烯酮

Deeply study of the applications of this type of activated alkene in the synthitic organic chemistry is very important.

因此，进一步研究α-氰基二硫缩烯酮在合成中的应用尤为重要。

Three chiral phosphorus ligands were prepared using anisole as the startingat material.Their applications in the asymmetric hydroformylation and asymmetric conjug ed addition of diethylzinc to enones were investigated.

以苯甲醚为原料，合成了三种新的手性含磷配体，考察了三种配体在不对称氢甲酰化反应和ZnEt2对环己烯酮的不对称共轭加成反应中的应用。

In this thesis, a convenient and efficient synthesis of highly functionalizeddihydropyrido[2,3-d]pyrimidines via a double [5 + 1] annulation strategy startingfrom easily available α-alkenoyl-α-carbamoyl ketene--acetals 1 and cheapreagents (NH4OAc, DMF, and POCl3) has been developed.

本论文探索了一种简便有效的合成高度官能化的二氢吡啶并[2，3-d]嘧啶的方法，此方法由易得的α-乙酰基-α-氨基乙酰基二硫缩烯酮1和便宜的试剂(醋酸铵，二甲基甲酰胺和三氯氧磷)通过两步[5 + 1]加成而实现。

Furthermore, the selective reductions of 2,2'-dinitrobiphenyl have been detailedstudied in the synthesis of achiral biphenyl backbones.

运用不对称活化的策略，成功地在Cu催化Et_2Zn对链烯酮的1，4-共轭加成反应中获得了高对映体选择性的加成产物。

Lactam was gained by the Staudinger reaction of imine and olefineketone in the presence of N-heterocyclic carbene catalyst.

以N-杂环卡宾催化剂1催化亚胺与烯酮之间的Staudinger反应，得到相应的β-内酰胺。

For example, cyanuric acid 〓 is added to the exhaust gas in the RAPRENOx process.

烯酮自由基在消除大气中的NOx过程中具有与异氰酸相似的作用。

In this thesis, we carried out a study of antigen synthesis, antibody production and hapten alteration to develop a quicky and sensitive detection method of Quinocetone's residue in animal edible tissues.

本论文通过抗原和抗体的制备及半抗原的改造，进行了在动物可食用组织中喹烯酮残留的ELISA快速检测的方法学研究。

Theoretical investigation of the solvent effects on the mechanism of the reaction of pentafulvenone with hydrocyanic acid to produce the main product of acid of type b was carried out at B3LYP/6-311+G** level via the conductor-like polarizable continuum model.

在B3LYP/6-311+G**计算水平上，采用导体极化连续模型研究了溶剂化效应对6-亚甲基环戊二烯酮与HCN反应生成主要产物b类酸的反应机理的影响。

By the reactions ofα-acylamino ketene--acetals and oxalyl chloride, a serie of pyrrolidinetriones were prepared.

通过α-酰胺基二硫缩烯酮和草酰氯的反应，成功制备了一系列吡咯烷酮类化合物。

In the first part of this thesis, a formal [4+2] cycloaddition of ketenes with N-benzoyldiazenes catalyzed by chiral NHCs was studied, which gave 1,3,4-oxadiazin-6-ones in very high yields and enantioselectivites.

论文的第一部分内容是在手性氮杂环卡宾的催化下，烯酮与N-苯甲酰偶氮化合物的环加成反应，合成各种手性的噁二嗪酮，它们还可以经过简单的两步一锅法制备手性氨基酯。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。