烷基锌

The present invention adopts ammonium salt solution as leach, and adopts the liquid-phase oxidation activating agent formed from surfactant sodium ligno-sulfonate or sodium dodecyl sulfonate, liquir phase oxidation catalyst Cu(2+) and sulfur-extracting agent tetrachloroethylene to implement quick leaching process of sulkfide mineral in gas-liquid-solid three-phase reactor, all the sulfurs contained sulfide in mineral powder can be converted into elementary sulfur and sulfuric acid radical, the contained zinc, copper, nickel, cobalt, lead, cadmium and silver can be changed into soluble salt, and fed into leach or remained in the leaching out slag.

本发明涉及的有色金属硫化矿的铵盐液相氧化直接浸出方法，其特征在于：采用铵盐溶液作浸出剂，采用由表面活化剂木质磺酸钠或十二烷基磺酸钠，液相氧化催化剂Cu2+、萃硫剂四氯乙烯组成的液相氧化活化剂，在气液固三相反应器内，实现硫化矿的快速浸出过程，矿粉中各种硫化物所含的硫转变为单质硫和硫酸根，所含的锌、铜、镍、钴、铅、镉、银等变成可溶性盐类进入浸出液中或留在浸出渣中，消除传统流程中二氧化硫，硫化氢，氮氧化物及含砷含汞含铅等有毒烟气的排放。

On the basis of investigating the developments of inorganic mesoporous material's syntheses and applications, mesostructured tin oxide, bismuth oxychloride, lead sulfide, bismuth sulfide, titanium phosphate and zinc phosphate were synthesized by Sol-Gel and hydrothermal techniques, employing the neutral surfactant organic amine and anion surfactant alkyl sulfonate as templates.

在对无机介孔材料的合成、应用等方面的发展现状进行了充分调研的基础上，本文运用溶胶一凝胶法、水热法等合成手段，选用中性表面活性剂有机伯胺和阴离子表面活性剂烷基磺酸盐为模板，制备了二氧化锡、氯氧化铋、硫化铅、硫化铋、磷酸钛、磷酸锌等无机介孔材料。

On the basis of investigating the developments of inorganic mesoporous material's syntheses and applications, mesostructured tin oxide, bismuth oxychloride, lead sulfide, bismuth sulfide, titanium phosphate and zinc phosphate were synthesized by Sol-Gel and hydrothermal techniques, employing the neutral surfactant organic amine and anion surfactant alkyl sulfonate as templates.

中文题名非硅基介孔材料的合成与表征副题名外文题名论文作者周书喜导师李健民学科专业物理化学研究领域\研究方向学位级别博士学位授予单位中国科学技术大学学位授予日期2003 论文页码总数92页关键词介孔材料介孔分子筛馆藏号BSLW /2003 /O643.3 /50 在对无机介孔材料的合成、应用等方面的发展现状进行了充分调研的基础上，本文运用溶胶一凝胶法、水热法等合成手段，选用中性表面活性剂有机伯胺和阴离子表面活性剂烷基磺酸盐为模板，制备了二氧化锡、氯氧化铋、硫化铅、硫化铋、磷酸钛、磷酸锌等无机介孔材料。

Zinc diamyl dithiocarbamate antioxidant showed good synergism with antimony diakyl dithiocarbamate antiwear additive in improving the oxidation stability of modified soybean oils. The incipient oxidation temperature and induction period time of genetically modified soybean oils were improved significantly by adding polyalphaolefin and additives, and they were even better than that of the synthetic base oil PAO with the same additive formulation.

结果表明，改性大豆油的不饱和脂肪酸含量越高，其氧化安定性越差；抗氧剂二戊基二硫代氨基甲酸锌和抗磨剂二烷基二硫代氨基甲酸锑在改性大豆油中均表现出了良好的抗氧协同性能，尤其在基因改性大豆油中，聚-α-烯烃和添加剂的复配使其起始氧化温度和氧化诱导时间均超过了相同配方的聚-α-烯烃油样。

The attack causes the cleavage of P-S double bonds, then the decomposition products reacting with the surface of Fe metal lead to the formation of the anti-wear and anti-friction film largely composed of polyphosphates and sulphides.

计算表明二烷基二硫代磷酸锌的活性元素为6位和7位硫原子，其与铁发生摩擦化学反应时，最可能的断键位置是6位和7位硫原子的双键。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。