烯烃

Some typical oxidation reactions of alkane ,olefin,and arene in supercritical CO2(scCO2)are introduced in this review.

介绍了有关烷烃、烯烃、芳烃化合物在超临界CO2介质中进行的氧化反应。

The nucleophiles include alkene , alkyne, alcohol, acid, amine, water, etc.

亲核试剂包括烯烃、炔烃、醇、酸、胺、水等。

Fischer et al.in 1973. Since these compounds have various particular reactions in organic synthesis,especially in vitamins,peptides,synthesis of anti-cancer drugs and natural products,and as olefins, alkyne polymerization catalysts demonstrated its unique advantages and broad application prospects.

由于这类化合物有各种奇特的反应性能，在有机合成中，尤其是在维生素，多肽，抗癌药物和天然产物的合成，和作为烯烃，炔烃聚合催化剂方面显示出其独特的优越性和广阔的应用前景。

On the other hand, a method for the synthesis of-vinyl chalcogenides by the coupling of vinyl bromides with thiols or diphenyl diselenide using copper salts as catalysts in ionic liquids based on amino acids also has been described. The ionic liquids play multiple roles in the reaction: they act as solvent, base, and excellent promoter for the copper-catalyzed coupling reactions.

在新型的氨基酸负离子的离子液体中，开发了一个亚铜盐催化的Z-型溴代烯烃与硫族元素的交叉偶联反应，为立体选择性的制备Z-型烯基硫醚或烯基硒醚类化合物提供了一个新的方法；在此反应体系中，离子液体不仅起到了反应溶剂的作用，而且还起到了金属催化剂的配体和中和反应副产物的碱的作用。

HMT general synthesis is aluminum chloride as a catalyst, isopropyl - toluene right with the new hexene, or 2 January 2 3 1 2 1-butene six-olefins reaction.

HMT的合成一般是以三氯化铝为催化剂，由对异丙基甲苯与新己烯、或2，3一二甲基一2一丁烯等六碳烯烃反应生成。

Was applied to the AD reaction of eight olefins in PEG/NMO system according to the protocol of ligand 8. The yields and ees of the diols were 70～90% and 77～96%(except for trans-5-decene and ally naphthyl ether) respectively.

在与8相同的催化反应条件下，手性配体9催化八种烯烃的AD反应得到的化学产率和ee值分别为70～90％和77-96％（反式-5-癸烯和萘基烯丙基醚除外）。

The yields were 67～89% and 61～90% respectively, and the ees were 66～99. 9% and 68～99. 9% respectively (except for trans-5-decene and ally naphthyl ether). With trans-stilbene as the substrate, chiral ligands and OsO〓 could be recovered and reused five times in the AD reaction with high catalytic activity and stereoselectivity.

4在PF〓/NMO体系中，将配体8和10分别用于八种烯烃的AD反应，配体、OsO〓和底物的摩尔比为0.02/0.015/1时，化学产率分别为67～91％和61～90％，ee值分别为66～99.9％和68～99.9％（反式-5-癸烯和萘基烯丙基醚除外）。

LOSA-1 is an assistant for increasing production of Light olefine with FCC.The result of its comnercial application in No.2 heavy oil FCC unit in Luoyang company shows that it can raise propylene content in liquefied gas.When its equilibrium addition is about 200kg/d with the proportion to fresh catalyst volume of 5%,the propylne content in liquefied gas can keep at 42%～45%. FCC;propylene;assistant LOSA-1;commercial application

LOSA-1助剂是岳阳三生化工公司和国内科研院所开发的增产轻烯烃FCC助催化剂，该剂在中国石化洛阳分公司2号重油催化裂化装置工业应用的结果表明，LOSA-1助剂具有较强的提高液化气中丙烯浓度的性能，当其平衡加入量控制在200kg/d左右、对新鲜催化剂加入比例为5%左右时，液化气中的丙烯体积浓度能够保持在42%～45%。

The future technical advances hot poits in the petrochemical industry into new century for the refining-chemical integration and increasing olefine production technology ,the sythetic gas producing fuel and chemicals and light alkane activation technology ,the new separation and reaction technology ,the biochemlcal products technology 、the nanotechnology and the high efficiency informatiom technology are presented .

进入新世纪以来，世界石化原料和石化产品需求仍将持续增长，据2002年召开的第17届世界石油大会预测，1998~2010年间，乙烯需求将由8000万吨增加到12000万吨，丙烯将由4500万吨增加到8200万吨，丁烯-1将由80万吨增加到140万吨，α-烯烃将由100万吨增加到220万吨，苯将由2700万吨增加到4000万吨，对二甲苯将由1400万吨增加到3000万吨。2000~2020年间，石油用于石油化工的年均增长率为2.5%，超过石油的其他用途增长率。

In order to decrease copolymerization loss of isoprene during thermal dimerization of cyclopentadiene in C5-fraction,the effect of three inhibitors,diethylhydroxylamine,p-tert-butylcatechol and o-nitrophenol,on dienes' polymerization in the process was investigated by experiment with sealed glasstube.

为减少C5馏分环戊二烯热二聚过程中异戊二烯的聚合损失，采用封管实验方法考察了添加阻聚剂二乙基羟胺、对叔丁基邻苯二酚、邻硝基苯酚对热二聚过程中各二烯烃组分聚合程度的影响。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新