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1 M packed with Mellapak SM-250 under vacuum in batch process to obtain fractions rich in such components as pinenes, camphene, limonene as well as p-cymene, terpenol s, respectively.

松轻油先用碱液进行预处理,再用工业SM-250型孔板波纹填料塔(300mm、高10.1m),以真空间歇操作方式进行一次性精馏分离,分别得到富含蒎烯、莰烯、苧烯及对-伞花烃、萜烯醇等的馏分。

GC/MS analysis on the leaf oil indicated that the main components with a relative content of ≥3% were alloocimene (43.22%),α-pinene (13.63%),γ-terpinene (5.49%),-3, 7-dimethyl-, 2, 6-octadien-1-ol (3.58%),β-fenchyl alcohol (4.58%), and 2-amino-3, 5-dicyano-6-(4-methoxyphenoxy)-pyridine (3.67%).

用GC/MS联用方法,对巨尾桉挥发油进行鉴定,相对百分含量在3%以上的化合物有:α-蒎烯(13.63%)、别罗勒烯(43.22%)、γ-萜品烯(5.49%)、3,7-二甲基-2,6-辛二烯醇(3.58%)、β-小茴香醇(4.58%)和2-氨基-3,5-二氰基-6-(4-甲氧基苯氧基)-吡啶(3.67%)。

The simulation results show that the free energy of hydrogenation of acetylacetone iron to prepare enol-acetylacetone is less than that of the reaction to produce keto-acetylacetone at the same temperature.

计算结果表明:相同温度下,乙酰丙酮铁加氢生成烯醇式乙酰丙酮的反应自由能小于生成酮式结构乙酰丙酮的反应自由能;乙酰丙酮铁加氢更倾向于生成烯醇式结构的产物。

Furthermore, the main volatiles rom Hippophae rhamnoides included Nonane, Octane, 3-methyl-1-Butanol, Pentanal, 2-methyl- Butanal, 2-Hexen-1-ol, 2-Hexenyl benzoate in close natural state.

在近自然状态下,壬烷、辛烷、3-甲基丁醇、戊醛、2-甲基丁醛、2-壬烯醇、2-苯甲酸叶醇酯为沙棘枝叶主要挥发物组分。

Given the current complexity of industrial recovery of 3'-methyl-2'-butenyl 3, 3-dimethyl-pentenoate and the decomposition problems with 2-methyl-1-butene, research was conducted on a process for direct recycling of MBDP involving an ester exchange reaction of MBDP with either methanol, trimethyl orthoacetate, or solutions of methanol and trimethyl orthoacetate.

针对目前工业上回收3,3-二甲基-4-戊烯酸-3'-甲基-2'-丁烯酯工艺复杂、异戊烯大量分解问题,研究了MBDP直接返回循环使用工艺,MBDP与甲醇、原乙酸三甲酯或与甲醇原乙酸三甲酯混合溶液进行酯交换反应的回收新工艺,比较了四异丙基钛酸酯、甲醇钠、氢氧化钾用作酯交换催化剂的效果,筛选出回收MBDP&一锅煮&最佳工艺:按照n:n:n:n=1.0:9.8:9.2:0.05物质的量比投料,74℃~78℃反应21h,MBDP转化为贲亭酸甲酯和异戊烯醇,单程转化率87.7%,用85%的磷酸中和甲醇钠,蒸出甲醇,直接用于合成贲亭酸甲酯。

In order to solve the problems with heavy turpentine, such as complex constituents, vicinal boiling point, difficult to separation and hard to comprehensive utilization, the α-santalene was converted to natural structure similar product α-santalol by light-oxidize reaction, and caryophyllene epoxide was obtained at the same time.

摘要为了解决重质松节油组成复杂、沸点相近导致分离困难、难以深加工综合利用等问题,利用光氧化反应技术,将其中的α-檀香烯转化为与天然α-檀香醇结构相似的檀香型新香料-α-檀香烯醇,同时可得到环氧石竹烯。

Leaf oil of Litsea cubeba:α-cis-ocimene,-3, 7-dimethyl-1, 6-octadien-3-ol and n-trans-nerolidol

山苍子叶油:α-顺式罗勒烯、3,7-二甲基-1,6-辛二烯醇-3、正-反式橙花椒醇

Escherichia coli and many other microoganism synthesize aromatic amino acids through the condensation reaction between phospho enolpyruvate and erythro.

ppsA和tktA是芳香族氨基酸生物合成中心途径的两个关键酶基因,在大肠杆菌中,ppsA基因编码磷酸烯醇式丙酮酸合成酶A ,该酶催化丙酮酸合成磷酸烯醇式丙酮酸;tktA基因编码转酮酶A ,该酶在磷酸戊糖途径中生成 4 磷酸赤藓糖起主要作用。

ResultsCTX,PDD were adminstered alone and in combination with polyprenols respectively , the inhibination of Heps nodule was raised from 42.25% and 45.04% to 56.49% and 54.96% resp...

结果聚戊烯醇分别与CTX、PDD合用,对肝癌Heps的抑瘤率分别从4 2 。2 5 %、4 5 。0 4 %提高到 5 6 。4 9%、5 4 。96 %;聚戊烯醇分别联合CTX、5 Fu用药,对艾氏腹水瘤EC的抑瘤率分别从37.6 4 %、39.89%提高到 6 2 。92 %、5 3.37%。

The reductive hydrogenation of sterols is stronger downward with the depth,and that is much stronger in Site 8 than in Site 17 due to the different sedimentary circumstances.

随着沉积深度的增加,甾烯醇的加氢还原作用越强,且由于两个站位不同的沉积环境,8站位甾烯醇的加氢还原作用更强。

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