烯酮类

In the paper, the research evolvement of electrocarboxylation from carbon dioxide with olefin, alkyne, and ketones in near decades was summarized, these reactions were convenient ways to synthesize some valuable pharmaceutical precursor and intermediates in organic synthesis.

文章综述了近几十年来二氧化碳与烯烃化合物、炔烃化合物以及酮类化合物的电羰基化反应的研究进展，这些反应是合成一些有价值的药物前驱体或是有机合成中间体的简便方法。

At the meantime, we synthesized the chiral spiroketal enol ether steroselectively and their absolute configuration were determined.

我们还对螺环缩酮烯醇醚类化合物的立体选择性形成规律进行了探索，并取得了积极的结果。

Additionally, the quantum chemical study on the isomeriaation mechanism of the enol ester of 2-acyl-l,3-cyclohexanedione was performed, which was discovered by Yang when he synthesized the derivate of 2-acyl-l,3-cyclohexanedione.

第三部分工作是对杨定亚在合成2-酰基-1，3-环己二酮类化合物的衍生物时意外发现的烯酯异构化反应机理进行了研究。

Theoretical investigation of the solvent effects on the mechanism of the reaction of pentafulvenone with hydrocyanic acid to produce the main product of acid of type b was carried out at B3LYP/6-311+G** level via the conductor-like polarizable continuum model.

在B3LYP/6-311+G**计算水平上，采用导体极化连续模型研究了溶剂化效应对6-亚甲基环戊二烯酮与HCN反应生成主要产物b类酸的反应机理的影响。

By the reactions ofα-acylamino ketene--acetals and oxalyl chloride, a serie of pyrrolidinetriones were prepared.

通过α-酰胺基二硫缩烯酮和草酰氯的反应，成功制备了一系列吡咯烷酮类化合物。

In volatile oil of processed Cyperus, the contents of alkene and ketone compounds are more than those in unprocessed Cypreus, while the content of acid compounds is less than that of unprocessed Cypreus.

醋炙香附挥发油的主要成分中各种烯类、酮类化合物含量高于生品中的含量，而酸类化合物的含量低于生品中的含量。

In Granards' reactionof fluorinated β-ketophosphonium salts we found differentGranard reagents give different reaction mechanisms andPhMgBr realized the enolate reaction of fluorinatedβ-keto-phosphonium salts.

在研究含氟β-酮基鏻盐的β位亲核加成反应中，我们利用含氟α-烷氧基-β-酮基鏻盐与有机锂试剂的亲核加成反应一锅法高度立体选择性地合成了E式或Z式三氟甲基的烯醚类化合物。

The most prominent feature of Australian propolis is contained abundant flavonoid and terpenoid substances.

含有更丰富的黄酮类、萜烯类物质是澳洲蜂胶的最大特点。

There is a wealth of organic acids, terpenoid substances, vitamins, enzymes, polysaccharides, such as biological and pharmacological activity of natural ingredients.

澳洲蜂胶富含有20大类、380多种天然成分，包括30多种人体必需的微量元素、20多种氨基酸、数10种芳香化合物、30多种黄酮类物质，还有丰富的有机酸、萜烯类物质、维生素、酶类、多糖等具有生物学和药理学活性的天然成分。

It occurs at the carbon-carbon triple bond in a highl regioselective manner. Therefore, the reaction not only expanded the synthetic applications of Diels-Alder reaction but also provided a facile and efficient synthetic procedure for the synthesis of 4-functionalized quinoline derivatives.

上述反应实现不仅扩展了Diles-Alder反应在有机合成的应用，同时喹啉类化合物4-位上官能化的二硫缩烯酮基团也为其4-位取代打开了大门，为合成各种4-取代喹啉类化合物开辟了一个简洁高效的方法。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。