烯烃

Three kinds of CpTiCl had been synthesized when was catechol , 2, 2′-biphenol , or 2, 2′-binaphthol , respectively. In the case of CpTiCl〓, was 8-hydroxylquinoline , 2-methyl-8-hydroxyl-quinoline , and 8hydroxyl-5-nitro-quinoline , respectively.

研究表明，这三类半茂钛配合物在助催化剂MAO作用下，于30℃、0.1MPa乙烯压力下均可催化乙烯聚合，并显示较高的活性，远高于未引入非茂配体的CpTiCl〓及不含茂环的相应非茂配合物的活性，这说明同时含一个茂配体和一个非茂配体的半茂配合物是烯烃聚合的优良催化剂。

A2D iim ine nickel, palladium complexes and pyridine bisimine iron, cobalt complexes are discovered in recent years to be new generation late transition metal catalysts for olefin homogeneous poly merization and oligomerization.

A2二亚胺镍、钯络合物和吡啶二亚胺铁、钴络合物是近几年来发现的新一代烯烃均相聚合后过渡金属催化剂。

In part three oxidation of bromide with an ion-supportedbenzene in ionic liquids afforded a clean path for bromination of alkenes. It was found that this reaction is highly stereoselective.

在离子液体中使用离子支持的二乙酸碘苯氧化溴离子，提供了一条清洁的烯烃加溴途径，发现反应具有高的立体选择性。4。

Mimetic peroxidase of high catalytical activity and selectively is very important in bio-analytical field.

建立一系列关于这些酶的模拟体系将为以下三个方面的研究工作提供非常重要的工具：（1）工业或者精细化工方面重要反应新型催化剂的开发，例如烷烃的选择性氧化以及具有立体选择性的烯烃环氧化；（2）新的生物活性物质，例如药物的氧化机理的研究和预测；（3）具有合适底物的高活性过氧化物酶模拟酶在生化分析领域的前景。

Asymmetric epoxidation is the most attractive section in catalytical olefin-epoxidation with Schiffbase-transition metal complexes.

不对称环氧化是过渡金属Schiffbase配合物催化烯烃环氧化的核心。

The elaboration of systems that are able to mimic those enzymes should provide very important tools for three main purposes:(1) the development of new catalysts for important reactions in industrial and fine chemistry, such as the selective oxidation of alkanes and the stereoselective epoxidation of alkenes;(2) the prediction of the oxidative metabolism of new biologically active molecules such as drugs.(3) mimetic peroxidase of high catalytical activity and selectively is very important in bio-analytical field.

建立一系列关于这些酶的模拟体系将为以下三个方面的研究工作提供非常重要的工具：（1）工业或者精细化工方面重要反应新型催化剂的开发，例如烷烃的选择性氧化以及具有立体选择性的烯烃环氧化；（2）新的生物活性物质，例如药物的氧化机理的研究和预测；（3）具有合适底物的高活性过氧化物酶模拟酶在生化分析领域的前景。

The cationic complexes of transition metals serve as catalytically active species for olefin polymerization. Their structures and properties directly influence the resulting polymers in terms of microstructure and function.

阳离子型金属有机化合物是催化烯烃聚合反应的活性物种，其结构与性质直接影响所得聚合物的微观结构和性能，具有重要的研究价值。

In this thesis, several novel reaction-controlled chiral phase-transfer catalysts were designed and synthesized from readily available materials, and were used in the asymmetric epoxidation of unfunctionalized olefins and chalcone.

本文以有机合成方法学为目标，从廉价的原料出发，合成出几个新的反应控制的手性相转移催化剂，并且检验了他们在催化烯烃的不对称环氧化中的催化效果。

The determination of conjugated dienes content in gasoline by polarographic method is studied.

研究了用极谱法测定汽油中的共轭二烯烃含量的方法。

In this catalyst system, the Knoevenagel condensations of a series of aromatic aldehydes with malononitrile or ethyl cyanoacetate were programmed and a mechanism was postulated as well. When aromatic aldehydes reacted with ethyl cyanoacetate, the corresponding alkenes proved to be E-isomers by 1H NMR.

在该反应体系中考察了一系列芳香醛和丙二氰、氰基乙酸乙酯的缩合反应，并推测了Knoevenagel缩合反应的机理，芳香醛与氰基乙酸乙酯缩合产物经1H NMR检测为E式烯烃。

By the time of its fall, most of the prisoners were writers who had written against the corruptions of the government.

到它被攻陷的时候，里面多数的犯人是写了反对政府贪污文章的作家。

The most obvious variation to ovum morphological character was that the color was changed from light green to sepiaceous in embryonic development, and all the ovums were almost hatched after 96h.

在胚胎发育过程中卵的形态特征最明显的变化是颜色从淡绿到深褐色，卵在发育96h后卵基本全部孵化。