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It revealed that the gaseous oxygen was related to the deep oxidation of hydrocarbon, since the breakage of C-C bond in allylic intermediate didn't exist during the process of reaction. This is due to the weak ability of lattice oxygen to attack hydrocarbon molecular.

实验结果指出,烃类的深度氧化反应与气相氧的存在有关,晶格氧对烃分子中碳碳键的攻击较弱,反应中烯丙基中间体几乎不发生碳碳键的断裂。

This paper expounds the photochemical reaction of alkenes, ketones and aromatic hydrocarbon, and discusses the mechanism of their photochemical decomposition and the application of photochemistry in organic synthesis.

本文介绍了烯、酮、芳烃体系的光化学反应,从光化学过程讨论了它们的光解机理以及它们在有机合成中的应用。

When the proportion of the aryl halides was changed,the aromatic products with different number substitutes could be obtained.

通过研究我们发现,活泼酰基与烯丙基在偶联反应中活性相当,可得到不同成环方式的产物,且当改变卤代物比例时,将得到不同数量取代芳烃的产物。

Surprisingly, cadalene, retene and perylene, usually used as the terrestrial biomarkers, are abnormally abundant in the Lower Paleaozoic source rocks.

卡达烯、惹烯和苝在下古生界烃源岩中的普遍存在充分说明它们不是可靠的陆源标志物,早古生代繁盛的兰绿藻等浮游植物无疑也是其主要的生物来源。

The alkaloids were studied by gas chromatography coupled to mass spectrometry. Six major venom alkaloids were detected in worker venom which are all trans 2-methyl-6-alkyl or alkenyl pepdine according to mass spectral data and relative report on S.invicta.

通过保留时间和质谱离子碎片数据,并与国外相关报道比较分析得出:入红火蚁毒液中主要成分为2-甲基-6-烷基或烯基哌啶生物碱,仅有6位取代烃基碳链长短和烯键有无及顺反异构的差异。

Dehydration process based on hollow fiber composite membrane is one of the crucial and effective methods to remove water vapor from industrial gases such as light hydrocarbon, compressed air, natural gas and so on. Dehydration of propylene with VP method was studied in the thesis. We prepared the PVA/PS、CS/PS and PVA-CS/PS hollow fiber composite membranes by spread method. The permeation behavior of water vapor among coagulable light hydrocarbons through composite membranes and asymmetric membrane was researched by vapor permeation method. Also a differential mathematical model was established which can describe dehydration of gas phase propylene.

本论文以采用蒸气渗透法脱除丙烯中微量水分为目标,制备了 PVA/PS、 CS/PS、PVA-CS/PS 中空纤维复合膜;研究了可凝性轻烃蒸气中的微量水分在复合膜、非对称膜中的渗透行为,建立了描述丙烯气相脱水的数学模型,并进行了模拟计算;深入探讨了水蒸气在交联 PVA 致密膜中的渗透机理。

Dehydration process based on hollow fiber composite membrane is one of thecrucial and effective methods to remove water vapor from industrial gases such aslight hydrocarbon, compressed air, natural gas and so on. Dehydration of propylenewith VP method was studied in the thesis. We prepared the PVA/PS、CS/PS andPVA-CS/PS hollow fiber composite membranes by spread method. The permeationbehavior of water vapor among coagulable light hydrocarbons through compositemembranes and asymmetric membrane was researched by vapor permeation method.Also a differential mathematical model was established which can describedehydration of gas phase propylene.

本论文以采用蒸气渗透法脱除丙烯中微量水分为目标,制备了 PVA/PS、CS/PS、PVA-CS/PS 中空纤维复合膜;研究了可凝性轻烃蒸气中的微量水分在复合膜、非对称膜中的渗透行为,建立了描述丙烯气相脱水的数学模型,并进行了模拟计算;深入探讨了水蒸气在交联 PVA 致密膜中的渗透机理。

The lumped kinetic model of monoterpene, abietic type resin acid, pimaric acid type resin acid, p-cymene, hydro-monoterpene, dehydro-abietic acid, hydro-abietic type resin acid, and hydro-pimaric acid type resin acid was established based on the structural groups and approximate reaction kinetic theory according to the fundamental principles of the lumped method.

在消除内、外扩散影响的条件下,在线跟踪反应产物并用气相色谱法测定反应体系组成随时间的变化,构造了Pd/C催化剂上松脂分子间氢转移集总反应网络,建立了包含单萜烯、枞酸型树脂酸、海松酸型树脂酸、对伞花烃、氢化单萜烯、脱氢枞酸、氢化枞酸型树脂酸和氢化海松酸型树脂酸等复杂反应体系的集总动力学模型,并估算了模型参数。

A conjugate addition of alkadienyl carbonyl compound with vinyl palladium intermediates which can be formed from oxypalladation of alkynes or allenes was studied, and 1, 6-addition products were obtained.

发现不饱和烃的分子内氧钯化得到的烯基钯中间体能够与不饱和共轭双烯的醛酮反应,选择性的得到1,6-加成产物。

These novel reagents were treated with base to produce polystyrene-supported a-seleno carbanions, which reacted with alkyl halides, followed by stereospecific selenoxide syn-elimination to give 2i-vinylphosphonates and is-vinylsulfones respectively.

它们在碱的作用下形成α—硒基碳负离子,然后与卤代烃发生烷基化反应,烷基化后的树脂可以通过温和条件下的氧化消除以良好产率和较高纯度分别合成了烯基磷酸酯和烯基砜。

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