烯酮

Receptor agonist ; SA4503{1?[2?（3; 4?dimethoxyphenyl）ethyl]?4?（3?phenylpropyl）piperazine}; DTG[3?di（2?tolyl）guanidine]; DHEAS ; PREGS ; learning ; memory

σ受体激动剂； 1-[2-（3； 4-二甲氧基苯基）乙基]-4-（3-苯丙基）哌嗪（SA4503）； 1； 3-二（2-甲苯基胍）；脱氢雄表酮硫酸酯；孕烯醇酮硫酸酯；学习记忆

In this paper, the synthesis ways and applications of 4,5-dimethyl-l,3-dioxolen -2-one were introduced. An appropriate way synthesizing DMDO from acetoin via acylation, cyclization and dehydrochlorination was selected. The influences of various process conditions on the reaction were studied in detail, and the optimum process conditions were obtained by single factor experiments.

本文介绍了医药中间体4，5-二甲基-1，3-二氧杂环戊烯-2-酮的应用情况和合成路线，选择了适于工业化生产的工艺路线，即采用羟基丁酮为原料，经酰化、环合和脱氯化氢等步骤合成DMDO，并采用单因素试验法详细研究了各项工艺条件对反应结果的影响规律，确定了优化工艺条件。

Selective allylation of the linear, cyclic and mixed diketones in the presence of water by allyl bromide and metallic zinc have been successfully achieved.

本文报道锌参与下水相介质中对称双酮及混合双酮的选择性烯丙基化反应的研究。

Moreover,the selective oxidation of primary and secondary alcohols to corresponding carbonyl compounds with the multinuclear copper complexes Cul-Cu4 as catalysts have been conducted using TBHP and O_2/TEMPO,respectively.Among them,the copper complex Cu3 showed the best performance.On the performances of the two classes of oxidants,benzylic and heterocyclic alcohols could be effectively oxidized to carbonyl compounds.Specifically,the secondary alcohols could be effectively oxidized to ketones with excellent selectivity up to 100%in the presence of TBHP and the allylic alcohols could be effectively oxidized to aldehydes in the presence of O_2/TEMPO system.

实验结果还表明，在TBHP或O_2/TEMPO存在下，各配合物催化剂均能使各种取代芳香伯/仲醇以及杂环醇等以不同程度的转化率和选择性转化成相应的醛或酮，其中，配合物Cu3在O_2/TEMPO存在下可使苯甲醇和烯丙醇等以较高转化率和近100%的选择性转化成相应的醛，而对其它芳香醇和脂肪伯/仲醇等的催化性能则较差；在TBHP存在下，配合物Cu3则可使1-苯乙醇和其它仲醇以较高转化率和近100%的选择性转化为相应的酮，但对各类其它伯醇选择氧化的性能相对较差。

