烯酮类

First, a series ofα-oxo ketene dithioacetals were preparated on the basis of our recent work.

具体研究如下：1。在十分温和的条件下，合成了一系列α-羰基二硫缩烯酮类化合物。2。

Therefore it is very important to explore the feadibility of clean synthesis lf complex compounds from a-oxo ketene dithioacetals

因此，以a-羰基二硫缩烯酮类化合物为合成子，探索复杂化合物的绿色合成方法将具有重要意义

Oxo ketene dithioacetals are a kind of versatile intermediates in organicsynthesis. It can be widely used in forming aromatic and heterocyclic compounds.

α-羰基二硫缩烯酮类化合物是一类重要的有机合成中间体，广泛应用于芳环和杂环化合物的合成中。

From the view of structure,α-alkenoyl ketene dithioacetals contain divinyl ketones.

从结构上看，α-烯酰基二硫缩烯酮可以看作二烯酮类物质。

Hydroxyl ketene dithioacetals were treated under diversely catalyzed conditions, and a wide range of significant compounds and synthetic precursors thus were obtained.

羟基二硫缩烯酮类化合物可以通过各种不同的反应条件进行多种转化，能够获得许多有意义的化合物和合成潜体。

Besides, The reaction of aldehydes with dithioacetate enethiolates followed by alkylation effectively gives α-hydroxyl ketene dithioacetals.

此外，用醛与硫代羧酸硫酯反应再通过烷基化也可以有效地获得α-羟基二硫缩烯酮类化合物。

In the end, a Novel and facile method has been used to synthesize functionalized cyclopentadienes by Nazarov cyclization ofα-alkenoyl ketene dithioacetals under Vilsmeier conditions.

从合成的α-烯酰基二硫缩烯酮类化合物出发，经过Vilsmeier试剂作用下的Nazarov环合反应，合成了官能化环戊二烯类化合物。

Among the variousα-oxo ketene dithioacetals,α-alkenoyl ketene dithioacetals are easier to prepare and bear much more functionalities.

在众多的α-羰基二硫缩烯酮类化合物中，α-烯酰基二硫缩烯酮具有易于制备，官能团多等特点。

The Nazarov cyclization, a powerful tool for the construction of five-membered carbocycles from divinyl ketones and related compounds, has attracted increasing attention in recent years due to its wide applications in the synthesis of complex natural and unnatural products.

Nazarov环合反应是通过二烯酮类物质和类似化合物构建五元碳环的有效方法。由于该方法广泛地应用于复杂天然和非天然产物的合成，近年来引起人们的广泛关注。

Synthesis of organic sulfuric compounds in aqueous media is carried out by: using thio-olefin compounds with carbonyl compounds, acetal/keltone, hydrazone, oxime, osazone and enamine to synthesize mercaptal/keltone compounds in aqueous media; using thio-olefin compounds with alpha-hydroxyaldehyde/keltone or alpha-halogenated aldehyde/keltone to synthesize thia-olefin derivatives in a queous media; using thio-olefin compounds with alpha, beta-unsaturated hydroxy compounds, C-C treble bond, C-N treble bond, C-C double bond, N-N double bond, C-N double bond, C-S double bond, epoxy and its derivatives, aziridine and its derivatives, cyclopropane and its derivatives and halogenated carboxy to synthesize sulfoether compounds in a queous media.

含水介质中有机硫化合物的合成方法，本发明属于有机合成方法，用硫缩烯酮类化合物与羰基化合物、缩醛/酮、腙、肟、脎、烯胺在含水介质中合成缩硫醛/酮化合物，与α-羟基醛/酮或α-卤代醛/酮在含水介质中合成噻烯类衍生物，与α，β-不饱和羰基化合物、碳碳叁键、碳氮叁键、碳碳双键、氮氮双键、碳氮双键、碳硫双键、环氧乙烷及其衍生物、氮杂环丙烷及其衍生物、环丙烷及其衍生物、卤代烃等在含水介质，中合成硫醚化合物。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。