温度、氧气流量等主要因素对焦炭燃烧的影响,并研究配制了4种具有良好助燃效果的助燃剂组分进行焦炭催化燃烧试验。

The results indicate the mutual effect exists between the single coals, which could increase the maximum of thermal weight loss obviously and has a small effect on the temperature extent of the weight loss. The main pyrolysis production of coal is coke, but the main production of waste plastics is tar; the yield of water became decrease and the gas became increase by adding the waste plastics. And the CRI and CSR decreased with the ratio of waste plastics in coal. The main ingredients of tar from blend coal are aromatic hydrocarbon and alkane, while those of waste plastics are alkane and alkene. The result of co-coking with coal and waste plastics make the light tar and the aromatic hydrocarbon increase obviously. The combustible ingredient(CO、H2、CH4) of gas from co-coking with coal increase at different ratio; Co-coking with coal and waste plastics could increase the combustible ingredient and thermal value of gas.

结果表明,废塑料与煤混合物在煤的塑性温度区间内存在明显的相互作用,使最大热解失重峰迁移,热解速率变大,且随着废塑料配比的增加呈现规律性的变化;煤热解产物固体焦炭为主,而废塑料的热解产物以焦油为主,废塑料的添加使得总体焦炭和水产率下降,焦炉煤气和焦油的产率增加,即共焦化呈现出明显的&增油减水&效应;随着塑料添加量的增加,焦炭热强度呈现劣化趋势;废塑料代替瘦煤配煤炼焦可使其比例提高到3%而不影响焦炭的质量;纯煤焦化所得焦油以芳香烃类和烷烃类为主,而废塑料热解焦油以烷烃和烯烃为主;废塑料配煤炼焦,可使得的焦油呈现&环构化&和&轻质化&趋势;废塑料的添加可使煤气中的可燃组分(CO、H2、CH4)的含量均有不同程度的增加;废塑料配煤炼焦可以优化焦炉煤气的组成,增加煤气中的可燃组分,提高焦炉煤气的热值。

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