烷基卤

Four extracting agents for Lanthanides/Actinides separation , dialkyldithiophosphinic acids, were synthesized from PSCl3 and alkyl halide by Grignard reaction, sulfuration and acidification.

以PSCl3和卤代烷为原料，经格氏反应、硫化和酸化合成了用于镧/锕分离的4个萃取剂——二烷基二硫代次膦酸，其结构经NMR，IR和MS表征。

The catalyst includes: supported Ziegler-Natta catalyst of titanium halide compound and organic electron donor compound supported with MgCl2 alcoholate carrier; aluminoxane prepared with trialkyl aluminum and water; and one kind of organic electron donor, such as organosilicon compound R2Si(OCH3)2, where R is phenyl, isopropyl, isobutyl or cyclopentyl.

该催化剂包括，a一种负载型的Ziegler-Natta催化剂，即将卤钛化合物和有机给电子体化合物负载在氯化镁醇合物载体上得到的固体催化剂，b一种通过三烷基铝与水反应而制备得到的铝氧烷和c一种有机电子给体，如有机硅化合物R 2 Si(OCH 3 ) 2 ，其中R为苯基、异丙基、异丁基或环戊基。

For the synthesis of NHC precursors, there are also several routes: condensation of glyoxal, amines and paraformaldehyde; alkylation of imidazole or monosubstituted imidazole with alkyl halide; annulation of ortho esters and 1,2-diamines; ring closure of hydrazines or amides with acetic anhydride; reduction of thiones with Na/K in THF.

关于N-杂环卡宾前体的合成途径主要有：乙二醛、伯胺和多聚甲醛的缩合反应；卤代烷与咪唑及其取代咪唑的烷基化反应；原甲酸酯与1，2-二胺的成环反应；肼或酰胺与酸酐的环化反应；用Na/K对环硫脲化合物的还原反应。

The probable reactions of the adamantane,for example halogenation , alcoholization, nitration and alkylation,are summarized.

文章从分子设计的角度综述了金刚烷可能发生的化学反应，如卤化、羟基化、硝化、烷基化等；同时探讨了金刚烷化学反应的机理，为金刚烷在精细化工领域的深层次应用打下基础。

The manufacture of chemicals from petroleum is based on the ready response of the various compound types to basic chemical reactions, such as oxidation, halogenation, nitration, dehydrogenation, addition, polymerization, and alkylation.

从石油生产化学品的依据是各种类型的化合物对各种基本的化学作用感应迅速，如氧化作用、卤化作用、硝化作用、脱氢作用、添加作用、聚合作用和烷基化作用。

The manufacture of chemicals from petroleum is based on the ready response of the various compound types to basic chemical reactions, such as oxidation, halogenation, nitration, dehydrogenation, addition, polymerization, alkylation.

从石油生产化学品的依据是各种类型的化合物对各种基本的化学作用感应迅速，如氧化作用、卤化作用、硝化作用、脱氢作用、添加作用、聚合作用和烷基化作用。

Ure of chemicals from petroleum is based on the ready response of the various compound types to basic chemical reactions, such as oxidation, halogenation, nitration, dehydrogenation, addition, polymerization, and alkylation.

从石油生产化学品的依据是各种类型的化合物对各种基本的化学作用感应迅速，如氧化作用、卤化作用、硝化作用、脱氢作用、添加作用、聚合作用和烷基化作用。

These novel reagents were treated with base to produce polystyrene-supported a-seleno carbanions, which reacted with alkyl halides, followed by stereospecific selenoxide syn-elimination to give 2i-vinylphosphonates and is-vinylsulfones respectively.

它们在碱的作用下形成α—硒基碳负离子，然后与卤代烃发生烷基化反应，烷基化后的树脂可以通过温和条件下的氧化消除以良好产率和较高纯度分别合成了烯基磷酸酯和烯基砜。

This novel reagent was treated with LDA to produce polystyrene-supported a-seleno carbanions, which reacted with alkyl halides and epoxides, followed by stereospecific selenoxide syn-elimination to give olefins and allylic alcohols respectively.

它与LDA反应形成α—硒基稳定的碳负离子，再与卤代烃或环氧化合物发生α—烷基化反应，烷基化后的树脂可以在30%的双氧水中进行氧化-消除，以良好产率和较高纯度合成了取代烯烃或烯丙基醇。

Firstly, Vinyl ethers were prepared in a one-pot, two-step transformation by O-alkylation reaction of 2-hydroxyalkyl phenyl selenides with primary or secondary organic halides followed by oxidation-elimination with 30 % hydrogen peroxide.

1.2-羟基烷基苯基硒醚和伯、仲卤代烃通过O-烷基化反应，然后用30％的双氧水进行氧化消除反应，提供了&两步、一锅法&合成烯基醚的新方法，该方法反应条件温和，操作简便，产物收率中等到良好(70-85％)。

The concept of equivalent rotationally rigidity is offered and the formula of rotationally rigidity is obtained.

主要做了如下几个方面的工作：对伸臂位于顶部的单层框架—筒体模型进行分析，提出了等效转动约束的概念和转动约束刚度的表达式。

Male cats normally do not need aftercare with the exception of the night after the anesthetic.

男猫通常不需要善后除了晚上的麻醉。