烯酮

All dates were analyzed by the principal component analysis through using the SIMCA-P 10.0 software. Result: The PCA demonstrated that the metabolome between treated group and control group had difference in rat urine sample after of 22 days administrated, for treated group 169 kinds of biomarkers were found including oxalacetic acid, malic acid, 2-ketoglutaric acid, NE, arachidonic acid, 5-HIAA and other compounds, the result was consistent with pharmacological effects of R.coptidis , such as antiinflammatory, inhibiting biosynthesis of CA biosynthesis, anti-central nerve and energy metabolism inhibition.

结果：给药22 d，黄连组与对照组大鼠尿样代谢组有较大差异，发现了169个生物标记物，其中可能的化合物为草酰乙酸、苹果酸、2-酮戊二酸、去甲肾上腺素、花生四烯酸、5-羟吲哚乙酸等物质，这与黄连抗炎、阻止儿茶酚胺的生物合成、抑制中枢神经、降低能量代谢的药理作用相一致。

Androstenedione and dehydroepiandrosterone as a new steroid material attracts people's attention because of the shortage of diosgenin resource and successful synthesis of AD by degradation of sterols. The followings were included in this thesis: 1. 24 new oxime-ether and oxime-ester compounds from AD were synthesized by cleavage of A-ring through NaIO_4/KMnO_4 oxidation, ring closure by amination, oximation with hydroxylaminechloride in C-17 position.

甾体药物的合成原料一般为薯蓣皂素、剑麻皂素、番麻皂素等，随着薯蓣资源日渐枯竭，使得甾体药物工业不得不寻求新的原料，而微生物降解胆固醇和植物甾醇合成雄烯二酮获得成功，使得AD成为新兴的甾体原料吸引了人们的注意。

Instead of environmentally toxic chromium oxidant, singlet oxygen generated photochemically was used as environmentally friendly and benign oxidizing agent to accomplish the transformation of pseudodiosgenin diacetate to diosone efficiently in a low toxic and less expensive solvent acetone.

裂解薯蓣皂甙元所得的假薯蓣皂甙元，在低毒且廉价的丙酮溶剂中，在光敏剂和光的存在下，与氧气反应，得到的产物再经酸解消除反应得到合成其它多种甾族药物的重要前体16-脱氢孕烯醇酮醋酸酯。

Herein, a series of compounds, BP-C〓-NBD (n=2, 3, 4, 5, 6, 8, 10), was synthesized. Nanosecond flash photolysis, phosphorescence emission and lifetime, as well as photoisomerization reaction of norbornadiene were used to understand the intramolecular triplet energy transfer in detail.

我们设计、合成了以多亚甲基连接的二苯酮与降冰片二烯（BP-C〓-NBD，n=2，3，4，5，6，8，10）系列化合物，利用纳秒时间分辨技术、低温磷光发射、磷光寿命以及光敏异构化的方法，对其分子内三重态能量传递过程进行了详细地研究。

Promoted by metal dysprosium, aldehydes and ketones could react smoothly with propargyl bromide to afford the corresponding homopropargylic alcohol s in good to excellent yields, and no allenic alcohols were found.

在金属镝的促进下，醛、酮可与炔丙基溴反应，高选择性高产率地得到相应的高炔丙醇，没有发现连二烯醇的存在。

Promoted by metal dysprosium, aldehydes and ketones could react smoothly with propargyl bromide to afford the corresponding homopropargylic alcohols in good to excellent yields, and no allenic alcohol s were found.

当用苯基炔丙基溴代替炔丙基溴与醛、酮反应时，主要得到了相应的连二烯醇，而没有发现高快丙醇的存在，由此提出了六元环过渡态的反应机理

The beta-thioalkoxyalcohols could be obtained in good yields by the reaction of dialkyl-substituted propargylic dithioacetals with a series of carbonyl compounds.

我们发现在铁触媒和格林那试剂的存在下，利用双烷基取代炔丙基硫缩酮和羰基化合物反应生成的beta-硫烷氧基醇，可以进行不常见的beta-氧消去反应，而得到烯炔衍生物。

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Hydrophilic monomers pyrrolidone and acrylamide were grafted on polyurethane film surface by UV irradiation to improve the surface lubricity.

用紫外光直接引发亲水性单体 N-乙烯吡咯烷酮、丙烯酰胺在医用聚氨酯表面进行接枝反应，可以提高 PU表面的润滑性。

Comparison of inhibitors for anti-polymerization of isoprene, such as NaNO2, p-tert-butylcatechol, N-methyl pyrrolidone and paradioxybenzene, was carried out using polymer segregation process and the results showed that TBC was the best one.

采用聚合物离析法比较了亚硝酸钠（NaNO2）、对叔丁基邻苯二酚、N-甲基吡咯烷酮、对苯二酚对异戊二烯的阻聚效果，发现TBC阻聚效果最好。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。