Mission:"equality and mutual benefit, reputation first, unity and cooperation and friendship between the long-term" supply products: ethylenediamine; diethylamide; triethylamine; Diethylenetriamine; three ethylene diamine; three ethylene amines 40; 40 Five ethylene amines; five ethylene amines 6; caprolactam; DMF; allyl amine; N, N dimethylaniline; propylamine; are butylamine; are TOA; 3 Poly Cyanamide; 1,2 c diamine; ethanolamine; diethanolamine, triethanolamine; potassium iodide, potassium hydroxide, potassium permanganate, toluene, xylene, toluene of chlorine ; Acetone, butanone; acetylacetone; ethyl acetate, butyl acetate; Y-butyrolactone; DMC; acetyl of methyl acetate; Sanfu acetyl acid; Sanfu acetyl B Ethyl; methanol, ethanol, isopropanol; propylene glycol; glycerol; propargyl alcohol; 1.3 propylene glycol; xylitol; acetic acid; have acid; mercaptoacetic acid; vary Bitterness; adipic acid; trifluoroacetic acid; oxalic acid, the amino acid; o-amygdalin acid; DL-Acid; anhydrous piperazine; six non-piperazine, furfural, castor oil, ethylene Aldehyde; glutaraldehyde, multi-POM; isopropyl ether; anisole; tetrahydropyrrole; pure pyridine; 1.2 dichloroethane; methylene chloride, chloroform, carbon tetrachloride; hydrazine hydrate; Nonylphenol;-m-cresol; Se phenol; phenol; the tert-butyl phenol; Titanium Dioxide; iron; full Tangfen; Bisphenol A; azo two different nitrile; sodium azide; sodium carbonate ; Sodium chloride; iron oxide; cuprous chloride; thionyl chloride; D4; sodium bicarbonate; ammonia, potassium chloride; anhydrous sodium sulphite; ammonium persulfate; glycol Dingmi; B Glycol ether; calcium chloride; cyclohexanone; cyclohexane, methyl tertiary butyl ether, potassium carbonate, ferric chloride, potassium nitrate; Linsuansanna; zinc oxide; sodium nitrite; antimony oxide; Tartrate; OP-10; TX-10; tablets base; AES; sodium benzoate, sodium citrate; partial sodium silicate, sodium perborate, a sodium carbonate, sodium benzene; Asia sodium chlorate; Wuluo Care products; urea; hydrochloric acid, sulfuric acid, lactic acid; amino acid, hydrogen peroxide, ammonium bicarbonate

公司宗旨：&平等互利，信誉至上，团结合作，友谊长久&乙二胺；二乙胺；三乙胺；二乙烯三胺；三乙烯二胺；三乙烯四胺；四乙烯五胺；五乙烯六胺；己内酰胺；二甲基甲酰胺；烯丙基胺；N，N二甲基苯胺；正丙胺；正丁胺；正辛胺；三聚氰胺；1，2丙二胺；一乙醇胺；二乙醇胺；三乙醇胺；碘化钾；氢氧化钾；高锰酸钾；甲苯；二甲苯；对氯甲苯；丙酮；丁酮；乙酰丙酮；醋酸乙酯；醋酸丁酯；Y-丁内酯；碳酸二甲酯；乙酰乙酸甲酯；三伏乙酰乙酸；三伏乙酰乙酸乙酯；甲醇；无水乙醇；异丙醇；丙二醇；丙三醇；丙炔醇；1.3丙二醇；木糖醇；冰醋酸；己醛酸；巯基乙酸；异辛酸；己二酸；三氟乙酸；乙二酸；对氨基苯乙酸；邻氯苦杏仁酸；DL-扁桃酸；无水哌嗪；六无哌嗪；糠醛；蓖麻油；乙二醛；戊二醛；多聚甲醛；异丙醚；苯甲醚；四氢吡咯；纯吡啶；1.2二氯乙烷；二氯甲烷；三氯甲烷；四氯化碳；水合肼；壬基酚；纯间甲酚；硒酚；苯酚；对叔丁基苯酚；钛白粉；铁粉；全糖粉；双酚A；偶氮二异丁腈；叠氮化钠；碳酸钠；氯化钠；三氧化二铁；氯化亚铜；氯化亚砜；D4；碳酸氢钠；氨水；氯化钾；无水亚硫酸钠；过硫酸铵；乙二醇丁醚；乙二醇乙醚；氯化钙；环己酮；环己烷；甲基叔丁基醚；碳酸钾；三氯化铁；硝酸钾；磷酸三钠；氧化锌；亚硝酸钠；氧化锑；酒石酸；OP-10；TX-10；粒碱；AES；苯甲酸钠；柠檬酸钠；偏硅酸钠；过硼酸钠；过碳酸钠；苯磺酸钠；亚氯酸钠；乌洛托品；尿素；盐酸；硫酸；乳酸；氨基磺酸；双氧水；碳酸氢铵

The active compound Celangulin-V, which is the main active compound against insect pest from Celastrus angulatus Max, was modified at its 6-OH and the core structure β-dihydroagarofuran polyol of Celangulins from the basic hydrolysis of the extract of the root bark of Celastrus angulatus Max was modified by combinatorial chemical method.

