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In the paper, the research evolvement of electrocarboxylation from carbon dioxide with olefin, alkyne, and ketones in near decades was summarized, these reactions were convenient ways to synthesize some valuable pharmaceutical precursor and intermediates in organic synthesis.

文章综述了近几十年来二氧化碳与烯烃化合物、炔烃化合物以及酮类化合物的电羰基化反应的研究进展,这些反应是合成一些有价值的药物前驱体或是有机合成中间体的简便方法。

A desire to elucidate this reaction, and the analogous alkyne metathesis reaction, led to the discovery and development of high oxidation state complexes that contain a M=C or M C bond, so-called alkylidene and alkylidyne complexes, respectively.

为了阐述复分解反应,发现和发展了含有双键和三键的金属有机化合物,分别被称谓杂金属烯烃和杂金属炔烃。

This was attributed to its low acidity, which suppressed the aromatization and cracking reactions. Moreover, the olefin content in gasoline was significantly increased.

而且产物组成中烯烃的含量有明显上升,因此汽油的辛烷值仍能保持在较高的水平,没有因芳烃含量减少而降低。

A process for preparing cycloolefin features that in the presence of catalyst slurry containing metal Ru catalyst, water and metallic sulfate, the mononuclear aromatics is partially hydrogenated by hydrogen, and includes a step to control the activity of catalyst.

一种生产环烯烃的方法,该方法是在含有金属钌催化剂、水和金属硫酸盐的催化剂浆液存在下用氢部分加氢单环芳烃进行该方法,其中包括控制催化剂活性的步骤。

"Olefin Any unsaturated hydrocarbon containing one or more pairs of carbon atoms linked by a double Bond."

烯烃:含有一对或多对由双键连接的碳原子的一类不饱和烃。

"Olefin Any unsaturated hydro carbon containing one or more pairs of carbon atoms linked by a double bond."

烯烃:含有一对或多对由双键连接的碳原子的一类不饱和烃。

After methanol is taken out, the research octane number of C5 etherealization product is about 95. The alkene content is less than 35%, the sulfur content is less than 10μg/g and the aromatics content is less than 1%, it is a clean and high quality gasoline component with high octane number.

脱除甲醇后,裂解C5馏分选择性加氢后的醚化产物的研究法辛烷值为95左右,烯烃含量小于35%,硫含量小于10×10^(-6),芳烃含量小于1%,是一种优质、清洁的高辛烷值汽油组分。

And selectivities of mono- alkylbenzene and mono-alkyltoluene were more than 85% and 90% respectively.

以离子液体为催化剂,采用间歇式和连续式烷基化装置,研究了C20~C28长链α烯烃和芳烃烷基化制备长链烷基苯和长链烷基甲苯的工艺。

Anti-knock additive tetraethyl lead,vapor pressure,cetane number and content of aromatic hydrocarbon,ethylenes,sulfur and oxides respectively in the motor fuel are more detailedly analysed in regard to their effect on motor vehicle exhaust emission.

较为详细地分析了燃油中四乙铅抗爆剂、芳烃含量、烯烃含量、硫含量、蒸气压、十六烷值及含氧化合物等对汽车排放的影响,并简述了其发展趋势。

Result The results showed that its components were quite complex, and 89 organic compounds were identified. There were 72 kinds of oxygen-containing organic compounds which included esters, phenols, aethers, ketones and alcohols in the depolymerization product, small amounts of alkanes, alkenes, arenes, thiophenol and nitrogen-containing organic compounds were also detected, which showed that characteristics of the product with high oxygen content, low nitrogen and sulphur content.

结果]超临界乙醇解聚产物成分十分复杂,GC/MS分析鉴定出89种有机化合物,其中72种为含氧化合物,主要有酯、酚、醚、酮和醇等,还检测出少量烷烃、烯烃、芳烃、苯硫酚和含氮化合物,反映了解聚产物的高含氧量和低含氮硫量的特性。

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