烯烃

Methylpyridine-coordinated ruthenium benzylidene complex 62 shows thehighest catalytic activity. TOF=960 h~(-1) is achieved during RCM reaction of 50, TOF=4 h~(-1)is obtained during the CM reaction of acrylonitrile with 1-decene.

其中，2-甲基吡啶配位的钌卡宾配合物62的催化活性最高，在催化烯烃50闭环交互置换反应时TOF可达960 h~(-1)；催化丙烯腈与1-癸烯交叉交互置换反应时TOF达到4 h~(-1)。

Ti-MWW is more attractive by a comparison with those conventional titanosilicates (TS-1,Ti-MCM-41,et al ) in the epoxidation of linear functionalized alkenes, on which the epoxidation of allyl alcohol to glycidol is one of the most industrial promising processes for benign reaction conditions, high yields of the product and environment friendly.

Ti-MWW 对线性官能烯烃的环氧化具有优良的催化性能，特别是对烯丙醇环氧化制缩水甘油的过程，其反应条件温和，产率高，且对环境友好而最具有工业应用前景。

Both catalytic activity and selectivity of Ru(PPh_3)_3Cl_2 were improved in ionic liquid BMImPF_6/DME medium.The conversion of hexene and selectivity ofβ-adduct for the hydrosilylation reaction of 1-hexene with triethoxysilane catalyzed by Ru(PPh_3)_3Cl_2 in ionic liquid BMImPF_6DME (V/V=1/4) medium at 90℃were 100% and 89.0%,respectively.

实验结果表明，在乙二醇二甲醚/离子液体1-丁基-3-甲基咪唑六氟磷酸盐(BMImBF_6)(V/V =1/4)介质中，于90℃下，己烯与三乙氧基硅烷反应的转化率为100%，β加成物的选择性可达89.0%，而用Rh(PPh_3)_3Cl作为反应的催化剂，在纯离子液体BMImPF_6中，就可以高效催化烯烃与三乙氧基氢硅烷的加成反应，过渡金属Rh(PPh_3)_3Cl，Ru(PPh_3)_3Cl_2催化剂/离子液体BMImPF_6催化体系，不仅解决了产物与催化剂分离困难这一难题，同时，离子液体BMImPF_6的存在提高了过渡金属Rh(PPh_3)_3Cl，Ru(PPh_3)_3Cl_2催化硅氢加成反应的活性，特别是β加成物的选择性。

The compoud 1 can be converted to intramolecular coupled cyclic olefine (2) as a main product in the presence of iron catalyst.

控制反应条件，在铁催化下可以生成偶联烯烃化的环烯产物(2 )为主要产物；不加催化剂，加热回流反应得到分子内亲核取代反应产物环丙烷化合物 3

This dissertation concentrated on its low-cost synthesis, adjusting of silica to alumina molar ratio and catalytic applications in olefinic alkylation of thiophenic sulfur of simulated FCC gasoline and aromatization of butene in liquefied-petroleum-gas process.

本论文旨在降低MCM-22合成成本，获得硅铝比范围宽泛可调的MCM-22，并拓展其在烯烃烷基化脱硫与液化气丁烯芳构化方面的应用。

A piperylene based petroleum resin was modified by the monoolefin fraction from C_5 separation unit.

采用 C5分离装置得到的 C5单烯烃馏分对间戊二烯石油树脂进行改性。

Some aqueous catalysis systems have been applied in the industrial production of butyl aldehyde by propene hydroformylation.

其中水溶性催化剂体系已经用于丙烯氢甲酰化反应制备丁醛的工业化生产，然而，长链烯烃在含有催化剂的水相中溶解性较差，反应速率较慢。

XRD results reveal that the addition of HF decreases the defects in the crystal lattice of SAPO 34, which is proved by the two distinct double peaks at 2 θ=26°and 31° and other ...

以氟化氢三乙胺复合模板剂合成的分子筛，在催化甲醇制低碳烯烃反应中结焦速率降低，生成乙烯及丙烯的选择性则略有提高

A desulfurization method is proposed for the removal of sulfur compounds from FCC gasoline by alkylation reaction of thiophenic sulfur with olefins over acid catalysts, and the higher boiling sulfur-containing products are removed by fractional distillation.

选择以噻吩的甲基取代衍生物(包括 2-甲基噻吩、3-甲基噻吩及 2，5-二甲基噻吩)与异丁烯的烷基化反应为模型反应，考察了经三氯化铝气相固载法改性的 CT175 树脂催化剂催化噻吩的甲基取代衍生物与烯烃的烷基化反应性能。

Advances in ethylene selective trimerization catalysts, especially composition, activity and cost of trimerization catalysts and their overall selectivity to 1-hexene.

对乙烯选择性三聚反应进行了论述，着重分析了催化剂的组成、活性、成本和1-己烯的总选择性，并展望了烯烃选择性齐聚反应的发展。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新