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Part 2. Annulation reaction of 3, 4-dichlorocoumarin (1) and 3, 4-dichloromaleimide (8) by a new general annulation strategy developed in this group with 2-phenylbenzofuran (15), 3-phenylbenzofuran (16), 2, 5-diphenyloxazole (17), 2, 5-diphenylthiazole (18), 2-methyl-4-phenylthiazole (19) and 2, 3-dimethoxy-1, 3-butadiene (40) were investigated.

二。在本课题组前一阶段提出的从二氯代环烯酮与1,1-二芳基乙烯的光化反应以及光化反应中得到的环丁烷产物的连续电环化反应对3,4-二氯马来酰亚胺以及3,4-二氯香豆素进行增环反应的工作基础上,研究了3,4-二氯香豆素(1)和3,4-二氯马来酰亚胺(8)与5个α-苯基取代的环烯烃2-苯基苯并呋喃(15),3-苯基苯并呋喃(16),2,5-二苯基噁唑(17),2,5-二苯基噻唑(18),2-甲基-4-苯基噻唑(19),以及一个丁二烯——2,3-二甲氧基丁二烯(40)进行的芳香族增环反应。

The copolymerization compound comprises based on a proportioning ratio by weight: 25-99 percent ethylene aromatic series monomer; 0-30 percent olefinic undersaturation nitrile monomer; 1-50 percent olefinic dibasic acid ramification monomer.

这种共聚组合物按重量百分比包含:25至99%的乙烯基芳香族单体;0至30%的烯属不饱和腈类单体;1至50%的烯属二元酸衍生物单体。

According to the weight percent, the copolymer composition comprises: 25 percent to 99 percent of the vinyl aromatic monomer; 0 percent to 30 percent of the en-unsaturated nitrile monomer; 1 percent to 50 percent ene dicarboxylic acid derivative monomer.

这种共聚组合物按重量百分比包含:25至99%的乙烯基芳香族单体;0至30%的烯属不饱和腈类单体;1至50%的烯属二元酸衍生物单体。

The biosynthesis of the quinoid nucleus are the same in all coenzyme Qs. The biosynthesis of the isoprenoid side chain determine the kind of coenzyme Q.

芳香环的合成在所有的辅酶Q族物质中都是相同的,异戊烯基侧链的长度则决定了辅酶Q的种类,这里存在一个关键酶,即异戊烯焦磷酸合成酶。

On the other hand, a method for the synthesis of-vinyl chalcogenides by the coupling of vinyl bromides with thiols or diphenyl diselenide using copper salts as catalysts in ionic liquids based on amino acids also has been described. The ionic liquids play multiple roles in the reaction: they act as solvent, base, and excellent promoter for the copper-catalyzed coupling reactions.

在新型的氨基酸负离子的离子液体中,开发了一个亚铜盐催化的Z-型溴代烯烃与硫族元素的交叉偶联反应,为立体选择性的制备Z-型烯基硫醚或烯基硒醚类化合物提供了一个新的方法;在此反应体系中,离子液体不仅起到了反应溶剂的作用,而且还起到了金属催化剂的配体和中和反应副产物的碱的作用。

Tyrosine An aromatic amino acid derived from erythrose 4-phosphate and phosphoenolpyruvate.

酪氨酸:由4-磷酸赤藓糖和磷酸烯醇式丙酮酸衍生的一种芳香族氨基酸。

Phenylalanine An aromatic AMINO ACID derived from phosphoenolpyruvate and erythrose 4-phosphate.

苯丙氨酸:是来自于磷酸烯醇式丙酮酸和4-磷酸赤藓糖的芳香族氨基酸。

Escherichia coli and many other microoganism synthesize aromatic amino acids through the condensation reaction between phospho enolpyruvate and erythro.

ppsA和tktA是芳香族氨基酸生物合成中心途径的两个关键酶基因,在大肠杆菌中,ppsA基因编码磷酸烯醇式丙酮酸合成酶A ,该酶催化丙酮酸合成磷酸烯醇式丙酮酸;tktA基因编码转酮酶A ,该酶在磷酸戊糖途径中生成 4 磷酸赤藓糖起主要作用。

Advances in Research on Plants Reactions under Phosphate Starvation;2. Topics discussed in this article includes synthesis and structures of R2M24, the reactions of its metal-metal triple bond with various reagents such as nucleophiles, carbon-carbon mu.

本文对一类重要的ⅥB族金属叁键化合物R_2M_2_4(R为环戊二烯基及类环戊二烯基)近年来的研究成果进行了综述,综述重点是这类化合物的官能团M≡M参键的化学活性,全文包括R_2M_2_4的合成及结构,M≡M叁键与亲核试剂、与碳-碳重键,与氧或与金属羰基物等试剂的反应及其应用。

Topics discussed in this article includes synthesis and structures of R2M24, the reactions of its metal-metal triple bond with various reagents such as nucleophiles, carbon-carbon mu.

本文对一类重要的ⅥB族金属叁键化合物R_2M_2_4(R为环戊二烯基及类环戊二烯基)近年来的研究成果进行了综述,综述重点是这类化合物的官能团M≡M参键的化学活性,全文包括R_2M_2_4的合成及结构,M≡M叁键与亲核试剂、与碳-碳重键,与氧或与金属羰基物等试剂的反应及其应用。

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