烯酮

The efficient first asymmetric syntheses of-6β-hydroxy-7αH-eudesm-4-en-3-one, and its C-6 epimer were achieved starting from-dihydrocarvone, whichprovide a novel and efficient synthetic method to 6-oxgenated eudesmanes.

以-二氢香芹酮为原料，经五步反应，首次完成了6β-羟基-4(5)-烯-3-羰基桉烷及其6位差向异构体的立体选择合成，并为C-6位含氧官能团取代桉烷类化合物的合成提供了一种简便有效的方法。

A gas chromatographic-mass spectrometric method for the simultaneous determination of environmental estrogens (including 4-nonylphenol, bisphenol A,diethylstilbestrol and 17α-ethinylestradiol) and endogenous estrogens (including 17α-estradiol, 17β-estradiol, estriol and estrone) in urine and bed mud is reported.

报道了尿及河底泥中环境雌激素(壬基酚、双酚A、己烯雌酚、17α-乙炔基雌二醇)和内源性雌激素(17α-雌二醇、17β-雌二醇、雌三醇、雌酮)的气相色谱-质谱测定法。

To investigate the pollution levels, occurrence and distribution of estrogens, six estrogens in the surface sediments of Wenyuhe River were analyzed quantitatively by GC/MS following ultrasonicated extraction including diethylstilbestrol, estrone(E1),β-estradiol(E2), 17α-ethynylestradiol(EE2), estriol(E3), and β-estradiol 17-valerate. Six estrogen concentrations ranged from 0.39-36.6ng/g and the mean concentration was 10.2ng/g.

为了调查温榆河沉积物中雌激素物质的污染状况，采用超声萃取、GC/MS法研究了6种常用雌激素（包括己烯雌酚DES、雌酮E1、雌二醇E2、乙炔基雌二醇EE2、雌三醇E3和戊酸雌二醇EV）在北京温榆河上游及干流表层沉积物中的含量水平，并对其分布及来源情况进行了分析。

A series of products have been put on the market which include mainly gamma-Hexalactone, gamma-Heptalactone, Whisky lactone, 4-hexen-3-one, fenchyl alcohol and rosemary antioxidant, shikimic acid and so on.

目前已规模化生产的香料产品有丙位已内酯、丙位庚内酯、威士忌内酯、4-己烯-3-酮和葑醇等。批量生产迷迭香抗氧化剂、罗汉果甜苷、莽草酸等植物提取物。

The result showed that the molecular probe incorporated with fluorescein can penetrate into the zebrafish embryo.

同时我们也合成孕烯醇酮的连接端末端具有 3-Hydroxyflavone衍生物。

A novel carbonyl transposition led by anilines'nucleophilic addition to methyl 2-keto α-D-glucopyranoside was discovered. And the mechanism of the reaction concerned to an enol rearrangment was provided through tracing the change of 〓H-NMR and 〓C-NMR of a hemiacetal intermediate which was obtained in the reaction of o-phenylene diamine with 2-keto glycoside. Both the intermediate and the converting product were identified by 〓H-NMR,〓C-NMR,〓H-〓H COSY and HMQC.

一、发现了2-位氧化α-甲基D-葡萄糖苷的芳胺亲核加成引起羰基转位的新方法，利用核磁共振氢谱及碳谱对邻苯二胺与2-位氧化α-甲基D-葡萄糖苷加成生成的稳定中间体半缩酮化合物在氘代丙酮中的变化进行跟踪，结合对转化产物的氢氢相关谱和HMQC结构确证，提出了该反应中2-位羰基通过烯醇化互变而转至3-位的机理并得到了验证。

Nsted acid for the activation of the imine and acetic acid (20 mol %) as the non-chiral proton source for the shift of the keto-enol equilibrium.

94%酸、活化的亚胺乙酸(20摩尔%)的非手质子源为转移的酮-烯醇平衡。

The calculated results shed more light on the water′s influence on the proton transfer and offer a new insight into the structural tautomer interconversion of FM.

溶液状态下的质子转移研究将会对水分子对中心分子的异构化研究提供参考，同时也部分解释了试验中酮式比例高于烯醇式的现象。

As fine chemical raw material, isoprene can be used to produce various perfumes, medicines, pesticide intermediates such as high value-added linalool, pyrethroid and ionone.

化学级异戊二烯是精细化工的原料，可以生产高附加值的芳樟醇、拟除虫菊酯、紫罗兰酮等多种香料、医药、农药中间体。

In chapter four molecular modeling method is employed to comparatively study five S-allyl γ-hydroxy ketene dithioacetals reactions of Thio-Claisen rearrangement with and without zeolite catalysts.

第四章用分子模拟途径研究了在有、无分子筛催化条件下五种丙烯基羟基乙烯酮二硫代乙缩醛Thio-Claisen重排反应。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。