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Part 2. Annulation reaction of 3, 4-dichlorocoumarin (1) and 3, 4-dichloromaleimide (8) by a new general annulation strategy developed in this group with 2-phenylbenzofuran (15), 3-phenylbenzofuran (16), 2, 5-diphenyloxazole (17), 2, 5-diphenylthiazole (18), 2-methyl-4-phenylthiazole (19) and 2, 3-dimethoxy-1, 3-butadiene (40) were investigated.

二。在本课题组前一阶段提出的从二氯代环烯酮与1,1-二芳基乙烯的光化反应以及光化反应中得到的环丁烷产物的连续电环化反应对3,4-二氯马来酰亚胺以及3,4-二氯香豆素进行增环反应的工作基础上,研究了3,4-二氯香豆素(1)和3,4-二氯马来酰亚胺(8)与5个α-苯基取代的环烯烃2-苯基苯并呋喃(15),3-苯基苯并呋喃(16),2,5-二苯基噁唑(17),2,5-二苯基噻唑(18),2-甲基-4-苯基噻唑(19),以及一个丁二烯——2,3-二甲氧基丁二烯(40)进行的芳香族增环反应。

The relation of the chromatographic retention indices of alkene to topological index,double bond atomic hybridization state index,polarizability effect index of branched chain to double bond atomic,immobile liquid polarity values and column temperatureat different temperatures on different stationary phases was studied.

通过对部分烯烃在不同固定相不同柱温下的1031个样本集的气相色谱保留指数值与其部分参数关系的研究,发现RI与拓扑指数、双键原子杂化状态指数、支链对双键的极化效应指数、固定液极性值及柱温的关系可表示为:^RI=-58.138+57.7460Q-8.2591Q+0.120T+0.807CP+36.460PBD+7.919DHSI(R=0.9989)继以留一法(Leave-one-out,LOO)进行交互检验,相关系数RCV=0.9977,说明所建模型具有良好的稳定性和预测能力,较好地揭示了烯烃类化合物气相色谱保留指数RI随固定相极性、柱温的改变而变化的规律

We gained the ethynylferrocene in high yield by the the reaction of triphenylphosphine with chloroform or bromoform in the presence of KOBu~t to give witting reagent, which reacted with formylferrocene and then followed by n-butyllithium dehydrohalogenation.

在本论文的第二部分,我们用三苯基磷与溴仿或氯仿在叔丁醇钾作用下,制得三苯基磷甲叉烯,然后与二茂铁甲醛反应,得到二氯取代烯烃,在正丁基锂作用下得到二茂铁乙炔。

The results showed that, both diene and alkaline nitrogen-containing compounds had negative influence on the aromatization stability of the catalyst.

用小型固定床加压反应器研究了液化石油气(C4 LPG)中的丁烯在纳米ZSM-5型催化剂DLG-1上的低温芳构化反应,重点考察了原料中二烯烃和碱性氮杂质,以及反应温度、压力和C4 LPG进料重量空速条件对催化剂芳构化反应活性及稳定性的影响。

The results show that there is excellent linear relationship between solute-related parameters and retention indexes for the saturated hydrocarbon, olefine and diene compounds on different polar chromatographic stationary phases.

结果表明:烷烃、烯烃、二烯烃类化合物在不同极性的色谱柱上的色谱保留与其分子结构描述参数之间具有较好的线性关系,烃类化合物在不同极性固定相上的保留主要与溶质分子的MR有关,即与溶质分子的色散力有关。

The reaction conversion and selectivity can be increased effectively by using multi-stage hydrogenation process and controlling H 2/ diolefin s molar ratio.

以该催化剂为基础开发的长链双烯多段选择性加氢工艺,在很宽的温度、压力、空速范围内都可达到很好的结果,严格控制氢气与双烯烃摩尔比,可有效提高反应的转化率和选择

Propylene production methods including olefin metathesis and catalytic cracking were introduced.

介绍了烯烃经歧化反应和催化裂解生产丙烯的方法,列举了国内外各大化工企业在该领域的研究及应用状况。

The influence of the amount of catalyst, reaction temperature, molar ratio of β-methylnaphthalene and olefins, reaction time and the amount of solvent has also been studied in detail.

详细考察了三氯化铝催化剂用量、反应温度、芳烯物质的量比、反应时间及溶剂用量对β-甲基萘与长链烯烃烷基化的影响。

These fabrics are made of such fibers as polypropylene , olefin, polyester, nylon, and acrylic.

这些织物使用的纤维有:聚丙烯、烯烃、涤纶、尼龙以及丙烯膊纤维。

The structures and configurations of other components weredetermined too.The results show that the structure of components ofChinese lacquer urushiol are the same as components of Japaneselacquer. In this work,2D-heteronuclear relayed coherence transferspectroscopy plays an important role in determining molecularskeleton carbon linkage.

研究结果表明,中国生漆漆酚中含量最大并起关键作用的两双键共轭的三烯漆酚的结构与构型与日本漆中的该组分完全相同,即都有末端甲基的3—十五碳烯烃(8′Z,11′E,13′Z)邻苯二酚,而没有末端双键的存在,其它几个漆酚主要组分的结构也与日本漆酚对应组分基本相同。

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