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It was found that the thermodynamically unfavourable isomerization of quadracyclane to norbornadiene could be accomplished in the presence of toluene or durene as a co-sensitizer.

首次发现在甲苯、杜苯等芳烃共敏化下,可以使原来不能进行的、热力学不利的四环烷→降冰片二烯异构化得以进行,并根据CIDNP结果提出这是由于生成了敏化剂/底物/芳烃三元基激络合物使反应的势能面改变造成的并促进单线态的系间窜跃。

For example,the addition reaction with small molecular,the metathetical reaction with alkynes and Wittig reaction to prepare high-valent transtion-metal allenylidene complexes.

对于化合物11,详细研究了其与小分子加成反应、炔烃复分解反应以及通过Wittig反应制备高价态过渡金属丙二烯基卡宾化合物。

A high molecular weight polyisobutenyl succinimide dispersant with high nitrogen content and good thermal and oxidative stabilities was developed.

采用氯化烃化工艺和后偶联反应技术开发了一种氮含量高、热稳定性和氧化稳定性好的高相对分子质量的聚异丁烯基丁二酰亚胺分散剂。

The studies found that compatibility between ZDDP and succinimide dispersants primarily depended upon active α-amino-group content in succinimides. The active α-amino-group content was affected by the alkylation and amination processes, and also affected by the structure of polyisobutylene in succinimides.

研究结果表明,丁二酰亚胺与 ZDDP 的相互作用主要取决于丁二酰亚胺中活泼的伯胺氮含量,而伯胺氮含量则决定于丁二酰亚胺在生产中的烃化、胺化工艺和聚异丁烯基的结构。

A conjugate addition of alkadienyl carbonyl compound with vinyl palladium intermediates which can be formed from oxypalladation of alkynes or allenes was studied, and 1, 6-addition products were obtained.

发现不饱和烃的分子内氧钯化得到的烯基钯中间体能够与不饱和共轭双烯的醛酮反应,选择性的得到1,6-加成产物。

These substituents are either small groups such as phenoxy groups,aryls,cyclic secondary amines,cyano groups,and halogens or large functional moieties such as PDI,Phthalocyanines, porphyrins,BODIPY,cyclodextrin,Fullerene,calixarene,and so on.

这在过去的工作中,人们把一些小分子的,如酚氧基、仲胺基、苯基、氰基以及卤素氟、氯、引入到PDI中,同时也把一些较大功能团,如PDI本身、卟啉、酞菁、环糊精、BODIPY、杯芳烃、富勒烯等和PDI连接在一起。

Firstly, Vinyl ethers were prepared in a one-pot, two-step transformation by O-alkylation reaction of 2-hydroxyalkyl phenyl selenides with primary or secondary organic halides followed by oxidation-elimination with 30 % hydrogen peroxide.

1.2-羟基烷基苯基硒醚和伯、仲卤代烃通过O-烷基化反应,然后用30%的双氧水进行氧化消除反应,提供了&两步、一锅法&合成烯基醚的新方法,该方法反应条件温和,操作简便,产物收率中等到良好(70-85%)。

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For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降,而后引起了信用卡大规模的亏损。

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弗四23 而在你们心思的灵里得以更新

Lao Qiu is the Chairman of China Qiuyang Translation Group and the head master of the Confucius School. He has committed himself to the research and promotion of the classics of China.

老秋先生为中国秋阳翻译集团的董事长和孔子商学院的院长,致力于国学的研究和推广。