主要结果如下： 1、合成了苦皮藤素V6-乙酯、6-烯丙基醚和6-酮等衍生物，通过NMR方法鉴定了化合物的结构，经文献检索均为新化合物，生测结果表明酮衍生物丧失了杀虫活性，乙酯衍生物与苦皮藤素V活性相当，醚衍生物较苦皮藤素V活性提高11倍。

The steroids of cholest 4 ene 3 one and cholestane 3,6 dion in Yisheng Capsules were determined by capillary gas chromatography. The results provide a reference to work out its quality standard.

采用毛细管气相色谱法测定了益肾胶囊中胆甾-4-烯-3-酮、胆甾-3，6-二酮的含量，为该制剂制度质量标准提供了参考依据。

The paint includes liquid A, which consists of acrylic resin, mixed solvent of xylene, acetone and isophorone, organic silicone solution, superfine silica powder, titanium dioxide powder, methyl-(N-beta-amino ethyl gamma-amino propyl)-dimethoxy siloxane solution, gamma-methyl acrylyloxy propyl tromethoxy siloxane solution and fluorocarbon modified siloxane; and liquid B, which consists of hexamethylene diisocyanate, polydiisocyanate, xylene, and methoxy propyl acetate. When the paint is used, two components are mixed together.

由丙烯酸树脂、二甲苯和丙酮及异佛尔酮混合溶剂、有机硅酮溶液、超细二氧化硅粉、钛白粉、甲基(N-β-氨乙基γ-氨丙基)二甲氧基硅烷溶液、γ-甲基丙烯酰氧基丙基三甲氧基硅烷溶液、氟碳改性硅氧烷溶液组成A液，由六亚甲基二异氰酸酯聚异氰酸酯、二甲苯和甲氧基乙酸丙酯混合溶液组成B液，使用时将两组分混合。

Its mechanism is the use of anthraquinone in alkali conditions off proton surface forming 10 more stable carbon anion face, but because carbon anion and oxygen ion exist between testosterone and enolate type each other changes, cause reaction product complex, at least five, reaction selectivity, product yield, separation difficulties, and product purity is not high, therefore, using the type and quantity of alkali, phase transfer catalyst type, solvent, to optimize the selection process conditions so as to improve the yield target product.

其机理是利用蒽酮在碱存在的条件下脱去氢质子面形成10位较稳定的碳负离子面进行，但是因为碳负离子和氧负离子之间存在酮式和烯醇式的互变，导致反应复杂，产物至少有五种，反应选择性差，产物分离困难，产率低，且产品纯度不高，因此，利用对碱的种类和量的多少，相转移催化剂的种类，反应溶剂的选择，来优化反应工艺条件从而提高目标产物的产率。

In Granards' reactionof fluorinated β-ketophosphonium salts we found differentGranard reagents give different reaction mechanisms andPhMgBr realized the enolate reaction of fluorinatedβ-keto-phosphonium salts.

在研究含氟β-酮基鏻盐的β位亲核加成反应中，我们利用含氟α-烷氧基-β-酮基鏻盐与有机锂试剂的亲核加成反应一锅法高度立体选择性地合成了E式或Z式三氟甲基的烯醚类化合物。

Singer Leona Lewis and former Led Zeppelin guitarist Jimmy Page emerged as the bus transformed into a grass-covered carnival float, and the pair combined for a rendition of "Whole Lotta Love".

歌手leona刘易斯和前率领的飞艇的吉他手吉米页出现巴士转化为基层所涵盖的嘉年华花车，和一双合并为一移交&整个lotta爱&。

This is Kate, and that's Erin.

这是凯特，那个是爱朗。